Professor
Research
Research focus. My group’s work in synthetic polymer chemistry includes the preparation of new monomers, polymers, and nanocomposite structures, and cuts across application areas of biomolecular materials, electronic materials and devices, and interface modification and stabilization. Recognizing that many pressing needs in materials science and engineering cannot be satisfied with commercially available “off-the-shelf” polymers, we strive to discover functional polymers that open exciting opportunities in soft materials science. Some materials chemistry advances made by my group include new types of polymer interlayers in electronic materials and devices (Science 2014, Angew Chem 2019, and ACS Nano 2021), functional polymers that produce “smart droplets” and “adhesive fluids” (Advanced Functional Materials 2019 and J. Am. Chem. Soc. 2021), and methods for preparing a wide range of novel and unconventional polymer zwitterions (J. Am. Chem. Soc. 2021 and ACS MacroLetters 2021). We enjoy working simultaneously along several segments of synthetic chemistry which altogether imparts a collaborative spirit to our group and its activities.
You can follow us on Twitter @Emrickgroup and freely reach out to me at @email.
Examples of @Emrickgroup research
Smart droplets and approaches to self-healing. In one example of current research, we are designing functional hydrophilic and amphiphilic polymers that segregate to fluid-fluid interfaces, stabilize emulsion droplets, and bring useful functional properties to droplets. Several years ago, inspired by theoretical work of Anna Balazs (U Pittsburgh), we developed a preparation of emulsion droplets that successfully deliver reagents to substrates, and in particular to damaged areas of substrates to promote mechanical healing. This research has since evolved to produce a rich array of smart droplets, typically stabilized by polymer zwitterions in which additional useful functionality is integrated into the backbone. Recently, as shown in the accompanying cover art, we prepared new types of polymer-stabilized droplets that proved amenable to picking up particles from pristine (undamaged) regions of substrates, carrying the particles temporarily, and then depositing the particles into the damaged regions of the same substrate (Advanced Functional Materials, 2019). This “clean-and-repair” concept, inspired by Nature’s ability to use cell surfaces to probe and repair wound sites in vivo, requires tailoring the properties of all relevant interfaces: substrate/droplet, particle/substrate, particle/droplet, and fluid/fluid. In the process of this research, we learn how to simplify the complex chemistry and biology of living systems, using new synthetic polymers and attention to interfacial energies.
Polymer zwitterions as biomaterials and in therapeutics. For several years, we have been building the chemistry of polymer zwitterions in new directions, with objectives to produce advanced biomaterials and polymer scaffolds that enable improved drug delivery in vivo. Recognizing the importance of phosphorylcholine (PC)-containing methacrylate polymers (such as pioneered by Ishihara and coworkers), we have constructed a platform of “PC-polymers”, ranging from polyolefins to polyesters to methacrylate derivatives. A particularly exciting opportunity is found in the “reverse PC” or choline phosphate polymers, which we find to be amenable to direct incorporation of useful, reactive functionality for bioconjugation, drug attachment, and cross-linking chemistry (J. Am. Chem. Soc. 2016). Early on, our group recognized the potential to use polymer zwitterions as “PEG-replacements” in therapeutics, and have produced numerous examples of polymer-drug conjugates using polymer zwitterions, including with the chemotherapeutics doxorubicin, camptothecin, and temozolomide (TMZ) (our recent TMZ example is described in ACS Chemical Neuroscience 2018). At the same time, we have studied new types of polymer chemistry and architecture for DNA complexation and delivery, as described in a recently published article (WIREs Nanomedicine 2019) that we co-authored with our collaborator Marxa Figueiredo (Purdue).
Conjugated polymer zwitterions (CPZs) for electronic materials & devices. Combining zwitterionic functionality with p-conjugated polymers has yielded a library of new structures that prove impressively useful as interlayer materials in devices such as solar cells. Our initial curiosity as to the properties of conjugated polymers containing zwitterionic pendent groups led to numerous findings, including the impact of CPZs on the work function of metals with which they come into contact and the unique solubility of CPZs that allows for integration of clean CPZ interlayers at the electrode-active layer interface of solar cells (e.g., Science 2014 and ACS Central Science 2018). These two features, coupled with CPZ facilitation of charge transport even for relatively thick interlayers (50 nm or greater), make CPZs exceptionally useful for any of a variety of (opto)electronic materials and devices. We are now finding CPZs, and more generally polymer zwitterions, to produce similarly interesting effects on 2D materials such as transition metal dichalcogenides (TMDCs) and graphene (ACS Nano, 2018), opening yet another avenue for polymer zwitterions in conjunction with electronic materials.
People
- Dylan Barber, Ph.D. Polymer Science and Engineering, 2022, Harvard University
- Irem Bolukbasi, Ph.D. Polymer Science and Engineering, 2015, 3M
- Rebecca Boudreaux, Ph.D. Polymer Science and Engineering, 2009, Oberon Fuels
- Kurt Breitenkamp, Ph.D. Polymer Science and Engineering, 2009, NanoGraf Corporation
- Marcel Brown, Ph.D. Polymer Science and Engineering, 2022, Celanese
- Deborah Cassaro-Snyder, Ph.D. Polymer Science and Engineering, 2024
- Chia-Chih (George) Chang, Ph.D. Polymer Science and Engineering, 2017, National Chiao Tung University Taiwan, Hsinchu, Taiwan
- Sirinya Chantarak, Ph.D. Polymer Science and Engineering, 2014, Prince of Songkla University
- Marcus Cole, Ph.D. Polymer Science and Engineering, 2020, Universal Display Corporation
- Beth Cooper, Ph.D. Polymer Science and Engineering, 2010, The Dow Chemical Company
- Kenneth Ellzey, Ph.D. Polymer Science and Engineering, 2004, Matrix Research, Inc.
- Genevieve Fein, M.S. Polymer Science and Engineering, 2006, Newton County Day School
- Dina Feith, M.S. Polymer Science and Engineering, 2004, Tarveda Therapeutics
- Aleksandr Gerasimenko, M.S. Polymer Science and Engineering, 2012, Vitro
- Elizabeth Glogowski, Ph.D. Polymer Science and Engineering, 2009, University of Wisconsin-Eau Claire
- Polina Gokun, M.S. Polymer Science and Engineering, 2013
- Brenton Hammer, Ph.D. Polymer Science and Engineering, 2013, California State University, Northridge
- Yunxia Hu, Ph.D. Polymer Science and Engineering, 2011, Tianjin Polytechnic University
- Hyunki Kim, Ph.D. Polymer Science and Engineering, 2020, 3M
- Katrina Kratz, Ph.D. Polymer Science and Engineering, 2012, Celanese
- Jimmy Lawrence, Ph.D. Polymer Science and Engineering, 2015, Louisiana State University
- Cheol Hee Lee, Ph.D. Polymer Science and Engineering, 2014, LG Chemical, KOREA
- Rachel Letteri, Ph.D. Polymer Science and Engineering, 2016, University of Virginia
- Caroline Miesch, Ph.D. Polymer Science and Engineering, 2014, Dow Chemical
- James Pagaduan, Ph.D. Polymer Science and Engineering, 2023, DOW Chemical
- Samantha Page, Ph.D. Polymer Science and Engineering, 2014, Cantor Colburn LLP
- Zachariah Page, Ph.D. Polymer Science and Engineering, 2015, The University of Texas at Austin
- Bryan Parrish, Ph.D. Polymer Science and Engineering, 2006, Clorox
- Cristiam Santa Chalarca, Ph.D. Polymer Science and Engineering, 2019, Glasst Innovation Company
- Ashlin Sathyan, Ph.D. Polymer Science and Engineering, 2021, Dupont
- Ryan Selhorst, Ph.D. Polymer Science and Engineering, 2019, Air Force Research Laboratory
- Kevin Sill, Ph.D. Polymer Science and Engineering, 2006, BW Therapeutics
- Habib Skaff, Ph.D. Polymer Science and Engineering, 2005, Florida Carpet and Pad Recycling
- Matthew Skinner, Ph.D. Polymer Science and Engineering, 2018, Tender Food
- Elizabeth Stubbs, Ph.D. Polymer Science and Engineering, 2022, Delrin
- Ravisubhash Tangirala, Ph.D. Polymer Science and Engineering, 2009, Sila Nanotechnologies
- Carolyn Telfer, M.S. Polymer Science and Engineering, 2023
- Phillip von Tiedemann, M.S. Polymer Science and Engineering, 2015, BASF
- Hsin-Wei Wang, Ph.D. Polymer Science and Engineering, 2016, Intel
- Sarah Ward, Ph.D. Polymer Science and Engineering, 2021, Cornell University Center for Technology Licensing
- Qingling Zhang, Ph.D. Polymer Science and Engineering, 2008, BASF Automotive OEM Coating
- Le Zhou, Ph.D. Polymer Science and Engineering, 2023, Dupont
- Delphine Chan-Seng, Postdoc (2007 - 2011), CNRS
- Xiangji Chen, Postdoc (2008 - 2011), Medtronic Inc
- Umesh Choudhary, Postdoc (2015 - 2017), Entegris, Inc
- Jianxun Cui, Postdoc (2021 - 2022)
- Gaojie Hu, Postdoc (2013 - 2015), Evonik
- Aabid Mir, Postdoc (2013 - 2016), Entegris
- Sangram S. Parelkar, Postdoc (2007 - 2014), UMass Medical School
- Abhijit Paul, Postdoc (2015 - 2016), EEStor. Corporation
- Emily Pentzer, Postdoc (2010 - 2013), Case Western Reserve University
- Egle Puodziukynaite, Postdoc (2013 - 2015)
- Thangamani Ranganathan, Postdoc (2005 - 2009)
- Hemali Rathnayake, Postdoc (2006 - 2009)
- Ravindra Revanur, Postdoc (2004 - 2008)
- Banishree Saha, Postdoc (2016 - 2018), University of Massachusetts Medical School
- Debasis Samanta, Postdoc (2006 - 2009)
- Angela Sauers, Postdoc (2010 - 2012)
- Madhu Sheri, Postdoc (2016 - 2019), University of Massachusetts Amherst
- Pallikkava Sudeep, Postdoc (2006 - 2010), Cabot Microelectronics
- Yun Lu Sun, Postdoc (2016 - 2019), The University of Texas at Austin
- Megan Szyndler, Postdoc (2013 - 2015)
- Zhefei Yang, Postdoc (2017 - 2023), Oak Ridge National Laboratory
- Ying (Richard) Ying (Richard) , Postdoc (2013 - 2007), School Materials Science and Engineering at Sun Yat-sen Universi
- Seunghoo Yoo, Postdoc (2002 - 00/0)
- Jing Zhao, Postdoc (2018 - 2021)
Awards
- 2016 College of Natural Sciences Outstanding Research Award, University of Massachusetts
- 2016 Elected to the 2016 class of POLY Fellows of the American Chemical Society
- 2015 Carl S. Marvel Creative Polymer Chemistry Award, American Chemical Society
- 2014 Selected as a member of the 2014 class of Fellows of the American Chemical Society
- 2013 Selected to the National Academy of Inventors
- 2013 Landmark Award, Commercial Ventures in Intellectual Property University of Massachusetts (10th awarded patent)
- 2013 Elected to the 2013 Class of PMSE Fellows of the American Chemical Society
- 2011 Chair, Macromolecular Materials Gordon Research Conference, Ventura CA
- 2011 Chair, Polymeric Materials Science & Engineering (PMSE) Division of the ACS
- 2010 Keynote Speaker, Bayer Material Science Innovation Technology Symposium, Pittsburgh, PA
- 2010 Milestone Award, Commercial Ventures in Intellectual Property, University of Massachusetts (5th awarded patent)
- 2009 Featured speaker, Hybrid Materials 2009, Tours, France
- 2006 Arthur K. Doolittle Award, Polymer Materials Science & Engineering (PMSE) Division of the American Chemical Society
- 2005 Juniata College Young Alumni Achievement Award
- 2004 Technology Development Award, Persident's Office, University of Massachusetts
- 2003 National Science Foundation CAREER Award
- 2003 NSF travel award: CERC-3 Conference in Gotenborg, Sweden
- 2003 Selected as a U.S. representative to the U.S.-German Polymer Symposium, Bayreuth, Germany
- 2002 Center for UMass-Industry Research on Polymers (CUMIRP): Exploratory Research Award
- 2001 Omnova, Inc. Signature Young Faculty Award
Support Funding
- The support of a number of agencies and corporations has been critically important to the research efforts:
The National Institute of Health - R21
The National Science Foundation (CHE, CBET, DMR-BMAT)
The NSF-Materials Research Science and Engineering Center on Polymers at UMass (DMR-0820506)
The Department of Energy Office of Basic Energy Sciences
The PHaSE Energy Frontier Research Center at UMass
Army Research Office
The Federal Aviation Administration
BASF
News from the Emrick Research Group
More News from the Emrick Research GroupPublications
(274 Peer-Reviewed; H-Index = 54)
Most Cited Papers (Top 10)
1. Balazs, A.C.; Emrick, T.; Russell, T.P. “Nanoparticle-polymer Composites: Where Two Small Worlds Meet” Science, 2006, 314, 1107-1110. (1760 citations)
2. Lin, Y.; Boker, A.; He, J.B.; Sill, K.; Xiang, H.Q.; Abetz, C.; Li, X.F.; Wang, J.; Emrick, T.; Long, S.; Wang, Q.; Balas, A.; Russell, T.P. “Self-directed Self-assembly of Nanoparticle/copolymer Mixtures” Nature 2005, 434, 55-59. (800 citations)
3. Lin, Y.; Skaff, H.; Emrick, T.; Dinsmore, A.D.; Russell, T.P. “Nanoparticle Assembly and Transport at Liquid-Liquid Interfaces” Science 2003, 299, 226-229. (781 citations)
4. Parrish, B.; Breitenkamp, R.B.; Emrick, T. “PEG and Peptide-grafted Aliphatic Polyesters by Click Chemistry” J. Am. Chem. Soc., 2005, 127, 7404-7410. (502 citations)
5. Boeker, A.; He, J.; Emrick, T.; Russell, T. P. Self-assembly of nanoparticles at interfaces. Soft Matter 2007, 3 (10), 1231-1248. DOI: 10.1039/b706609k. (406 citations)
6. Huang, J; Juskiewicz, M; de Jeu, WH; Cerda, E; Emrick, T; Menon, N; Russell, T.P. “Capillary wrinkling of floating thin polymer films” Science 2007, 317, 650-653. (333 citations)
7. Boeker, A.; Lin, T.; Chiapperini, K.; Horowitz, R.; Thompson, M.; Carreon, V.; Xu, T.; Abetz, C.; Skaff, H.; Dinsmore, A.D.; Emrick, T.; Russell, T.P. “Hierarchical Nanoparticle Assemblies Formed by Decorating Breath Figures” Nature Materials 2004, 3, 302-306. (294 citations)
8. Zhang, Q., Cirpan, A., Russell, T.P., Emrick, T.. "Donor-Acceptor Poly(thiophene-block-perylene diimide) Copolymers: Synthesis and Solar Cell Fabrication" Macromolecules. 2009, 42, 1079-1082. (272 citations)
9. Gupta, S.; Zhang, Q. L.; Emrick, T.; Balazs, A. C.; Russell, T. P. Entropy-driven segregation of nanoparticles to cracks in multilayered composite polymer structures. Nature Materials 2006, 5 (3), 229-233. DOI: 10.1038/nmat1582. (245 citations)
10. Hong, R.; Fisher, N.O.; Verma, A.; Goodman, C.M.; Emrick, T.; Rotello, V.M. “Control of Protein Structure and Function through Surface Recognition by Tailored Nanoparticle Scaffolds” J. Am. Chem. Soc. 2004, 126, 739-743. (241 citations)
11. Emrick, T.; Chang, H-T.; Fréchet, J.M.J. "An A2 + B3 Approach to Hyperbranched Aliphatic Polyethers Containing Chain End Epoxy Substituents" Macromolecules 1999, 32, 6380. (235 citations)
298. Brown, M. U.; Seong, H.; Russell, T.P.; Emrick, T. Zwitterionic Sulfonium Solfonate Polymers: Impacts of Substituents and Inverted Dipole. Macromolecules 2023 56, 1105-1110. DOI:10.1021/acs.macromol.2c02359
297. Sonu, K. P.; Zhou, L.; Biswas, S.; Klier, J.; Balazs, A.C.; Emrick, T.; Peyton, S.R. Strain-stiffening Hydrogels with Dynamic, Secondary Cross-Linking. Langmuir 2023, 39, 2659-2666. DOI: 10.1021/acs.languir.2c03117.
296. Barber, D.M.; Emrick, T.; Grason, G.M.; Crosby, A.J. Self-Spinning Filaments for Autonomously Linked Microfibers. Nature Chemistry 2023, article in press. doi.org/10.1038/s41467-023-36355-w.
295. Zhou, L.; Yang, Z.; Pagaduan, J.N.; Emrick, T. Fluorinated Zwitterionic Polymers as Dynamic Surface Coatings. Polym. Chem. 2023, 14, 32-28. DOI:10,1039/d2py01197b.
294. Hamilton, H.; Meissner, C.; Emrick, T.; Bradley, L.C. One-Step Synthesis of Biphasic, Cavity-Forming Polymer Particles via Dispersion Copolymerization of Styrene and Sulfobetaine Methacrylate Macromol. Rapid Commun. 2023, 2200873 DOI 10.1012/marc.202200873.
2018
Ly, J.T.; Burnett, E.K.; Thomas, S.; Aljarb, A.; Liu, Y.; Park, S.; Rosa, S; Yi, Y.; Lee, H.; Emrick, T.; Russell, T.P.; Bredas, J.L.; Briseno, A.L. Efficient Electron Mobility in an All-Acceptor Napthalenediimide-Bithiazole Polymer Semiconductor with Large Backbone Torsion. ACS Applied Materials & Interfaces 2018, 10 (46), 40070-40077. DOI: 10.1021/acsami.8b11234
Santa Chalarca, C.F.; Letteri, R.A.; Perazzo, A.; Stone, H.A.; Emrick, T. Building supracolloidal fibers from zwitterion-stabilized adhesive emulsions. Advanced Functional Materials 2018, 28(45), Article 1804325, 10 pages. DOI: 10.1002/adfm.201804325
Sun, Y.L.; Tang, H.Y.; Ribbe, A.; Duzhko, V.; Woodard, T.L.; Ward, J.E.; Bai, Y.; Nevin, K.P.; Nonnenmann, S.S.; Russell, T.; Emrick, T.; Lovley, D.R. Conductive composite materials fabricated from microbially produced protein nanowires. Small 2018, 14 (44), Article 1802624, 5 pages. DOI: 10.1002/smll.201802624
Ward, S.M.; Skinner, M.; Saha, B.; Emrick, T. Polymer - Temozolomide conjugates as therapeutics for treating Glioblastoma. Molecular Pharmaceutics 2018, 15 (11), 5263-5276. DOI: 10.1021/acs.molpharmaceut.8b00766
Karak, S.; Page, Z.A.; Li, S.G.; Tinkham, J.S.; Lahti, P.M.; Duzhko, V.V.; Emrick, T. Amino-fulleropyrrolidines as electrotropic additives to enhance organic photovoltaics. Sustainable Energy & Fuels 2018, 2(10), 2143-2147. DOI: 10.1039/c8se00294k
Skinner, M.; Johnston, B.M.; Liu, Y.L.; Hammer, B.; Selhorst, R.; Xenidou, I.; Perry, S.L.; Emrick, T. Synthesis of Zwitterionic Pluronic Analogs. Biomacromolecules 2018, 19(8), 3377-3389. DOI: 10.1021/acs.biomac.8b00676
Liu, Y.; Sheri, M.; Cole, M.D.; Emrick, T.; Russell, T.P. Combining Fullerenes and Zwitterions in Non-Conjugated Polymer Interlayers to Raise Solar Cell Efficiency. Angewandte Chemie-International Edition 2018, 57 (31), 9675-9678. DOI: 10.1002/anie.201803748
Heo, K.; Miesch, C.; Na, J.H.; Emrick, T.; Hayward, R.C. Assembly of P3HT/CdSe nanowire networks in an insulating polymer host. Soft Matter 2018, 14 (25), 5327-5332. DOI: 10.1039/c8sm01001c
Jansen, L.E.; Amer, L.D.; Chen, E.Y.UT.; Nguyen, T.V.; Saleh, L.S.; Emrick, T.; Liu, W.F.; Bryant, S.J.; Peyton, S.R. Zwitterionic PEG-PC Hydrogels Modulate the Foreign Body Response in a Modulus-Dependent Manner. Biomacromolecules 2018, 19 (7), 2880-2888. DOI: 10.1021/acs.biomac.8b00444
Selhorst, R.; Wang, P.J.; Barnes, M.; Emrick, T. Bithiazolidinyleidene polymers: synthesis and electronic interactions with transition metal dichalcogenides. Chemical Science 2018, 9 (22), 5047-5051. DOI: 10.1039/c8sc01416g
Forth, J.; Liu, X.B.; Hasnain, J.; Toor, A.; Miszta, K.; Shi, S.W.; Geissler, P.L.; Emrick, T.; Helms, B.A.; Russell, T.P. Reconfigurable Printed Liquids. Advanced Materials 2018, 30(16). artno. 1707603. DOI: 10.1002/adma.201707603
Sheri, M.; Choudhary, U.; Grandhee, S.; Emrick, T. Fluoride-Catalyzed Deblocking: A Route to Polymeric Urethanes. Angewandte Chemie-International Edition 2018, 57(17), 4599-4602. DOI: 10.1002/anie.201800795
Liu, Y.; Cole, M.D.; Jiang, Y.F.; Kim, P.Y.; Nordlund, D.; Emrick, T.; Russell, T.P. Chemical and Morphological Control of Interfacial Self-Doping for Efficient Organic Electronics. Advanced Materials 2018, 30 (15), Article 1705976, 8 pages. DOI: 10.1002/adma.201705976
Barber, D.; Crosby, A.J.; Emrick, T. Mesoscale block copolymers. Advanced Materials 2018, 30 (13), Article 1706118, 6 pages. DOI: 10.1002/adma.201706118
Liu, Y.; Page, Z.A.; Zhou, D.M.; Duzhko, V.V.; Kittilstved, K.R.; Emrick, T.; Russell, T.P. Chemical Stabilization of Perovskite Solar Cells with Functional Fulleropyrrolidines. ACS Central Science 2018, 4 (2), 216-222. DOI: 10.1021/acscentsci.7b00454
Alon, H.; Stern, C.; Kirshner, M.; Sinai, O.; Wasserman, M.; Selhorst, R.; Gasper, R.; Ramasubramaniam, A.; Emrick, T.; Nayeh, D. Lithographically Patterned Functional Polymer-Graphene Hybrids for Nanoscale Electronics. ACS Nano 2018, 12 (2), 1928-1933. DOI: 10.1021/acsnano.7b08844
Skinner, M.; Ward, S.M.; Nilsson, C.L.; Emrick, T. Augmenting Glioblastoma Chemotherapy with Polymers. ACS Chemical Neuroscience 2018, 9 (1), 8-10. DOI: 10.1021/acschemneuro.7b00168
2017
Tran, Y.H.; Rasmuson, M.J.; Emrick, T.; Klier, J.; Peyton, S.R. Strain-stiffening gels based on latent crosslinking. Soft Matter 2017, 13 (47), 9007-9014. DOI: 10.1039/c7sm01888f
Kalasin, S.; Letteri, R.A.; Emrick, T.; Santore, MM. Adsorbed Polyzwitterion Copolymer Layers Designed for Protein Repellency and Interfacial Retention. Lanmuir 2017, 33 (47), 13708-13717. DOI: 10.1021/acs.langmuir.7b03391
Ramasubramanium, A.; Selhorst, R.; Alon, H.; Barnes, M.D.; Emrick, T.; Naveh, D. Combining 2D inorganic semiconductors and organic polymers at the frontier of the hard-soft materials interface. Journal of Materials Chemistry C 2017, 5 (43), 11158-11164.DOI: 10.1039/c7tc02790g
Liu, Y.; Renna, L.A.; Thompson, H.B.; Page, Z.A.; Emrick, T.; Barnes, M.D.; Bag, M.; Venkataraman, D.; Russell, T.P. Role of Ionic Functional Groups on Ion Transport at Perovskite Interfaces. Advanced Energy Materials 2017, 7 (21), Article 1701235, 13 pages. DOI: 10.1002/aenm.201701235
Ruscello, M.; Stolz, S.; Arellano, D.L.G.; Ullrich, F.; Hillebrandt, S.; Mankel, E.; Pucci, A.; Kowalsky, W.; Emrick, T.; Briseno, A.L.; Hernandez-Sosa, G. Electron injection and interfacial trap passivation in solution-processed organic light-emitting diodes using a polymer zwitterion interlayer. Organic Electronics 2017, 50, 384-388. DOI: 10.1016/j.orgel.2017.08.014
Kirschner, A.Y.; Chang, C.C.; Kasemset, S.; Emrick, T.; Freeman, B.D. Fouling-resistant ultrafiltration membranes prepared via co-deposition of dopamine/zwitterion composite coatings. Journal of Membrane Science 2017, 541, 300-311. DOI: 10.1016/j.memsci.2017.06.055
Letteri, R.A.; Chalarca, C.F.S.; Bai, Y.; Hayward, R.C.; Emrick, T. Forming Sticky Droplets from Slippery Polymer Zwitterions. Advanced Materials 2017, 29 (38), Article 1702921, 8 pages. DOI: 10.1002/adma.201702921
Cole, M.D.; Sheri, M.; Bielicki, C.; Emrick, T. Perylene Diimide-Based Ionene and Zwitterionic Polymers: Synthesis and Solution Photophysical Properties. Macromolecules 2017, 50 (19), 7535-7542. DOI: 10.1021/acs.macromol.7b01281
Wang, J.C.; Bindokas, V.P.; Skinner, M.; Emrick, T.; Marks, J.D. Mitochondrial mechanisms of neuronal rescue by F-68, a hydrophilic Pluronic block co-polymer, following acute substrate deprivation. Neurochemistry International 2017, 109 (Special Issue), 126-140. DOI: 10.1016/j.neuint.2017.04.007
Johnston, B.M.; Johnston, C.W.; Letteri, R.A.; Lytle, T.K.; Sing, C.E.; Emrick, T.; Perry, S.L. The effect of comb architecture on complex coacervation. Organic & Biomolecular Chemistry 2017, 15 (36), 7630-7642. DOI: 10.1039/c7ob01314k
Sae-Ung, P.; Kolewe, K. W.; Bai, Y.; Rice, E. W.; Schiffman, J. D.; Emrick, T.; Hoven, V. P. Antifouling Stripes Prepared from Clickable Zwitterionic Copolymers. Langmuir 2017, 33 (28), 7028-7035. DOI: 10.1021/acs.langmuir.7b01431
Choudhary, U.; Mir, A. A.; Emrick, T. Soluble, Allyl-Functionalized Deoxybenzoin Polymers. Macromolecules 2017, 50 (10), 3773-3779. DOI: 10.1021/acs.macromol.7b00460
Duzhko, V. V.; Dunham, B.; Rosa, S. J.; Cole, M. D.; Paul, A.; Page, Z. A.; Dimitrakopoulos, C.; Emrick, T. N-Doped Zwitterionic Fullerenes as Interlayers in Organic and Perovskite Photovoltaic Devices. ACS Energy Letters 2017, 2 (5), 957-963. DOI: 10.1021/acsenergylett.7b00147
Skinner, M.; Ward, S. M.; Emrick, T. Versatile Synthesis of Polymer-Temozolomide Conjugates. ACS Macro Letters 2017, 6 (3), 215-218. DOI: 10.1021/acsmacrolett.7b00007
Kosif, I.; Kratz, K.; You, S. S.; Bera, M. K.; Kim, K.; Leahy, B.; Emrick, T.; Lee, K. Y. C.; Lin, B. H. Robust Gold Nanoparticle Sheets by Ligand Cross-Linking at the Air-Water Interface. ACS Nano 2017, 11 (2), 1292-1300. DOI: 10.1021/acsnano.6b05563
Chalarca, C. F. S.; Emrick, T., Reactive polymer zwitterions: Sulfonium sulfonates. Journal of Polymer Science Part A-Polymer Chemistry 2017, 55 (1), 83-92. DOI: 10.1002/pola.28359.
2016
Bai, Y.; Chang, C. C.; Choudhary, U.; Bolukbasi, I.; Crosby, A. J.; Emrick, T., Functional droplets that recognize, collect, and transport debris on surfaces. Science Advances 2016, 2 (10), e1601462. DOI: 10.1126/sciadv.1601462.
Bai, Y.; Chang, C. C.; Zhao, X. J.; Ribbe, A.; Bolukbasi, I.; Szyndler, M. J.; Crosby, A. J.; Emrick, T. Mechanical Restoration of Damaged Polymer Films by "Repair-and-Go". Advanced Functional Materials 2016, 26(6), 857-863. DOI: 10.1002/adfm.201503947
Chang, C. C.; Kolewe, K. W.; Li, Y. Y.; Kosif, I.; Freeman, B. D.; Carter, K. R.; Schiffman, J. D.; Emrick, T. Underwater Superoleophobic Surfaces Prepared from Polymer Zwitterion/Dopamine Composite Coatings. Advanced Materials Interfaces 2016, 3(6), Article 1500521, 9 pages. DOI: 10.1002/admi.201500521
Ghobadi, A. F.; Letteri, R.; Parelkar, S. S.; Zhao, Y.; Chan-Seng, D.; Emrick, T.; Jayaraman, A. Dispersing Zwitterions into Comb Polymers for Nonviral Transfection: Experiments and Molecular Simulation. Biomacromolecules 2016, 17(2), 546-557. DOI: 10.1021/acs.biomac.5b01462
Hu, G. J.; Emrick, T. Functional Choline Phosphate Polymers. Journal of the American Chemical Society 2016, 138 (6), 1828-1831. DOI: 10.1021/jacs.5b13156
Kolewe, K. W.; Dobosz, K. M.; Rieger, K. A.; Chang, C. C.; Emrick, T.; Schiffman, J. D., Antifouling Electrospun Nanofiber Mats Functionalized with Polymer Zwitterions. ACS Applied Materials & Interfaces 2016, 8 (41), 27585-27593. DOI: 10.1021/acsami.6b09839.
Lawrence, J.; Emrick, T. Pentafluorophenyl Ester-Functionalized Nanoparticles as a Versatile Platform for Selective and Covalent Inter-nanoparticle Coupling. ACS Applied Materials & Interfaces 2016, 8(3), 2393-2398. DOI: 10.1021/acsami.5b11550
Lee, H.; Stephenson, J. C.; Richter, L. J.; McNeill, C. R.; Gann, E.; Thomsen, L.; Park, S.; Jeong, J.; Yi, Y.; DeLongchamp, D. M.; Page, Z. A.; Puodziukynaite, E.; Emrick, T.; Briseno, A. L. The Structural Origin of Electron Injection Enhancements with Fulleropyrrolidine Interlayers. Advanced Materials Interfaces 2016, 3(10), Article 1500852, 7 pages. DOI: 10.1002/admi.201500852
Liu, Y.; Duzhko, V. V.; Page, Z. A.; Emrick, T.; Russell, T. P., Conjugated Polymer Zwitterions: Efficient Interlayer Materials in Organic Electronics. Accounts of Chemical Research 2016, 49 (11), 2478-2488. DOI: 10.1021/acs.accounts.6b00402.
Liu, Y.; Bag, M.; Renna, L. A.; Page, Z. A.; Kim, P.; Emrick, T.; Venkataraman, D.; Russell, T. P. Understanding Interface Engineering for High-Performance Fullerene/Perovskite Planar Heterojunction Solar Cells. Advanced Energy Materials 2016, 6(2), Article 1501606, 7 pages. DOI: 10.1002/aenm.201501606
Liu, Y.; Renna, L. A.; Page, Z. A.; Thompson, H. B.; Kim, P. Y.; Barnes, M. D.; Emrick, T.; Venkataraman, D.; Russell, T. P., A Polymer Hole Extraction Layer for Inverted Perovskite Solar Cells from Aqueous Solutions. Advanced Energy Materials 2016, 6 (20), 1600664. DOI: 10.1002/aenm.201600664.
Liu, Y.; Renna, L. A.; Bag, M.; Page, Z. A.; Kim, P.; Choi, J.; Emrick, T.; Venkataraman, D.; Russell, T. P. High Efficiency Tandem Thin-Perovskite/Polymer Solar Cells with a Graded Recombination Layer. ACS Applied Materials & Interfaces 2016, 8(11), 7070-7076. DOI: 10.1021/acsami.5b12740
Mir, A. A.; Wagner, S.; Kramer, R. H.; Deglmann, P.; Emrick, T. Deoxybenzoin-containing polysulfones and polysulfoxides: Synthesis and thermal properties. Polymer 2016, 84, 59-64. DOI: 10.1016/j.polymer.2015.12.031
Morozova, S.; Hu, G.; Emrick, T.; Muthukumar, M. Influence of Dipole Orientation on Solution Properties of Polyzwitterions. ACS Macro Letters 2016, 5(1), 118-122. DOI: 10.1021/acsmacrolett.5b00876
Page, Z. A.; Liu, Y.; Puodziukynaite, E.; Russell, T. P.; Emrick, T. Hydrophilic Conjugated Polymers Prepared by Aqueous Horner-Wadsworth-Emmons Coupling. Macromolecules 2016, 49(7), 2526-2532. DOI: 10.1021/acs.macromol.5b02501
Selhorst, R. C.; Puodziukynaite, E.; Dewey, J. A.; Wang, P.; Barnes, M. D.; Ramasubramaniam, A.; Emrick, T. Tetrathiafulvalene-containing polymers for simultaneous non-covalent modification and electronic modulation of MoS2nanomaterials. Chemical Science 2016, 7(7), 4698-4705. DOI: 10.1039/c6sc00305b
Skinner, M.; Selhorst, R.; Emrick, T. Synthesis of Water-Soluble Zwitterionic Polysiloxanes. Journal of Polymer Science Part A-Polymer Chemistry 2016, 54(1), 127-134. DOI: 10.1002/pola.27773
Wong, K. E.; Mora, M. C.; Skinner, M.; Page, S. M.; Crisi, G. M.; Arenas, R. B.; Schneider, S. S.; Emrick, T. Evaluation of PolyMPC-Dox Prodrugs in a Human Ovarian Tumor Model. Molecular Pharmaceutics 2016, 13(5), 1679-1687. DOI: 10.1021/acs.molpharmaceut.6b00092
2015
Chang, CC., Letteri, R., Hayward, RC., Emrick, T. “Functional sulfobetaine polymers: Synthesis and salt-responsive stabilization of oil-in-water droplets” Macromolecules, 2015, 48, 7843-7850. DOI: 10.1021/acs.macromol.5b01861
Chen, DY., Chang, CC., Cooper, B., Silvers, A., Emrick T., Hayward, RC. “Photopatternable biodegradable aliphatic polyester with pendent benzophenone groups” Biomacromolecules, 2015, 16, 3329-3335. DOI: 10.1021/acs.biomac.5b00991
Liu, YJ., Chen, YC., Hutchens, S., Lawrence, J., Emrick, T., Crosby, AJ. “Directly measuring the complete stress-strain response of ultrathin polymer films” Macromolecules, 2015, 48, 6534-6540. DOI: 10.1021/acs.macromol.5b01473
Liu, Y., Page, ZA., Russell, TP., Emrick, T. “Finely tuned polymer interlayers enhance solar cell efficiency” Angewandte Chemie-International Edition, 2015, 54, 11485-11489. DOI: 10.1002/anie.201503933
Kim, HJ., Skinner, M., Yu, H., Oh, JH., Briseno, AL., Emrick, T., Kim, BJ., Haryward, RC. “Water processable polythiophene nanowires by photo-cross-linking and click-functionalization” Nano Letters, 2015, 15, 5689-5695. DOI: 10.1021/acs.nanolett.5b01185
Liu, Y., Page, Z., Ferdous, S., Liu, F., Kim, P., Emrick, T., Russell, T. “Dual functional zwitterionic fullerene interlayer for efficient inverted polymer solar cells” Advanced Energy Materials, 2015, 5. DOI: 10.1002/aenm.201500405
Neto, MF., Letteri, R., Chan-Seng, D., Emrick, T., Figueiredo, ML. “Sonodelivery facilitates sustained luciferase expression from an episomal vector in skeletal muscle” Materials, 2015, 8, 4608-4617. DOI: 10.3390/ma8074608
Acevedo-Cartagena, DE., Zhu, JX., Trabanino, E., Pentzer, E., Emrick, T., Nonnenmann, SS., Briseno, AL., Hayward, RC. “Selective nucleation of poly(3-hexyl thiophene) nanofibers on multilayer graphene substrates” ACS Macro Letters, 2015, 4, 483-487. DOI: 10.1021/acsmacrolett.5b00038
Karak, S., Page, ZA., Tinkham, JS., Lahti, PM., Emrick, T., Duzhko, VV. “Raising efficiency of organic solar cells with electrotropic additives” Applied Physics Letters, 2015, 106. DOI: 10.1063/1.4914847
Page, ZA., Liu, F., Russell, TP., Emrick, T. “Tuning the energy gap of conjugated polymer zwitterions for efficient interlayers and solar cells” Journal of Polymer Science Part A-Polymer Chemistry, 2015, 53, 327-336. DOI: 10.1002/pola.27349
Lee, H., Puodziukynaite, E., Zhang, Y., Stephenson, JC., Richter, LJ., Fischer, DA., DeLongchamp, DM., Emrick, T., Briseno, AL. “Poly(sulfobetaine methacrylate)s as electrode modifiers for inverted organic electronics” Journal of the American Chemical Society, 2015, 137, 540-549. DOI: 10.1021/ja512148d
Hu, GJ., Parelkar, SS., Emrick, T. “A facile approach to hydrophilic, reverse zwitterionic, choline phosphate polymers” Polymer Chemistry, 2015, 6, 525-530. DOI: 10.1039/c4py01292e
2014
Baghgar, M., Barnes, A.M., Pentzer, E., Wise, A.J., Hammer, B.A.G., Emrick, T., Dinsmore, A.D. and Barnes, M.D. Morphology-Dependent Electronic Properties in Cross-Linked (P3HT-b-P3MT) Block Copolymer Nanostructures. ACS Nano, 2014, 8(8): 8344-8349. DOI: 10.1021/nn502806d
Carnis, J., Cha, W., Wingert, J., Kang, J., Jiang, Z., Song, S., Sikorski, M., Robert, A., Gutt, C., Chen, S.-W., Dai, Y., Ma, Y., Guo, H., Lurio, L.B., Shpyrko, O., Narayanan, S., Cui, M., Kosif, I., Emrick, T., Russell, T.P., Lee, H.C., Yu, C.-J., Gruebel, G., Sinha, S.K. and Kim, H. Demonstration of Feasibility of X-Ray Free Electron Laser Studies of Dynamics of Nanoparticles in Entangled Polymer Melts. Scientific Reports, 2014, 4. DOI: 10.1038/srep06017
Chang, C.-C. and Emrick, T. Functional Polyolefins Containing Disulfide and Phosphoester Groups: Synthesis and Orthogonal Degradation. Macromolecules, 2014, 47(4): 1344-1350. DOI: 10.1021/ma500121a
Chantarak, S., Liu, F., Emrick, T. and Russell, T.P. Solvent-Assisted Orientation of Poly(3-hexylthiophene)-Functionalized CdSe Nanorods Under an Electric Field. Macromolecular Chemistry and Physics, 2014, 215(17): 1647-1653. DOI: 10.1002/macp.201400188
Ellis, J., Falzon, M., Emrick, T. and Figueiredo, M.L. Imaging Cytokine Targeting to the Tumor/Bone Microenvironment In Vivo. Human Gene Therapy Clinical Development, 2014, 25(4): 200-201.
DOI: 10.1089/humc.2014.085
Hammer, B.A.G., Reyes-Martinez, M.A., Bokel, F.A., Liu, F., Russell, T.P., Hayward, R.C., Briseno, A.L. and Emrick, T. Reversible, Self Cross-Linking Nanowires from Thiol-Functionalized Polythiophene Diblock Copolymers. ACS Applied Materials & Interfaces, 2014, 6(10): 7705-7711. DOI: 10.1021/am500976w
Hammer, B.A.G., Reyes-Martinez, M.A., Bokel, F.A., Liu, F., Russell, T.P., Hayward, R.C., Briseno, A.L. and Emrick, T. Robust polythiophene nanowires cross-linked with functional fullerenes. Journal of Materials Chemistry C, 2014, 2(45): 9674-9682. DOI: 10.1039/c4tc01898b
Kosif, I., Chang, C.C., Bai, Y., Ribbe, A.E., Balazs, A.C. and Emrick, T. Picking up Nanoparticles with Functional Droplets. Advanced Materials Interfaces, 2014, 1(5). DOI: 10.1002/admi.201400121
Lawrence, J., Pham, J.T., Lee, D.Y., Liu, Y., Crosby, A.J. and Emrick, T. Highly conductive ribbons prepared by stick-slip assembly of organosoluble gold nanoparticles. ACS Nano, 2014, 8(2), 1173-1179. DOI: 10.1021/nn4057726.
Lee, C.H., Crosby, A.J., Emrick, T. and Hayward, R.C. Characterization of heterogeneous polyacrylamide hydrogels by tracking of single quantum dots. Macromolecules, 2014, 47(2), 741-749. DOI: 10.1021/ma402373s.
Lee, C.H., Crosby, A.J., Hayward, R.C. and Emrick, T. Patterning nanoparticles into rings by "2-D pickering emulsions". ACS Applied Materials & Interfaces, 2014, 6(7), 4850-4855. DOI: 10.1021/am405828a.
Maiz, J., Zhao, W., Gu, Y., Lawrence, J., Arbe, A., Alegria, A., Emrick, T., Colmenero, J., Russell, T.P. and Mijangos, C. Dynamic study of polystyrene-block-poly(4-vinylpyridine) copolymer in bulk and confined in cylindrical nanopores. Polymer, 2014, 55(16): 4057-4066. DOI: 10.1016/j.polymer.2014.05.042
McRae Page, S., Henchey, E., Chen, X., Schneider, S. and Emrick, T. Efficacy of polyMPC-DOX prodrugs in 4T1 tumor-bearing mice. Molecular Pharmaceutics, 2014, 11(5): 1715-1720. DOI: 10.1021/mp500009r
Miesch, C. and Emrick, T. Photo-sensitive ligands on nanoparticles for achieving triggered emulsion inversion. Journal of Colloid and Interface Science, 2014, 425: 152-158. DOI: 10.1016/j.jcis.2014.03.036
Page, S.M., Henchey, E., Chen, X., Schneider, S. and Emrick, T. Efficacy of PolyMPC-DOX Prodrugs in 4T1 Tumor-Bearing Mice. Molecular Pharmaceutics, 2014, 11(5): 1715-1720. DOI: 10.1021/mp500009r
Page, S.M., Parelkar, S., Gerasimenko, A., Shin, D.Y., Peyton, S.R. and Emrick, T. Promoting cell adhesion on slippery phosphorylcholine hydrogel surfaces. Journal of Materials Chemistry B, 2014, 2(6), 620-624. DOI: 10.1039/c3tb21493a.
Page, Z.A., Liu, Y., Duzhko, V.V., Russell, T.P. and Emrick, T. Fulleropyrrolidine interlayers: Tailoring electrodes to raise organic solar cell efficiency. Science, 2014, 346(6208): 441-444. DOI: 10.1126/science.1255826
Page, Z.A., Liu, F., Russell, T.P. and Emrick, T. Rapid, facile synthesis of conjugated polymer zwitterions in ionic liquids. Chemical Science, 2014, 5(6): 2368-2373. DOI: 10.1039/c4sc00475b
Parelkar, S.S., Letteri, R., Chan-Seng, D., Zolochevska, O., Ellis, J., Figueiredo, M. and Emrick, T. Polymer-peptide delivery platforms: Effect of oligopeptide orientation on polymer-based DNA delivery. Biomacromolecules, 2014, 15(4), 1328-1336. DOI: 10.1021/bm401878p.
Pham, J.T., Lawrence, J., Grason, G.M., Emrick, T. and Crosby, A.J. Stretching of assembled nanoparticle helical springs. Physical Chemistry Chemical Physics, 2014, 16(22): 10261-10266. DOI: 10.1039/c3cp55502j
Puodziukynaite, E., Wang, H.-W., Lawrence, J., Wise, A.J., Russell, T.P., Barnes, M.D. and Emrick, T. Azulene Methacrylate Polymers: Synthesis, Electronic Properties, and Solar Cell Fabrication. Journal of the American Chemical Society, 2014, 136(31): 11043-11049. DOI: 10.1021/ja504670k
Szyndler, M.W., Timmons, J.C., Yang, Z.H., Lesser, A.J. and Emrick, T. Multifunctional deoxybenzoin-based epoxies: Synthesis, mechanical properties, and thermal evaluation. Polymer, 2014, 55(17): 4441-4446. DOI: 10.1016/j.polymer.2014.06.043
Wang, H.-W., Pentzer, E., Emrick, T. and Russell, T.P. Preparation of low band gap fibrillar structures by solvent-induced crystallization. ACS Macro Letters, 2014, 3(1), 30-34. DOI: 10.1021/mz400431s.
Zhang, Y., Diao, Y., Lee, H., Mirabito, T.J., Johnson, R.W., Puodziukynaite, E., John, J., Carter, K.R., Emrick, T., Mannsfed, S.C.B. and Briseno, A.L. Intrinsic and Extrinsic Parameters for Controlling the Growth of Organic Single-Crystalline Nanopillars in Photovoltaics. Nano Letters, 2014, 14(10): 5547-5554. DOI: 10.1021/nl501933q
2013
Emrick, T. and Pentzer, E. Nanoscale assembly into extended and continuous structures and hybrid materials. Nature Asia Materials, 2013, 5. DOI: 10.1038/am.2012.73
Zolochevska, O., Ellis, J., Parelkar, S., Chan-Seng, D., Emrick, T., Wei, JN., Patrikeev, I., Motamedi, M., Figueiredo, ML. “Interleukin-27 gene delivery for modifying malignant interactions between prostate tumor and bone” Human Gene Therapy, 2013, 24, 970-981. DOI: 10.1089/hum.2013.091
Pham, JT., Lawrence, J., Lee, DY., Grason, GM., Emrick, T., Crosby, AJ. “Highly stretchable nanoparticle helices through geometric asymmetry and surface forces” Advanced Materials, 2013, 25, 6703-6708. DOI: 10.1002/adma.201302817
Liu, F., Page, ZA., Duzhko, VV., Russell, TP., Emrick, T. “Conjugated polymeric zwitterions as efficient interlayers in organic solar cells” Advanced Materials, 2013, 25, 6868-6873. DOI: 10.1002/adma.201302477
Pham, JT., Lawrence, J., Lee, DY., Grason, GM., Emrick, T., Crosby, AJ. “Nanoparticle helices: Highly stretchable nanoparticle helices through geometric asymmetry and surface forces” Advanced Materials, 2013, 25, 6635. DOI: 10.1002/adma.201370287
Du, K., Glogowski, E., Tuominen, MT., Emrick, T., Russell, TP., Dinsmore, AD. “Self-assembly of gold nanoparticles on gallium droplets: controlling charge transport through microscopic devices” Langmuir, 2013, 29, 13640-13646. DOI: 10.1021/la403263z
Heo, K., Miesch, C., Emrick, T., Hayward, RC. “Thermally reversible aggregation of gold nanoparticles in polymer nanocomposites through hydrogen bonding” Nano Letters, 2013, 13, 5297-5302. DOI: 10.1021/nl402813q
Cui, MM., Emrick T., Russell, TP. “Stabilizing liquid drops in nonequilibrium shapes by the iinterfacial jamming of nanoparticles” Science, 2013, 342, 460-463. DOI: 10.1126/science.1242852
Baghgar, M., Pentzer, E., Wise, AJ., Labastide, JA., Emrick, T., Barnes, MD. “Cross-linked functionalized poly(3-hexylthiophehe) nanofibers with tunable excitonic coupling” ACS Nano, 2013, 7, 8917-8923. DOI: 10.1021/nn403392b
Herrick, WG., Ngyuen, TV., Sleiman, M., McRae, S., Emrick, TS. “PEG-phosphorylcholine hydrogels as tunable and versatile platforms for mechanobiology” Biomacromolecules, 2013, 14, 2294-2304. DOI: 10.1021/bm400418g
Page, SM., Martorella, M., Parelkar, S., Kosif, I., Emrick, T. “Disulfide cross-linked phosphorylcholine micelles for triggered release of camptothecin” Molecular Pharmaceutics, 2013, 10, 2684-2692. DOI: 10.1021/mp400114n
Han, DZ., Letteri, R., Chan-Seng, D., Emrick, T., Tu, HL. “Examination of zwitterionic polymers and gels subjected to mechanical constraints” Polymer, 2013, 54, 2887-2894. DOI: 10.1016/j.polymer.2013.04.003
Moon, S., Emrick, T. “High flame resistant and strong electrospun polyacrylonitrile-carbon nanotubes-ochre nanofibers” Polymer, 2013, 54, 1813-1819. DOI: 10.1016/j.polymer.2013.01.053
Lee, DY., Pham, JT., Lawrence, J., Lee, CH., Parkos, C., Emrick, T., Crosby, AJ. “Macroscopic nanoparticle ribbons and fabrics” Advanced Materials, 2013, 9, 1248-1253. DOI: 10.1002/adma.201203719
Laprade, EJ., Long, R., Pham, JT., Lawrence, J., Emrick, T., Crosby, AJ., Hui, CY., Shull, KR. “Large deformation and adhesive contact studies of axisymmetric membranes” Langmur, 2013, 5, 1407-1419. DOI: 10.1021/la303810d
Page, ZA., Duzhko, VV., Emrick, T. “Conjugated thiophene-containing polymer zwitterions: Direct synthesis and thin film electronic properties” Macromolecules, 2013, 2, 344-351. DOI: 10.1021/ma302232q
Chen, XJ., Lawrence, J., Parelkar, S., Emrick, T. “Novel zwitterionic copolymers with dihydrolipoic acid: Synthesis and preparation of nonfouling nanorods” Macromolecules, 2013, 1, 119-127. DOI: 10.1021/ma301288m
Kosif, I., Cui, MM., Russell, TP., Emrick, T. “Triggered insitu disruption and inversion of nanoparticle-stabilized droplets” Angewandte Chemie-International Edition, 2013, 52, 6620-6623. DOI: 10.1002/anie.201302112
2012
Bu, L., Pentzer, E., Bokel, F., Emrick, T., Hayward, R. “Growth of polythiophene/perylene tetracarboxydiimide donor/acceptor shish-kebab nanostructures by coupled crystal modification” ACS Nano, 2012, 6, 10924-10929. DOI: 10.1021/nn3043836
Chen, XJ., Parelkar, S., Henchey, E., Schneider, S., Emrick, T. “PolyMPC-doxorubicin prodrugs” Bioconjugate Chemistry, 2012, 23, 1753-1763. DOI: 10.1021/bc200667s
Silvers, A., Chang, CC., Emrick, T. “Functional aliphatic polyesters and nanoparticles prepared by organocatalysis and orthogonal grafting chemistry” Journal of Polymer Science Part A – Polymer Chemistry, 2012, 50, 3517-3529. DOI: 10.1002/pola.26114
Mcrae, S, Chen, XJ., Kratz, K., Samanta, D., Henchey, E., Schneider, S., Emrick, T. “Pentafluorophenyl ester-functionalized phosphorylcholine polymers: Preparation of linear, two-arm, and grafted polymer-protein conjugates” Biomacromolecules, 2012, 13, 2099-2109. DOI: 10.1021/bm3004836
Baghgar, M., Labastide, J., Bokel, F., Dujovne, I., McKenna, A., Barnes, AM., Pentzer, E., Emrick, T., Hayward, R., Barnes, MD. “Probing inter- and intrachain exciton coupling in isolated poly(3-hexylthiophene) nanofibers: Effect of solvation and regioregularity” Journal of Physical Chemistry Letters, 2012, 3, 1674-1679. DOI: 10.1021/jz3005909
Bae, J., Lawrence, J., Miesch, C., Ribbe, A., Li, W., Emrick, T., Zhu, J., Hayward, RC. “Multifunctional nanoparticle-loaded spherical and wormlike micelles formed by interfacial instabilities” Advanced Materials, 2012, 24, 2735-2741. DOI: 10.1002/adma.201200570
Pentzer, EB., Bokel, FA., Hayward, RC., Emrick, T. “Nanocomposite ‘superhighways’ by solution assembly of semiconductor nanostructures with ligand-functionalized conjugated polymers” Advanced Materials, 2012, 24, 2254-2258. DOI: 10.1002/adma.201104788
Kratz, K., Narasimhan, A., Tangirala, R., Moon, SC., Revanu, R., Kundu, S., Kim, HS.,Crosby, AJ., Russell, TP., Emrick, T., Kolmakov, G., Balazs, AC. “Probing and repairing damaged surfaces with nanoparticle-containing microcapsules” Nature Nanotechnology, 2012, 7, 87-90. DOI: 10.1038/NNANO.2011.235
Ravichandran, S., Nagarajan, S., Ku, BC., Coughlin, B., Emrick, T., Kumar, J., Nagarajan, R. “Halogen-free ultra-high flame retardant polymers through enzyme catalysis” Green Chemistry, 2012, 14, 819-824. DOI: 10.1039/c2gc16192c
Miesch, C., Kosif, I., Lee, E., Kim, JK., Russell, TP., Hayward, RC., Emrick, T. “Nanoparticle-stabilized double emulsions and compressed droplets” Angewandte Chemie-International Edition, 2012, 51, 145-149. DOI: 10.1002/anie.201106665
2011
Kratz, K., Xie, W., Lee, A., Freeman, BD., Emrick, T. “Phosphorylcholine-substituted ROMP polyolefin coatings provide fouling resistance to membrane materials” Macromolecular Materials and Engineering, 2011, 296, 1142-1148. DOI: 10.1002/mame.201100064
Elder, RM., Emrick, T., Jayaraman, A. “Understanding the effect of polylysine architecture on DNA binding using molecular dynamics simulations” Biomacromolecules, 2011, 12, 3870-3879. DOI: 10.1021/bm201113y
Hammer, BAG., Bokel, FA., Hayward, RC., Emrick, T. “Cross-linked conjugated polymer fibrils: Robust nanowires from functional polythiophene diblock copolymers” Chemistry of Materials, 2011, 23, 4250-4256. DOI: 10.1021/cm2018345
Ryu, BY., Emrick, T. “Bisphenol-1,2,3-triazole (BPT) epoxies and cyanate esters: Synthesis and self-catalyzed curing” Macromolecules, 2011, 44, 5693-5700. DOI: 10.1021/ma200767j
Lee, E., Hammer, B., Kim, JK., Page, Z., Emrick, T., Hayward, RC. “Hierarchical helical sssembly of conjugated poly(3-hexylthiophene)-block-poly(3-triethylene glycol thiophene) diblock copolymers” Journal of the American Chemical Society, 2011, 133, 10390-10393. DOI: 10.1021/ja2038547
Su, GM., Best, K., Ranganathan, T., Emrick, T., Crosby, AJ. “Tailored nanoparticles for enhancing polymer adhesion” Macromolecules, 2011, 44, 5256-5261. DOI: 10.1021/ma200561g
Li, L., Miesch, C., Sudeep, PK., Balazs, AC., Emrick, T., Russell, TP., Hayward, RC. “Kinetically trapped co-continuous polymer morphologies through intraphase gelation of nanoparticles” Nano Letters, 2011, 11, 1997-2003. DOI: 10.1021/nl200366z
Bokel, FA., Sudeep, PK., Pentzer, E., Emrick, T., Hayward, RC. “Assembly of poly(3-hexylthiophene)/CdSe hybrid nanowires by cocrystallization” Macromolecules, 2011, 44, 1768-1770. DOI: 10.1021/ma2003807
Parelkar, SS., Chan-Seng, D, Emrick, T. “Reconfiguring polylysine architectures for controlling polyplex binding and non-viral transfection” Biomaterials, 2011, 32, 2432-2444. DOI: 10.1016/j.biomaterials.2010.12.004
Pochan, DJ., Zhu, JH., Zhang, K., Wooley, KL., Miesch, C., Emrick, T. “Multicompartment and multigeometry nanoparticle assembly” Soft Matter, 2011, 7, 2500-2506. DOI: 10.1039/c0sm00960a
2010
Kim, HS., Lee, CH., Sudeep, PK., Emrick, T., Crosby, A. “Nanoparticle stripes, grids, and ribbons produced by flow coating” Advanced Materials, 2010, 22, 4600-4604. DOI: 10.1002/adma.201001892
Hu, Y., Samanta, D., Parelkar, S., Hong, SW., Wang, Q., Russell, T., Emrick, T. “Ferritin-polymer conjugates: Grafting chemistry and integration into nanoscale assemblies.” Advanced Function Materials, 2010, 20, 3603-3612. DOI: 10.1002/adfm.201000958
Ryu, BY., Emrick, T. “Thermally induced structural transformation of bisphenol-1,2,3-triazole polymers: Smart, self-extinguishing materials” Angewandte Chemie-International Edition, 2010, 49, 9644-9647. DOI: 10.1002/anie.201005456
Chen, XJ., McRae, S., Samanta, D., Emrick, T. “Polymer-protein conjugation in ionic liquids” Macromolecules, 2010, 43, 6261-6263. DOI: 10.1021/ma101156e
Du, K., Glogowski, E., Emrick, T., Russell, TP., Dinsmore, AD. “Adsorption energy of nano- and microparticles at liquid-liquid interfaces” Langmuir, 2010, 26, 12518-12522. DOI: 10.1021/la100497h
Hu YX., Chen, DA., Park, S., Emrick, T., Russell, TP. “Guided assemblies of ferritin nanocages: Highly ordered arrays of monodisperse nanoscopic elements” Advanced Materials, 2010, 22, 2583-2587. DOI: 10.1002/adma.200903578
Early, KT., Sudeep, PK., Emrick, T., Barnes, MD. “Polarization-driven stark shifts in quantum dot luminescence from single CdSe/oligo-PPV nanoparticles” Nano Letters, 2010, 10, 1754-1758. DOI: 10.1021/nl1001789
Ranganathan, T., Cossette, P., Emrick, T. “Halogen-free, low flammability polyurethanes derived from deoxybenzoin-based monomers” Journal of Materials Chemistry, 2010, 20, 3681-3687. DOI: 10.1039/b924034a
Lee, JU., Jung, JW., Emrick, T., Russell, TP., Jo, WH. “Synthesis of C-60-end capped P3HT and its application for high performance of P3HT/PCBM bulk heterojunction solar cells” Journal of Materials Chemistry, 2010, 20, 3287-3294. DOI: 10.1039/b923752f
Joralemon, MJ., Mcrae, S., Emrick, T. “PEGylated polymers for medicine: From conjugation to self-assembled systems” Chemical Communications, 2010, 46, 1377-1393. DOI: 10.1039/b920570p
Lee, JU., Jung, JW., Emrick, T., Russell, TP., Jo, WH. “Morphology control of a polythiophene-fullerene bulk heterojunction for enhancement of the high-temperature stability of solar cell performance by a new donor-acceptor diblock copolymer” Nanotechnology, 2010, 21. DOI: 10.1088/0957-4484/21/10/105201
Kolmakov, GV., Revanur, R., Tangirala, R., Emrick, T., Russell, TP., Crosby, AJ., Balazs, AC. “Using nanoparticle-filled microcapsules for site-specific healing of damaged substrates: Creating a "repair-and-go" system” ACS Nano, 2010, 4, 1115-1123. DOI: 10.1021/nn901296y
2009
Niu, ZW., Kabispatpathy, S., He, JB., Lee, LA., Rong, JH., Yang, L., Sikha, G., Popov, BN., Emrick, TS., Russell, TP., Wang, Q. “Synthesis and characterization of bionanoparticle-silica composites and mesoporous silica with large pores” Nano Research, 2009, 2, 474-485. DOI: 10.1007/s12274-009-9043-6
Sudeep, PK., Emrick, T. “Functional Si and CdSe quantum dots: Synthesis, conjugate formation, and photoluminescence” ACS Nano, 2009, 3, 4105-4109. DOI: 10.1021/nn901016u
Chen, XJ., McRae, S., Parelkar, S., Emrick, T. “Polymeric phosphorylcholine-camptothecin conjugates prepared by controlled free radical polymerization and click chemistry” Bioconjugate Chemistry, 2009, 20, 2331-2341. DOI: 10.1021/bc900339x
Cooper, BM., Emrick, T. “Sequential and localized grafting on aliphatic polyester diblock copolymers using alkyne deprotection and click cycladdition” Journal of Polymer Science Part A – Polymer Chemistry, 2009, 47, 7054-7065. DOI: 10.1002/pola.23745
Sudeep, PK., Emrick, T. “Pearls of wisdom: Stringing nanoparticles and polymers into new assemblies and materials” ACS Nano, 2009, 3, 2870-2875. DOI: 10.1021/nn901358a
Du, K., Knutson, CR., Glogowski, E., McCarthy, KD., Shenhar, R., Rotello, VM., Tuominen, MT., Emrick, T., Russell, TP., Dinsmore, AD. “Self-assembled electrical contact to nanoparticles using metallic droplets” Small, 2009, 5, 1974-1977. DOI: 10.1002/smll.200900203
Chan-Seng, D., Ranganathan, T., Zhang, XF., Tang, YW., Lin, Q.; Kleiner, L., Emrick, T. “Aliphatic polyester terpolymers for stent coating and drug elution: Effect of polymer composition on drug solubility and release” Drug Delivery, 2009, 16, 304-311. DOI: 10.1080/10717540902999653
Doi, MY., Early, KT., Tangirala, R., Sudeep, PK., Emrick, T., Barnes, MD. “Probing multiexcitonic emission in single CdSe-Oligo(phenylenevinylene) composite nanostructures” Journal of Physical Chemistry, 2009, 113, 13462-13465. DOI: 10.1021/jp9051787
Kratz, K., Breitenkamp, K., Hule, R., Pochan, D., Emrick, T. "PC-Polyolefins: Synthesis and assembly behavior in water" Macromolecules, 2009, 42, 3227-3229. DOI: 10.1021/ma900653h
He, JB., Niu, ZW., Tangirala, R., Wan, JY., Wei, XY., Kaur, G., Wang, Q., Jutz, G., Boeker, A., Lee, B., Pingali, SV., Thiyagaran, P., Emrick, T., Russell, TP. "Self-assembly of tobacco mosaic virus at oil/water interfaces" Langmuir, 2009, 25, 4979-4987. DOI: 10.1021/la803533n
Kaur, G., He, JB., Xu, J., Pingali, SV., Jutz, G., Boker, A., Niu, ZW., Li, T., Rawlinson, D., Emrick, T., Lee, B., Thiyagarajan, P., Russell, TP., Wang, Q. "Interfacial assembly of turnip yellow mosaic virus nanoparticles" Langmuir, 2009, 25, 5168-5176. DOI: 10.1021/la900167s
Tangirala, R., Hu YX., Joralemon, M., Zhang, QL., He, JB., Russell, TP., Emrick, T. "Connecting quantum dots and bionanoparticles in hybrid nanoscale ultra-thin films" Soft Matter, 2009, 5, 1048-1054. DOI: 10.1039/b807757f
Chen, D., Chen, JT., Glogowski, E., Emrick, T., Russell, TP. "Thin film instabilities in blends under cylindrical confinement" Macromolecular Rapid Communications, 2009, 30, 377-383. DOI: 10.1002/marc.200800730
Lee, JU., Cirpan, A., Emrick, T., Russell, TP., Jo, WH. "Synthesis and photophysical property of well-defined donor-acceptor diblock copolymers based on regioregular poly(3-hexythiophene) and fullerene" Journal of Materials Chemistry, 2009, 19, 1483-1489. DOI: 10.1039/b813368a
Early, KT., McCarthy, KD., Odoi MY., Sudeep, PK., Emrick, T., Barnes, MD. "Linear dipole behavior in single CdSe-Oligo(phenylene vinylene) nanostructures" ACS Nano, 2009, 3, 453-461. DOI: 10.1021/nn800785s
Zhang, QL., Cirpan, A., Russell, TP., Emrick, T. "Donor-acceptor poly(thiophene-block-perylene diimide) copolymers: Synthesis and solar cell fabrication" Macromolecules, 2009, 42, 1079-1082. DOI: 10.1021/ma801504e
Ryu, BY., Moon, S., Kosif, I., Ranganathan, T., Farris, RJ., Emrick, T. "Deoxybenzoin-based epoxy resins" Polymer, 2009, 50, 767-774. DOI: 10.1016/j.polymer.2008.12.009
Cooper, BM., Chan-Seng, D., Samanta, D., Zhang, XF., Parelkar, S., Emrick, T. “Polyester-graft-phosphorylcholine prepared by ring-opening polymerization and click chemistry” Chem. Commun. 2009, 7, 815-817. DOI: 10.1039/b817600k
Moon, S., Ku, B.C., Emrick, T., Coughlin, BE., Farris, RJ. “Flame resistant electrospun polymer nanofibers from deoxybenzoin” Journal of Applied Polymer Science, 2009, 111, 301-307. DOI: 10.1002/app.29067
2008
Sudeep, PK., Page, Z., Emrick, T. “PEGylated silicon nanoparticles: Synthesis and characterization” Chemical Communications, 2008, 46, 6126-6127. DOI: 10.1039/b813025f
Li, T., Niu, Z., Emrick, T., Russell TR., Wang, Q. “Core/Shell biocomposites from the hierarchical assembly of bionanoparticles and polymer” Small, 2008, 4, 1624-1629. DOI: 10.1002/smll.200800403
Samanta, D., McRae, S., Cooper, B., Hu, Y., Emrick, T. “End-functionalized phosphorylcholine methacrylates and their use in protein conjugation” Biomacromolecules, 2008, 9, 2891-2897. DOI: 10.1021/bm8006715
Breitenkamp, RB., Emrick, T. “Pentalysine-grafted ROMP polymers for DNA complexation and delivery” Biomacromolecules, 2008, 9, 2495-2500. DOI: 10.1021/bm800511p
Mark, P.R.; Murthy, N.S.; Weigand, S.; Breitenkamp, K.; Kade, M.; Emrick, T. “Microphase separated structures in the solid and molten states of double-crystal graft copolymers of polyethylene and poly(ethylene oxide)” Polymer, 2008, 49, 3116-3124. DOI: 10.1016/j.polymer.2008.05.012
Lyon, R.E.; Emrick, T. “Non-halogen fire resistant plastics for aircraft interiors” Polymers for Advanced Technologies, 2008, 19, 609-619. DOI: 10.1002/pat.1126
Ranganathan, T.; Beaulieu, M.; Ziberman, J.; Smith, K.D.; Westmoreland, P.R.; Farris, R.J.; Coughlin, E.B.; Emrick, T. “Thermal degradation of deoxybenzoin polymers studied by pyrolysis-gas chromatography/mass spectrometry” Polymer Degradation and Stability, 2008, 93, 1059-1066. DOI: 10.1016/j.polymdegradstab.2008.03.021
Li, Q.F; He, J.B.; Glogowski, E.; Li, X.F.; Wang, J.; Emrick, T.; Russell, T.P. “Responsive assemblies: Gold nanoparticles with mixed ligands in microphase separated block copolymers” Advanced Materials 2008, 20, 1462-1466. DOI: 10.1002/adma.200702004
Rathnayake, H.P.; Emrick, T. “Grafting-from nanoparticles using aldol group transfer polymerization” Macromolecules 2008, 41, 2969-2971. DOI: 10.1021/ma800571c
Bae, J.; Glogowski, E.; Gupta, S.; Chen, W.; Emrick, T.; Russell, T.P. “Effect of nanoparticles on the electrohydrodynamic instabilities of polymer/nanoparticle thin films” Macromolecules 2008, 41, 2722-2726. DOI: 10.1021/ma702750y
Bruckman, M.A.; Kaur, G.; Lee, L.A.; Xie, F.; Sepulvecla, J.; Breitenkamp, R.; Zhang, X.; Joralemon, M.; Russell, T.P; Emrick, T.; Wang, Q. “Surface modification of tobacco mosaic virus with “Click” chemistry” Chembiochem 2008, 9, 519-523. DOI: 10.1002/cbic.200700559
Sudeep, P.K.; Early, K.T.; McCarthy, K.D.; Odoi, M.Y.; Barnes, M.D.; Emrick, T. “Monodisperse oligo(phenylene vinylene) ligands on CdSe quantum dots: Synthesis and polarization anisotropy measurements” J. Am. Chem. Soc. 2008, 130, 2384-2385. DOI: 10.1021/ja077409
Samanta, D.; Kratz, K.; Zhang, X.; Emrick, T. “A synthesis of PEG- and phosphorylcholine-substituted pyridines to afford water-soluble ruthenium benzylidene metathesis catalysts” Macromolecules 2008, 41, 530-532. DOI: 0.1021/ma7019732
2007
Hammer, N.I.; Emrick, T.; Barnes, M.D. “Quantum dots coordinated with conjugated organic ligands: new nanomaterials with novel photophysics” Nanoscale Research Letters 2007, 2, 282-290. DOI: 10.1007/s11671-007-9062-8
Odoi, M.Y.; Hammer, N.I.; Early, K.T.; McCarthy, K.D.; Tangirala, R.; Emrick, T.; Barnes, MD. “Fluorescence lifetimes and correlated photon statistics from single CdSe/oligo(phenylene vinylene) composite nanostructures” NanoLetters 2007, 7, 2769-2773. DOI: 10.1021/nl0713068
Early, KT.; McCarthy, KD.; Hammer, NI.; Odoi, MY.; Tangirala, R.; Emrick, T.; Barnes, MD. “Blinking suppression and intensity recurrences in single CdSe-oligo(phenylene vinylene) nanostructures: experiment and kinetic model” Nanotechnology 2007, 18. DOI: 10.1088/0957-4484/18/42/424027
Breitenkamp, R.B.; Ou, Z.; Breitenkamp, K.; Muthukumar, M.; Emrick, T. “Synthesis and Characterization of polyolefin-graft-oligopeptide polyelectrolytes” Macromolecules 2007, 40, 7617-7624. DOI: 10.1021/ma070714v
Boker, A.; He, J.; Emrick, T.; Russell, TP. “Self-assembly of nanoparticles at interfaces” Soft Matter 2007, 3, 1231-1248. DOI: 10.1039/b706609k
Kutuzov, S.; He, J.; Tangirala, R.; Emrick, T.; Russell, TP.; Boker, A. “On the kinetics of nanoparticle self-assembly at liquid/liquid interfaces“ Physical Chemistry Chemical Physics 2007, 9, 6351-6358. DOI: 10.1039/b710060b
Ranganathan, T.; Ku, B.C.; Zilberman, J.; Beaulieu, M.; Farris, R.J.; Coughlin, E.B.; Emrick, T. “Poly(arylate-phosphonate) copolymers with deoxybenzoin in the backbone: synthesis, characterization, and thermal properties” J. Polym. Sci. A.: Polym. Chem. 2007, 45, 4573-4580. DOI: 10.1002/pola.22188
Sudeep, PK; Emrick, T. “Polymer-nanoparticle composites: Preparative methods and electronically active materials” Polymer Reviews 2007, 47, 155-163. DOI: 10.1080/15583720701271229
Huang, J; Juskiewicz, M; de Jeu, WH; Cerda, E; Emrick, T; Menon, N; Russell, TP. “Capillary wrinkling of floating thin polymer films” Science 2007, 317, 650-653. DOI: 10.1126/science.1144616
He, J; Zhang, Q; Gupta, S; Emrick, T; Russell, TR; Thiyagarajan, P. “Drying Droplets: A window into the behavior of nanorods at interfaces” Small, 2007, 3, 1214-1217. DOI: 10.1002/smll.200700055
Lee, JY; Zhang, Q.; Wang, JY; Emrick T; Crosby, A.J. “Failure mechanism of glassy polymer-nanoparticle composites” Macromolecules, 2007, 40, 6406-6412. DOI: 10.1021/ma0710479
Zhang, Q.; Russell, T.P.; Emrick, T. “Synthesis and Characterization of CdSe Nanorods Functionalized with Regioregular Poly(3-hexylthiophene)’ Chem. Mater., 2007, 19, 3712-3716. DOI: 10.1021/cm070603a
Revanur, R.; McCloskey, B.; Breitenkamp, K.; Freeman, B.D.; Emrick, T. “Reactive amphiphilic graft copolymer coatings applied to poly(vinylidene fluoride) ultrafiltration membranes,” Macromolecules, 2007, 40, 3624-3630. DOI: 10.1021/ma0701033
Glogowski, E.; Tangirala, R.; He, J.B.; Russell, T.P.; Emrick, T. “Microcapsules of PEGylated gold nanoparticles prepared by fluid-fluid interfacial assembly,” NanoLetters, 2007, 7, 389-393. DOI: 10.1021/nl062581h
He, J.B.; Tangirala, R.; Emrick, T.; Russell, T.P. “Self-assembly of nanoparticle-copolymer mixtures: A kinetic point of view,” Advanced Materials, 2007 19, 381-386. DOI: 10.1002/adma.200602094
Zou, S.; Hong, R.; Emrick, T.; Walker, G. “Ordered CdSe nanoparticles within self-assembled block copolymer domains on surfaces,” Langmuir, 2007, 23, 1612-1614. DOI: 10.1021/la0629274
Tangirala R.; Revanur R.; Russell T.P.; Emrick T. “Sizing nanoparticle-covered droplets by extrusion through track-etch membranes,” Langmuir, 2007, 23, 965-969. DOI: 10.1021/la061575y
Parrish B.; Emrick T. “Soluble camptothecin derivatives prepared by click cycloaddition chemistry on functional aliphatic polyesters,” Bioconjugate Chemistry, 2007, 18, 263-267. DOI: 10.1021/bc060201d
Hammer, NI., Emrick, T., Barnes, MD. “Quantum dots coordinated with conjugated organic ligands: new nanomaterials with novel photophysics” Nanoscale Research Letters, 2007, 2, 282-290. DOI: 10.1007/s11671-007-9062-8
2006
Hong, R; Fernandez, J.M; Nakade, H; Emrick, T; “In situ observation of place exchange reactions of gold nanoparticles: Correlation of monolayer structure and stability”, Chemical Communications, 2006, 22: 2347-2349. DOI: 10.1039/b603988j
Balazs, A.C.; Emrick, T.; Russell, T.P. “Nanoparticle-polymer Composites: Where Two Small Worlds Meet” Science, 2006, 314, 1107-1110. DOI: 10.1126/science.1130557
Zhang, Q.L.; Gupta, S.; Emrick, T.; Russell, T.P. “Surface-functionalized CdSe nanorods for assembly in diblock copolymer templates,” J. Am. Chem. Soc. 2006, 128, 3898-3899. DOI: 10.1021/ja058615p
Gupta, S; Zhang, Q.L.; Emrick, T.; Russell, T.P. “Self-corralling" nanorods under an applied electric field” NanoLetters 2006, 6, 2066-2069. DOI: 10.1021/nl061336v
Ranganathan T., Zilberman J., Farris R.J., Coughlin E.B., Emrick T. “Synthesis and characterization of halogen-free antiflammable polyphosphonates containing 4,4'-bishydroxydeoxybenzoin”, Macromolecules 2006, 39, 5974-5975. DOI: 10.1021/ma0614693
Jordan B.J., Hong R., Gider B., Hill J., Emrick T., Rotello, V.M. “Stabilization of alpha-chymotrypsin at air-water interface through surface binding to gold nanoparticle scaffolds” Soft Matter 2 (7): 558-560 2006 DOI: 10.1039/b603980d
Glogowski E., Tangirala R., Russell T.P., Emrick T. “Functionalization of nanoparticles for dispersion in polymers and assembly in fluids” J. Polym. Sci. A: Polym. Chem. 44 (17): 5076-5086 2006 DOI: 10.1002/pola.21598
Hammer N.I., Early K.T., Sill K., Odoi M.Y., Emrick T., Barnes M.D. “Coverage-mediated suppression of blinking in solid state quantum dot conjugated organic composite nanostructures”, J. Phys. Chem. B. 2006, 110, 14167-14171. DOI: 10.1021/jp062065f
Niu Z.W., Bruckman M., Kotakadi V.S., He J.B., Emrick T., Russell T.P., Yang L., Wang Q. “Study and characterization of tobacco mosaic virus head-to-tail assembly assisted by aniline polymerization”, Chem. Commun. 2006, 28, 3019-3021. DOI: 10.1039/b603780a
Lee J.Y., Zhand Q.L., Emrick T., Crosby A.J. “ Nanoparticle alignment and repulsion during failure of glassy polymer nanocomposites” Macromolecules 2006, 39, 7392-7396. DOI: 10.1021/ma061210k
Cardoen G. Breitenkamp K., Emrick T., Coughlin E.B. “Manifold assembly for the convenient polymerization of ethylene oxide and butadiene” Macromolecules 2006, 39, 7170-7173. DOI: 10.1021/ma061379y
Ellzey, K.A., Ranganathan, T., Zilberman, J., Coughlin, EB; Farris, R.J., Emrick, T. “Deoxybenzoin-based Polyarylates as Halogen-free Fire-resistant Polymers”, Macromolecules 2006, 39, 3553-3558. DOI: 10.1021/ma052777o
Gupta, S.; Zhang, QL.; Emrick, T.; Balazs, A.C.; Russell, T.P. “Entropy-driven Segregation of Nanoparticles to Cracks: A Route to Self-healing Systems,” Nature Materials 2006, 5, 229-233. DOI: 10.1038/nmat1582
Odoi, M.Y.; Hammer, N.I.; Sill, K.; Emrick, T.; Barnes, M.D. “Observation of enhanced energy transfer in individual quantum dot-oligophenylene vinylene nanostructures” J. Am. Chem. Soc. 2006, 128, 3506-3507. DOI: 10.1021/ja058429j
2005
Glogowski, E.; He, J.B.; Russell, T.P.; Emrick, T. “Mixed monolayer coverage on gold nanoparticles for interfacial stabilization of immiscible fluids,” Chem. Commun. 2005, 32, 4050-4052. DOI: 10.1039/b503670d
Parrish, B.; Breitenkamp, R.B.; Emrick, T. “PEG and Peptide-grafted Aliphatic Polyesters by Click Chemistry” J. Am. Chem. Soc., 2005, 127, 7404-7410. DOI: 10.1021/ja050310n
Skaff, H.; Lin, Y.; Tangirala, R.; Breitenkamp, K.; Boker, A.; Russell, T.P.; Emrick, T. “Cross-linked Capsules of Quantum Dots by Interfacial Assembly and Ligand Cross-linking” Adv. Mater. 2005, 17, 2082-2085. DOI: 10.1002/adma.200500587
Sill, K.; Emrick, T. “Bis-dendritic Polyethylene Prepared by Ring-opening Metathesis Polymerization in the Presence of Bis-dendritic Chain Transfer Agents”, J. Polym. Sci. A.: Polym. Chem. 2005, 43, 5429-5439. DOI: 10.1002/pola.20995
Breitenkamp, K.; Emrick, T. “Amphiphilic Ruthenium Benzylidene Metathesis Catalysts with PEG-substituted Pyridine Ligands,” J. Polym. Sci. A.: Polym. Chem. 2005, 43, 5715-5721. DOI: 10.1002/pola.21061
Russell, J.T.; Lin, Y.; Boker, A.; Su, L; Carl, P.; Zettl, H.; He, J.B.; Sill, K.; Tangirala, R.; Emrick, T.; Littrell, K.; Thiyagarajan, P.; Cookson, D.; Fery, A.; Wang, Q.; Russell, T.P. “Self-assembly and Cross-linking of Bionanoparticles at Liquid-Liquid Interfaces,” Angew. Chem. Int. Ed. 2005, 44, 2420-2426. DOI: 10.1002/anie.200462653
Lin, Y.; Boker, A.; He, J.B.; Sill, K.; Xiang, H.Q.; Abetz, C.; Li, X.F.; Wang, J.; Emrick, T.; Long, S.; Wang, Q.; Balas, A.; Russell, T.P. “Self-directed Self-assembly of Nanoparticle/copolymer Mixtures” Nature 2005, 434, 55-59. DOI: 10.1038/nature03310
Zhang, Q.; Xu, T.; Butterfield, D.; Misner, M.J.; Ryu, D.Y.; Emrick, T.; Russell, T.P. “Controlled Placement of CdSe Nanoparticles in Diblock Copolymer Templates by Electrophoretic Deposition” NanoLetters 2005, 5, 357-361. DOI: 10.1021/nl048103t
Ki, C.D.; Emrick, T.; Chang, J.Y. “Preparation of Functional Nanoporous Silica for Encapsulation of CdSe Nanoparticles”, Adv. Mater. 2005, 17, 230-233. DOI: 10.1002/adma.200400184
Lin, Y.; Boeker, A.; Skaff, H.; Cookson, D.; Dinsmore, A.D.; Emrick, T.; Russell, T.P. “Nanoparticle Assembly at Fluid Interfaces: Structure and Dynamics” Langmuir, 2005, 21, 191-194. DOI: 10.1021/la048000q
Hong, R.; Fischer, N.O.; Emrick, T.; Rotello, V.M. “Surface PEGylation and Ligand Exchange Chemistry of FePt Nanoparticles for Biological Applications” Chem. Mater. 2005, 17, 4617-4621. DOI: 10.1021/cm0507819
2004
Skaff, H.; Emrick, T. “Reversible Addition-Fragmentation Chain Transfer Polymerization from the Surface of Unprotected CdSe Nanoparticles” Angew. Chem. Int. Ed. 2004, 43, 5383-5386. DOI: 10.1002/anie.200453822
Skaff, H.; Sill, K.; Emrick, T. “Quantum Dots Tailored with Poly(para-phenylene vinylene)” J. Am. Chem. Soc. 2004, 126, 11322-11325. DOI: 10.1021/ja047260r
Parrish, B.; Emrick, T. “Aliphatic Polyesters with Pendant Cyclopentene Groups: Controlled Synthesis and Conversion to Polyester-graft-PEG Copolymers” Macromolecules 2004, 37, 5863-5865. DOI: 10.1021/ma048981d
Boeker, A.; Lin, T.; Chiapperini, K.; Horowitz, R.; Thompson, M.; Carreon, V.; Xu, T.; Abetz, C.; Skaff, H.; Dinsmore, A.D.; Emrick, T.; Russell, T.P. “Hierarchical Nanoparticle Assemblies Formed by Decorating Breath Figures” Nature Materials 2004, 3, 302-306. DOI: 10.1038/nmat1110
Sill, K.; Emrick, T. “Nitroxide-Mediated Radical Polymerization from CdSe Nanoparticles”, Chemistry of Materials, 2004, 16, 1240-1243. DOI: 10.1021/cm035077b
Hong, R.; Fisher, N.O.; Verma, A.; Goodman, C.M.; Emrick, T.; Rotello, V.M. “Control of Protein Structure and Function through Surface Recognition by Tailored Nanoparticle Scaffolds” J. Am. Chem. Soc. 2004, 126, 739-743. DOI: 10.1021/ja037470o
Hong, R.; Emrick, T.; Rotello, V.M. “Monolayer-controlled Substrate Selectivity using Non-covalent Enzyme-Nanoparticle Conjugates” J. Am. Chem. Soc. 2004, 126, 13572-13573. DOI: 10.1021/ja0461163
2003
Breitenkamp, K.; Emrick, T. “Novel Polymer Capsules from Amphiphilic Graft Copolymers and Ring-opening Cross Metathesis” J. Am. Chem. Soc. 2003, 125, 12070-12071. DOI: 10.1021/ja036561i
Lin Y.; Skaff, H.; Boker, A.; Dinsmore, A.D.; Emrick, T.; Russell, T.P. “Ultrathin Cross-linked Nanoparticle Membranes” J. Am. Chem. Soc. 2003, 125, 12690-12691. DOI: 10.1021/ja036919a
Lin, Y.; Skaff, H.; Emrick, T.; Dinsmore, A.D.; Russell, T.P. “Nanoparticle assembly and transport at liquid-liquid interfaces” Science 2003, 299, 226-229. DOI: 10.1126/science.1078616
Misner, M.J.; Skaff, H.; Emrick, T.; Russell, T.P. "Directed Deposition of Nanoparticles using Diblock Copolymer Templates" Advanced Materials, 2003, 15, 221-224. DOI: 10.1002/adma.200390050
Skaff, H.; Emrick, T. "The Use of 4-Substituted Pyridines to Afford Amphiphilic, PEGylated Cadmium Selenide Nanoparticles" Chem. Comm. 2003, 52-53. DOI: 10.1039/b208718a
Ellzey, K.A.; Farris, R.J.; Emrick, T. “Synthetic and Thermal Studies of Bisphenol-C Containing Poly(aryletherketone)” Polym. Bull. 2003, 50, 235-242.
Evans, RN., Gilardi, R., Emrick, T. “1-(p-biphenyl)-4 '-(2-naphthyl)cubane” Acta Crystallographica Section E-Structure Reports Online, 2003, 59, O1283-O1285. DOI: 10.1107/S160053803017483
2002
Breitenkamp, K.; Simeone, J.; Jin, E.; Emrick, T. "Novel Amphiphilic Graft Copolymers Prepared by Ring-opening Metathesis Polymerization of Poly(ethylene glycol)-Substituted Cyclooctene Macromonomers” Macromolecules 2002, 35, 9249-9252.
Parrish, B.; Quansah, J.K.; Emrick, T. "Functional Polyesters Prepared by Polymerization of a-Allyl(d-valerolactone), and its Copolymerization with e-Caprolactone and d-Valerolactone" J. Polym. Sci. Part A: Polym. Chem. 2002, 40, 1983-1990.
Skaff, H.; Ilker, M.F.; Coughlin, E.B.; Emrick, T. “Preparation of Cadmium Selenide-Polyolefin Composites from Functional Phosphine Oxides and Ruthenium-based Metathesis” J. Am. Chem. Soc. 2002, 124, 5729-5733.
2000
Emrick, T.; Chang, H-T.; Fréchet, J.M.J. "The Preparation of Hyperbranched Aromatic and Aliphatic Polyether Epoxies by Chloride-Catalyzed Proton Transfer Polymerization from AB(n) and A(2) + B-3 Monomers" J. Polym. Sci. Part A: Polym. Chem. 2000, 33, 4850. DOI: 10.1002/1099-0518(200012)38:1+<4850::AID-POLA230>3.0.CO;2-G
Hecht, S.; Emrick, T.; Fréchet, J.M.J. "Hyperbranched Porphyrins - A Rapid Synthetic Approach To Multiporphyrin Macromolecules" Chem. Commun. 2000, 313. DOI: 10.1039/a909258g
Emrick, T.; Chang, H.T.; Fréchet, J.M.J., Baccei, L., Woods, J. "Hyperbranched Aromatic Epoxies in the Design of Adhesive Materials" Polym. Bull. 2000, 45, 1. DOI: 10.1007/s002890070049
1999
Emrick, T.; Chang, H-T.; Fréchet, J.M.J "An A(2)+B-3 Approach to Hyperbranched Aliphatic Polyethers Containing Chain End Epoxy Substituents" Macromolecules 1999, 32, 6380. DOI: 10.1021/ma990687b
Emrick, T.; Hayes, W.; Fréchet, J.M.J. "A TEMPO Mediated “Living” Free Radical Approach to ABA Triblock Dendritic-Linear Hybrid Copolymers" J. Polym. Sci. Part A: Polym. Chem. 1999, 37, 3748. DOI: 10.1002/(SICI)1099-0518(19991015)37:20<3748::AID-POLA2>3.3.CO;2-8
Emrick, T; Fréchet, J.M.J. "Self-Assembly of Dendritic Structures" Curr. Opin. Coll. In. Sci. 1999, 4, 15-23. DOI: 10.1016/S1359-0294(99)00008-4
Eaton, P.E.; Pramod, K.; Emrick, T., Gilardi, R. "Building with Cubane-1,4-diyl. Synthesis of Aryl Substituted Cubanes, p-[n]Cubyls, and Cubane Separated Bis-Arenes" J. Am. Chem. Soc. 1999, 121, 4111. DOI: 10.1021/ja983441f
Yildrim, T., Kilic, C., Ciraci, S., Gehring, PM., Neumann, DA., Eaton, PE., Emrick, T. “Vibrations of the cubane molecule: inelastic neutron scattering study and theory” Chemical Physics Letters, 1999, 309, 234-240. DOI: 10.1016/S0009-2614(99)00655-7
Yildrim, T., Gehring, PM., Neumann, DA., Eaton, PE., Emrick, T. “Neutron-scattering investigation of molecular reorientations in solid cubane” Physical Review B, 1999, 60, 314-321. DOI: 10.1103/PhysRevB.60.314
1994-1998
Yildirim, T.; Gehring, P.M.; Neumann D.A.; Eaton, P.E.; Emrick, T. "Solid Cubane: A Brief Review" Carbon 1998, 36, 809.
Yildrim, T., Gehring, PM., Neumann, DA., Eaton, PE., Emrick, T. “Unusual structure, phase transition, and dynamics of solid cubane” Physical Review Letters, 1997, 78, 4938-4941. DOI: 10.1103/PhysRevLett.78.4938
Hare, M.; Emrick, T.; Eaton, P.E.; Kass, S.R. "Cubyl Anion Formation and an Experimental Determination of the Acidity and C-H Bond Dissociation Energy of Cubane" J. Am. Chem. Soc. 1997, 119, 237.
Engling, G.; Emrick, T.; Hellmann, J.; McElroy, E.; Brandt, M.; Reingold, I.D. "A Novel Approach to Bicyclo[3.3.0]octane-2,8-dione" J. Org. Chem. 1994, 59, 1945-1946.
293. Yang, Z.; Snyder, D.; Pagaduan, J.N.; Waldman, A.; Crosby, A.J.; Emrick, T. Mesoscale Polymer Surfactants: Photolithographic Production and Localization at Droplet Interfaces. J. Am. Chem. Soc. 2022, 144, 22059-22066. DOI: 10.1021/jacs.2c09346.
292. Chen, Z.; Huang, Y.; Gao, J.; Zhang, L.; Zaifei, M.; Liu, M.; Emrick, T.; Liu, Y. Synchronous Doping Effects of Cathode Interlayers on Efficient Organic Solar Cells. ACS Energy Lett, 2022, 7, 4052-4060. DOI.org/10.1021/acsenergylett.2c02153.
291. Cheng, Y.H.; Kirschner, A.Y.; Chang, C.C.; He, Z.W.; Nassr, M.; Emrick, T.; Freeman, B.D. Surface Modification of Ultrafiltration Membranes with 1,4-Benzoquinone and Polyetheramines to Improve Fouling Resistance. ACS Applied Materials & Interfaces 2022, 14(46), 52390-52401. DOI: 10.1021/acsami.2c14884
290. Cui, J.X.; Cueto, C.; Bien, C.; Preda, D.; Gamliel, D.; Emrick, T. Robust polymer foams from 2-hydroxyethyl cellulose: Fabrication, stability, and chemical functionalization. Polymer 2022, 256, Article: 125131. DOI: 10.1016/j.polymer.2022.125131
289. Zhou, L.; Emenuga, M.; Kumar, S.; Lamantia, Z.; Figueiredo, M.; Emrick, T. Designing Synthetic Polymers for Nucleic Acid Complexation and Delivery: From Polyplexes to Micelleplexes to Triggered Degradation. Biomacromolecules 2022 23(10), 4029-4040. DOI: 10.1021/acs.biomac.2c00767
288. Cueto, C.; Hu, W.G; Ribber, A.; Bolduc, K.; Emrick, T. Polystyrene-based Macromolecular Ammonium Halides for Tuning Color and Exchange Kinetics of Perovskite Nanocrystals. Angewandte Chemie-International Edition 2022, 61(37), Article: e202207126. DOI: 10.1002/anie.202207126
287. Prevost, L.; Barber, D.M.; Daieff, M.; Pham, J.T.; Crosby, A.J.; Emrick, T.; du Roure, O.; Lindner, A. Shaping Nanoscale Ribbons into Microhelices of Controllable Radius and Pitch. ACS Nano 2022, 16(7), 10581-10588. DOI: 10.1021/acsnano.2c02038
286. Zhang, Z.W.; Cueto, C.; Ding, Y.M.; Yu, L.; Russell, T.P.; Emrick, T.; Liu, Y. High-Performance 1 cm2 Perovskite-Organic Tandem Solar Cells with a Solvent-Resistant and Thickness-Insensitive Interconnecting Layer. ACS Applied Materials & Interfaces 2022, 14(26), 29896-29904. DOI: 10.1021/acsami.2c06760
285. Hight-Huf, N.; Pagaduan, J.N.; Katsumata, R.; Emrick, T.; Barnes, M.D. Stabilization of Three-Particle Excitations in Monolayer MoS2 by Fluorinated Methacrylate Polymers. Journal of Physical Chemistry Letters 2022, 13(21), 4794-4799. DOI: 10.1021/acs.jpclett.2c01150
284. Marin, A.A.; Decker, R.E.; Kumar, S.; Lamantia, Z.; Yokota, H.; Emrick, T.; Figueiredo, M.L. Enhancing Prednisone-Based Arthritis Therapy with Targeted IL-27 Gene Delivery. Bioengineering-Basel 2022, 9(6), Article: 248. DOI: 10.3390/bioengineering9060248
283. Pagaduan, J.N.; Samitsu, S.; Varma, J.; Emrick, T.; Katsumata, R. Freeze-Burn: Fabrication of Porous Carbon Networks via Polymer-Templated Rapid Thermal Annealing. ACS Applied Materials 2022 4 (6), 4329-4338. DOI: 10-1021/acsapm.2c00283
282. Zhewei, Z.; Cueto,C.; Yiming D; Le Y; Russell, T.P.; Emrick, T.; Yao, L. High-Performance 1cm(2) Perovskite-Organic Tandem Solar Cells with a Solvent Resistant and Thickness-Insensitive Interconnecting Layer. ACS Applied Materials & Interfaces 2022, 14(26), 29896-29904. DOI: 10:1021/acsami.2c06760
281. Prevost, L.; Barber, D.M.; Daieff, M.; Pham, J.T.; Crosby, A.J.; Emrick, T.; du Roure, O.; Lindner, A. Shaping Nanoscale Ribbons into Microhelices of Controllable Radius and Pitch. ACS Nano 2022, 16(7), 10581-10588. DOI: 10.1021/acsnano.2c02038
280. Margossian, K.O.; Brown, M.U.; Emrick, T.; Muthukumar, M. Coacervation in polyzwitterion-polyelectrolyte systems and their potential applications for gastrointestinal drug delivery platforms. Nature Communications 2022, 13(1), Article: 2250. DOI: 10.1038/s41467-022-29851-y
279. Chen, Z.; Hu, M.Q.; Li, X.D.; Smith, D.M.; Seong, H.G.; Emrick, T.; Rzayev, J.; Russell, T.P. In Situ Hydrolysis of Block Copolymers at the Water-Oil Interface. Angewandte Chemie-International Edition 2022, Article e202201392. DOI: 10.1002/anie.202201392
278. Cueto, C.; Donaghue, C.; Bolduc, K.; Emrick, T. Zwitterion Block Copolymers for the Synthesis and Stabilization of Perovskite Nanocrystals. Chemistry-A European Journal 2022, 28(30), Article: e202200409. DOI: 10.1002/chem.202200409
277. Seong, H.G.; Chen, Z.; Emrick, T.; Russell, T.P. Reconfiguration and Reorganization of Bottlebrush Polymer Surfactants. Angewandte Chemie-International Edition 2022, 61(19), Article: e202200530. DOI: 10.1002/anie.202200530
276. Brown, M.U.; Seong, H.G.; Margossian, K.O.; Bishop, L.; Russell, T.P.; Muthukumar, M.; Emrick, T. Zwitterionic Ammonium Sulfonate Polymers: Synthesis and Properties in Fluids. Macromolecular Rapid Communications 2022 43(12), Article: 2100678. DOI: 10.1002/marc.202100678
275. Figueiredo, M.L.; Letteri, R.; Chan-Seng, D.; Kumar, S.; Rivera-Cruz, C.M.; Emrick, T.S. Reengineering Tumor Microenvironment with Sequential Interleukin Delivery. Bioengineering-Basel 2021, 8(7), Article: 90. DOI: 10.3390/bioengineering8070090
274. Zhou, L.; Triozzi, A.; Figueiredo, M.; Emrick, T. Fluorinated Polymer Zwitterions: Choline Phosphates and Phosphorylcholines. ACS Macro Letters 2021, 10(10), 1204-1209. DOI: 10.1021/acsmacrolett.1c00451
273. Hight-Huf, N.; Nagar, Y.; Levi, A.; Pagaduan, J.N.; Datar, A.; Katsumata, R.; Emrick, T.; Ramasubramaniam, A.; Naveh, D.; Barnes, M.D. Polarization-Driven Asymmetric Electronic Response of Monolayer Graphene to Polymer Zwitterions Probed from Both Sides. ACS Applied Materials & Interfaces 2021, 13(40), 47945-47953. DOI: 10.1021/acsami.1c13505
272. Yang, Z.F.; Zhao, J.; Emrick, T. Functional Polymer Zwitterions as Reactive Surfactants for Nanoparticle Capture. ACS Applied Materials & Interfaces 2021, 13(18), 21898-21904. DOI: 10.1021/acsami.1c05955
271. Brown, M.U.; Triozzi, A.; Emrick, T. Polymer Zwitterions with Phosphonium Cations. Journal of the American Chemical Society 2021, 143(17), 6528-6532. DOI: 10.1021/jacs.1c00793
270. Kim, H.; Sundaram, S.; Kang, J.H.; Tanjeem, N.; Emrick, T.; Hayward, R.C. Coupled oscillation and spinning of photothermal particles in Marangoni optical traps. Proceedings of the National Academy of Sciences of the United States of America 2021, 118(18), Article: e2024581118, 9 pages. DOI: 10.1073/pnas.2024581118
269. Zhao, J.; Pan, Z.H.; Snyder, D.; Stone, H.A.; Emrick, T. Chemically Triggered Coalescence and Reactivity of Droplet Fibers. Journal of the American Chemical Society 2021, 143(14), 5558-5564. DOI: 10.1021/jacs.1c02576
268. Sun, Y.L.; Montz, B.J.; Selhorst, R.; Tang, H.Y.; Zhu, J.X.; Nevin, K.P.; Woodard, T.L.; Ribbe, A.E.; Russell, T.P.; Nonnenmann, S.S.; Lovley, D.R.; Emrick, T. Solvent-Induced Assembly of Microbial Protein Nanowires into Superstructured Bundles. Biomacromolecules 2021, 22(3), 1305-1311. Article: e2024581118. DOI: 10.1021/acs.biomac.0c01790
267. Pagaduan, J.N.; Hight-Hug, N.; Datar, A.; Nagar, Y.; Barnes, M.; Naveh, D.; Ramasubramaniam, A.; Katsumata, R.; Emrick, T. Electronic Tuning of Monolayer Graphene with Polymeric “Zwitterists.” ACS Nano 2021, 15(2), 2762-2770. Article: e2024581118. DOI: 10.1021/acsnano.0c08624
Zhang, Z.W.; Sheri, M.; Page, Z.A.; Emrick, T.; Saeki, A.; Liu, Y.; Russell, T.P. Understanding Hole Extraction of Inverted Perovskite Solar Cells. ACS Applied Materials & Interfaces 2020, 12(50), 56068-56075. DOI: 10.1021/acsami.0c18108
Saraf, C.; Stubbs, E.; Hu, W.G.; Emrick, T.; Lesser, A.J. Combining Mechanical Fortification and Ultralow Flammability in Epoxy Networks. Macromolecular Materials and Engineering 2020, Early Access Nov 2020, Article 2000567, 9 pages. DOI: 10.1002/mame.202000567
Liu, Y.L.; Santa Chalarca, C.F.; Carmean, R.N.; Olson, R.A.; Madinya, J.; Sumerlin, B.S.; Sing, C.E.; Emrick, T.; Perry, S.L. Effect of Polymer Chemistry on the Linear Viscoelasticity of Complex Coacervates. Macromolecules 2020, 53(18), 7851-7864. DOI: 10.1021/acs.macromol.0c00758
Zhao, J.; Santa Chalarca, C.F.; Nunes, A.K.; Stone, H.A.; Emrick, T. Self-Propelled Supracolloidal Fibers from Multifunctional Polymer Surfactants and Droplets. Macromolecular Rapid Communications 2020, 41(15), Article 2000334, 7 pages. DOI: 10.1002/marc.202000334
Barber, D.M.; Yang, Z.F.; Prevost, L.; du Roure, O.; Lindner, A.; Emrick, T.; Crosby, A.J. Programmed Wrapping and Assembly of Droplets with Mesoscale Polymers. Advanced Functional Materials 2020, 30(36), Article 2002704, 9 pages. DOI: 10.1002/adfm.202002704
Figueiredo, M.L.; Neto, M.F.; Salameh, J.W.; Decker, R.E.; Letteri, R.; Chan-Seng, D.; Emrick, T. Ligand-Mediated Targeting of Cytokine Interleukin-27 Enhances Its Bioactivity in Vivo. Molecular Therapy-Methods & Clinical Development 2020, 17, 739-751. DOI: 10.1016/j.omtm.2020.03.022
Smith, A.F.; Liu, X.M.; Woodard, T.L; Fu, T.D.; Emrick, T.; Jimenez, J.M.; Lovley, D.R.; Yao, J. Bioelectronic protein nanowire sensors for ammonia detection. Nano Research 2020, 13(5), 1479-1484. DOI: 10.1007/s12274-020-2825-6
Kim, H.; Hight-Huf, N.; Kang, J.H.; Bisnoff, P.; Sundararajan, S.; Thompson, T.; Barnes, M.; Hayward, R.C.; Emrick, T. Polymer Zwitterions for Stabilization of CsPbBr3 Perovskite Nanoparticles and Nanocomposite Films. Angeqandte Chemie-International Edition 2020, 59(27), 10802-10806. DOI: 10.1002/anie.201916492
Wu, Y.; Liu, Y.; Emrick, T.; Russell, T.P. Polymer design to promote low work function surfaces in organic electronics. Progress In Polymer Science 2020, 103, Article 101222, 11 pages. DOI: 10.1016/j.progpolymsci.2020.101222
Salameh, J.W.; Zhou, L.; Ward, S.M.; Santa Chalarca, C.F.; Emrick, T.; Figueiredo, M.L. Polymer-mediated gene therapy: Recent advances and merging of delivery techniques. Wiley Interdisciplinary Reviews - Nanomedicine and Nanobiotechnology 2020, DOI: 10.1002/wnan.1598
Wang, J.Y.; Chen, W.; Nagao, M.; Shelat, P.; Hammer, B.A.G.; Tietjen, G.T.; Cao, K.D.; Henderson, J.M.; He, L.L.; Lin, B.; Akgun, B.; Meron, M.; Qian, S.; Ward, S.; Marks, J.D.; Emrick, T.; Lee, K.Y.C. Tailoring Biomimetic Phosphorylcholine-Containing Block Copolymers as Membrane-Targeting Cellular Rescue Agents. Biomacromolecules 2019, 20(9), 3385-3391. DOI: 10.1021/acs.biomac.9b00621
Stubbs, E.; Brown, M.; Steele, A.; Song, C.; Emrick, T. Designing branched deoxybenzoin polyesters and polymeric flame retardants. Journal of Polymer Science Part A-Polymer Chemistry 2019, 57(16), 17645-1770. DOI: 10.1002/pola.29446
Kim, H.; Kang, J.H.; Zhou, Y.; Kuenstler, A.S.; Kim, Y.; Chen, C.; Emrick, T.; Hayward, R.C. Light-driven shape morphing, assembly, and motion of nanocomposite gel surfers. Advanced Materials 2019, 31 (27), Article 1900932, 7 pages. DOI: 10.1002/adma.201900932
Liu, Y.; Sheri, M.; Cole, M.D.; Yu, D.M.; Emrick, T.; Russell, T.P. Transforming Ionene Polymers into Efficient Cathode Interlayers with Pendent Fullerenes. Angewandte Chemie-International Edition 2019, 58 (17), 5677-5681. DOI: 10.1002/anie.201901536
Li, Y.; Cole, M.D.; Gao, Y.G.; Emrick, T.; Xu, Z.; Liu, Y.; Russell, T.P. High-Performance Perovskite Solar Cells with a Non-doped Small Molecule Hole Transporting Layer. ACS Applied Energy Materials 2019, 2 (3), 1634-1641. DOI: 10.1021/acsaem.9b00164
Kim, H.; So, S.; Ribbe, A.; Liu, Y.; Hu, W.; Duzhko, V.V.; Harward, R.C.; Emrick, T. Functional polymers for growth and stabilization of CsPbBr3 perovskite nanoparticles. Chemical Communications 2019, 55 (12), 1833-1836. DOI: 10.1039/c8cc09343a
Sathyan, A.; Yang, Z.F.; Bai, Y.; Kim, H.; Crosby, A.; Emrick, T. Simultaneous "Clean-and-Repair" of Surfaces Using Smart Droplets. Advanced Functional Materials 2019, 29 (5), Article 1805219, 6 pages. DOI: 10.1002/adfm.201805219
Wang, P.J.; Selhorst, R.; Emrick, T.; Ramasubramaniam, A.; Barnes, M.D. Bidirectional Electronic Tuning of Single-Layer MoS2 with Conjugated Organochalcogens. Journal of Physical Chemistry C 2019, 123 (2), 1506-1511. DOI: 10.1021/acs.jpcc.8b10826
Sathyan, A.; Hayward, R.C.; Emrick T. Ring-Opening Polymerization of Allyl-Functionalized Lactams. Macromolecules 2019, 52 (1), 167-175. DOI: 10.1021/acs.macromol.8b02148
Ly, J.T.; Burnett, E.K.; Thomas, S.; Aljarb, A.; Liu, Y.; Park, S.; Rosa, S; Yi, Y.; Lee, H.; Emrick, T.; Russell, T.P.; Bredas, J.L.; Briseno, A.L. Efficient Electron Mobility in an All-Acceptor Napthalenediimide-Bithiazole Polymer Semiconductor with Large Backbone Torsion. ACS Applied Materials & Interfaces 2018, 10 (46), 40070-40077. DOI: 10.1021/acsami.8b11234
Santa Chalarca, C.F.; Letteri, R.A.; Perazzo, A.; Stone, H.A.; Emrick, T. Building supracolloidal fibers from zwitterion-stabilized adhesive emulsions. Advanced Functional Materials 2018, 28(45), Article 1804325, 10 pages. DOI: 10.1002/adfm.201804325
Sun, Y.L.; Tang, H.Y.; Ribbe, A.; Duzhko, V.; Woodard, T.L.; Ward, J.E.; Bai, Y.; Nevin, K.P.; Nonnenmann, S.S.; Russell, T.; Emrick, T.; Lovley, D.R. Conductive composite materials fabricated from microbially produced protein nanowires. Small 2018, 14 (44), Article 1802624, 5 pages. DOI: 10.1002/smll.201802624
Ward, S.M.; Skinner, M.; Saha, B.; Emrick, T. Polymer - Temozolomide conjugates as therapeutics for treating Glioblastoma. Molecular Pharmaceutics 2018, 15 (11), 5263-5276. DOI: 10.1021/acs.molpharmaceut.8b00766
Karak, S.; Page, Z.A.; Li, S.G.; Tinkham, J.S.; Lahti, P.M.; Duzhko, V.V.; Emrick, T. Amino-fulleropyrrolidines as electrotropic additives to enhance organic photovoltaics. Sustainable Energy & Fuels 2018, 2(10), 2143-2147. DOI: 10.1039/c8se00294k
Skinner, M.; Johnston, B.M.; Liu, Y.L.; Hammer, B.; Selhorst, R.; Xenidou, I.; Perry, S.L.; Emrick, T. Synthesis of Zwitterionic Pluronic Analogs. Biomacromolecules 2018, 19(8), 3377-3389. DOI: 10.1021/acs.biomac.8b00676
Liu, Y.; Sheri, M.; Cole, M.D.; Emrick, T.; Russell, T.P. Combining Fullerenes and Zwitterions in Non-Conjugated Polymer Interlayers to Raise Solar Cell Efficiency. Angewandte Chemie-International Edition 2018, 57 (31), 9675-9678. DOI: 10.1002/anie.201803748
Heo, K.; Miesch, C.; Na, J.H.; Emrick, T.; Hayward, R.C. Assembly of P3HT/CdSe nanowire networks in an insulating polymer host. Soft Matter 2018, 14 (25), 5327-5332. DOI: 10.1039/c8sm01001c
Jansen, L.E.; Amer, L.D.; Chen, E.Y.UT.; Nguyen, T.V.; Saleh, L.S.; Emrick, T.; Liu, W.F.; Bryant, S.J.; Peyton, S.R. Zwitterionic PEG-PC Hydrogels Modulate the Foreign Body Response in a Modulus-Dependent Manner. Biomacromolecules 2018, 19 (7), 2880-2888. DOI: 10.1021/acs.biomac.8b00444
Selhorst, R.; Wang, P.J.; Barnes, M.; Emrick, T. Bithiazolidinyleidene polymers: synthesis and electronic interactions with transition metal dichalcogenides. Chemical Science 2018, 9 (22), 5047-5051. DOI: 10.1039/c8sc01416g
Forth, J.; Liu, X.B.; Hasnain, J.; Toor, A.; Miszta, K.; Shi, S.W.; Geissler, P.L.; Emrick, T.; Helms, B.A.; Russell, T.P. Reconfigurable Printed Liquids. Advanced Materials 2018, 30(16). artno. 1707603. DOI: 10.1002/adma.201707603
Sheri, M.; Choudhary, U.; Grandhee, S.; Emrick, T. Fluoride-Catalyzed Deblocking: A Route to Polymeric Urethanes. Angewandte Chemie-International Edition 2018, 57(17), 4599-4602. DOI: 10.1002/anie.201800795
Liu, Y.; Cole, M.D.; Jiang, Y.F.; Kim, P.Y.; Nordlund, D.; Emrick, T.; Russell, T.P. Chemical and Morphological Control of Interfacial Self-Doping for Efficient Organic Electronics. Advanced Materials 2018, 30 (15), Article 1705976, 8 pages. DOI: 10.1002/adma.201705976
Barber, D.; Crosby, A.J.; Emrick, T. Mesoscale block copolymers. Advanced Materials 2018, 30 (13), Article 1706118, 6 pages. DOI: 10.1002/adma.201706118
Liu, Y.; Page, Z.A.; Zhou, D.M.; Duzhko, V.V.; Kittilstved, K.R.; Emrick, T.; Russell, T.P. Chemical Stabilization of Perovskite Solar Cells with Functional Fulleropyrrolidines. ACS Central Science 2018, 4 (2), 216-222. DOI: 10.1021/acscentsci.7b00454
Alon, H.; Stern, C.; Kirshner, M.; Sinai, O.; Wasserman, M.; Selhorst, R.; Gasper, R.; Ramasubramaniam, A.; Emrick, T.; Nayeh, D. Lithographically Patterned Functional Polymer-Graphene Hybrids for Nanoscale Electronics. ACS Nano 2018, 12 (2), 1928-1933. DOI: 10.1021/acsnano.7b08844
Skinner, M.; Ward, S.M.; Nilsson, C.L.; Emrick, T. Augmenting Glioblastoma Chemotherapy with Polymers. ACS Chemical Neuroscience 2018, 9 (1), 8-10. DOI: 10.1021/acschemneuro.7b00168
Tran, Y.H.; Rasmuson, M.J.; Emrick, T.; Klier, J.; Peyton, S.R. Strain-stiffening gels based on latent crosslinking. Soft Matter 2017, 13 (47), 9007-9014. DOI: 10.1039/c7sm01888f
Kalasin, S.; Letteri, R.A.; Emrick, T.; Santore, MM. Adsorbed Polyzwitterion Copolymer Layers Designed for Protein Repellency and Interfacial Retention. Lanmuir 2017, 33 (47), 13708-13717. DOI: 10.1021/acs.langmuir.7b03391
Ramasubramanium, A.; Selhorst, R.; Alon, H.; Barnes, M.D.; Emrick, T.; Naveh, D. Combining 2D inorganic semiconductors and organic polymers at the frontier of the hard-soft materials interface. Journal of Materials Chemistry C 2017, 5 (43), 11158-11164.DOI: 10.1039/c7tc02790g
Liu, Y.; Renna, L.A.; Thompson, H.B.; Page, Z.A.; Emrick, T.; Barnes, M.D.; Bag, M.; Venkataraman, D.; Russell, T.P. Role of Ionic Functional Groups on Ion Transport at Perovskite Interfaces. Advanced Energy Materials 2017, 7 (21), Article 1701235, 13 pages. DOI: 10.1002/aenm.201701235
Ruscello, M.; Stolz, S.; Arellano, D.L.G.; Ullrich, F.; Hillebrandt, S.; Mankel, E.; Pucci, A.; Kowalsky, W.; Emrick, T.; Briseno, A.L.; Hernandez-Sosa, G. Electron injection and interfacial trap passivation in solution-processed organic light-emitting diodes using a polymer zwitterion interlayer. Organic Electronics 2017, 50, 384-388. DOI: 10.1016/j.orgel.2017.08.014
Kirschner, A.Y.; Chang, C.C.; Kasemset, S.; Emrick, T.; Freeman, B.D. Fouling-resistant ultrafiltration membranes prepared via co-deposition of dopamine/zwitterion composite coatings. Journal of Membrane Science 2017, 541, 300-311. DOI: 10.1016/j.memsci.2017.06.055
Letteri, R.A.; Chalarca, C.F.S.; Bai, Y.; Hayward, R.C.; Emrick, T. Forming Sticky Droplets from Slippery Polymer Zwitterions. Advanced Materials 2017, 29 (38), Article 1702921, 8 pages. DOI: 10.1002/adma.201702921
Cole, M.D.; Sheri, M.; Bielicki, C.; Emrick, T. Perylene Diimide-Based Ionene and Zwitterionic Polymers: Synthesis and Solution Photophysical Properties. Macromolecules 2017, 50 (19), 7535-7542. DOI: 10.1021/acs.macromol.7b01281
Wang, J.C.; Bindokas, V.P.; Skinner, M.; Emrick, T.; Marks, J.D. Mitochondrial mechanisms of neuronal rescue by F-68, a hydrophilic Pluronic block co-polymer, following acute substrate deprivation. Neurochemistry International 2017, 109 (Special Issue), 126-140. DOI: 10.1016/j.neuint.2017.04.007
Johnston, B.M.; Johnston, C.W.; Letteri, R.A.; Lytle, T.K.; Sing, C.E.; Emrick, T.; Perry, S.L. The effect of comb architecture on complex coacervation. Organic & Biomolecular Chemistry 2017, 15 (36), 7630-7642. DOI: 10.1039/c7ob01314k
Sae-Ung, P.; Kolewe, K. W.; Bai, Y.; Rice, E. W.; Schiffman, J. D.; Emrick, T.; Hoven, V. P. Antifouling Stripes Prepared from Clickable Zwitterionic Copolymers. Langmuir 2017, 33 (28), 7028-7035. DOI: 10.1021/acs.langmuir.7b01431
Choudhary, U.; Mir, A. A.; Emrick, T. Soluble, Allyl-Functionalized Deoxybenzoin Polymers. Macromolecules 2017, 50 (10), 3773-3779. DOI: 10.1021/acs.macromol.7b00460
Duzhko, V. V.; Dunham, B.; Rosa, S. J.; Cole, M. D.; Paul, A.; Page, Z. A.; Dimitrakopoulos, C.; Emrick, T. N-Doped Zwitterionic Fullerenes as Interlayers in Organic and Perovskite Photovoltaic Devices. ACS Energy Letters 2017, 2 (5), 957-963. DOI: 10.1021/acsenergylett.7b00147
Skinner, M.; Ward, S. M.; Emrick, T. Versatile Synthesis of Polymer-Temozolomide Conjugates. ACS Macro Letters 2017, 6 (3), 215-218. DOI: 10.1021/acsmacrolett.7b00007
Kosif, I.; Kratz, K.; You, S. S.; Bera, M. K.; Kim, K.; Leahy, B.; Emrick, T.; Lee, K. Y. C.; Lin, B. H. Robust Gold Nanoparticle Sheets by Ligand Cross-Linking at the Air-Water Interface. ACS Nano 2017, 11 (2), 1292-1300. DOI: 10.1021/acsnano.6b05563
Chalarca, C. F. S.; Emrick, T., Reactive polymer zwitterions: Sulfonium sulfonates. Journal of Polymer Science Part A-Polymer Chemistry 2017, 55 (1), 83-92. DOI: 10.1002/pola.28359.
Bai, Y.; Chang, C. C.; Choudhary, U.; Bolukbasi, I.; Crosby, A. J.; Emrick, T., Functional droplets that recognize, collect, and transport debris on surfaces. Science Advances 2016, 2 (10), e1601462. DOI: 10.1126/sciadv.1601462.
Bai, Y.; Chang, C. C.; Zhao, X. J.; Ribbe, A.; Bolukbasi, I.; Szyndler, M. J.; Crosby, A. J.; Emrick, T. Mechanical Restoration of Damaged Polymer Films by "Repair-and-Go". Advanced Functional Materials 2016, 26(6), 857-863. DOI: 10.1002/adfm.201503947
Chang, C. C.; Kolewe, K. W.; Li, Y. Y.; Kosif, I.; Freeman, B. D.; Carter, K. R.; Schiffman, J. D.; Emrick, T. Underwater Superoleophobic Surfaces Prepared from Polymer Zwitterion/Dopamine Composite Coatings. Advanced Materials Interfaces 2016, 3(6), Article 1500521, 9 pages. DOI: 10.1002/admi.201500521
Ghobadi, A. F.; Letteri, R.; Parelkar, S. S.; Zhao, Y.; Chan-Seng, D.; Emrick, T.; Jayaraman, A. Dispersing Zwitterions into Comb Polymers for Nonviral Transfection: Experiments and Molecular Simulation. Biomacromolecules 2016, 17(2), 546-557. DOI: 10.1021/acs.biomac.5b01462
Hu, G. J.; Emrick, T. Functional Choline Phosphate Polymers. Journal of the American Chemical Society 2016, 138 (6), 1828-1831. DOI: 10.1021/jacs.5b13156
Kolewe, K. W.; Dobosz, K. M.; Rieger, K. A.; Chang, C. C.; Emrick, T.; Schiffman, J. D., Antifouling Electrospun Nanofiber Mats Functionalized with Polymer Zwitterions. ACS Applied Materials & Interfaces 2016, 8 (41), 27585-27593. DOI: 10.1021/acsami.6b09839.
Lawrence, J.; Emrick, T. Pentafluorophenyl Ester-Functionalized Nanoparticles as a Versatile Platform for Selective and Covalent Inter-nanoparticle Coupling. ACS Applied Materials & Interfaces 2016, 8(3), 2393-2398. DOI: 10.1021/acsami.5b11550
Lee, H.; Stephenson, J. C.; Richter, L. J.; McNeill, C. R.; Gann, E.; Thomsen, L.; Park, S.; Jeong, J.; Yi, Y.; DeLongchamp, D. M.; Page, Z. A.; Puodziukynaite, E.; Emrick, T.; Briseno, A. L. The Structural Origin of Electron Injection Enhancements with Fulleropyrrolidine Interlayers. Advanced Materials Interfaces 2016, 3(10), Article 1500852, 7 pages. DOI: 10.1002/admi.201500852
Liu, Y.; Duzhko, V. V.; Page, Z. A.; Emrick, T.; Russell, T. P., Conjugated Polymer Zwitterions: Efficient Interlayer Materials in Organic Electronics. Accounts of Chemical Research 2016, 49 (11), 2478-2488. DOI: 10.1021/acs.accounts.6b00402.
Liu, Y.; Bag, M.; Renna, L. A.; Page, Z. A.; Kim, P.; Emrick, T.; Venkataraman, D.; Russell, T. P. Understanding Interface Engineering for High-Performance Fullerene/Perovskite Planar Heterojunction Solar Cells. Advanced Energy Materials 2016, 6(2), Article 1501606, 7 pages. DOI: 10.1002/aenm.201501606
Liu, Y.; Renna, L. A.; Page, Z. A.; Thompson, H. B.; Kim, P. Y.; Barnes, M. D.; Emrick, T.; Venkataraman, D.; Russell, T. P., A Polymer Hole Extraction Layer for Inverted Perovskite Solar Cells from Aqueous Solutions. Advanced Energy Materials 2016, 6 (20), 1600664. DOI: 10.1002/aenm.201600664.
Liu, Y.; Renna, L. A.; Bag, M.; Page, Z. A.; Kim, P.; Choi, J.; Emrick, T.; Venkataraman, D.; Russell, T. P. High Efficiency Tandem Thin-Perovskite/Polymer Solar Cells with a Graded Recombination Layer. ACS Applied Materials & Interfaces 2016, 8(11), 7070-7076. DOI: 10.1021/acsami.5b12740
Mir, A. A.; Wagner, S.; Kramer, R. H.; Deglmann, P.; Emrick, T. Deoxybenzoin-containing polysulfones and polysulfoxides: Synthesis and thermal properties. Polymer 2016, 84, 59-64. DOI: 10.1016/j.polymer.2015.12.031
Morozova, S.; Hu, G.; Emrick, T.; Muthukumar, M. Influence of Dipole Orientation on Solution Properties of Polyzwitterions. ACS Macro Letters 2016, 5(1), 118-122. DOI: 10.1021/acsmacrolett.5b00876
Page, Z. A.; Liu, Y.; Puodziukynaite, E.; Russell, T. P.; Emrick, T. Hydrophilic Conjugated Polymers Prepared by Aqueous Horner-Wadsworth-Emmons Coupling. Macromolecules 2016, 49(7), 2526-2532. DOI: 10.1021/acs.macromol.5b02501
Selhorst, R. C.; Puodziukynaite, E.; Dewey, J. A.; Wang, P.; Barnes, M. D.; Ramasubramaniam, A.; Emrick, T. Tetrathiafulvalene-containing polymers for simultaneous non-covalent modification and electronic modulation of MoS2nanomaterials. Chemical Science 2016, 7(7), 4698-4705. DOI: 10.1039/c6sc00305b
Skinner, M.; Selhorst, R.; Emrick, T. Synthesis of Water-Soluble Zwitterionic Polysiloxanes. Journal of Polymer Science Part A-Polymer Chemistry 2016, 54(1), 127-134. DOI: 10.1002/pola.27773
Wong, K. E.; Mora, M. C.; Skinner, M.; Page, S. M.; Crisi, G. M.; Arenas, R. B.; Schneider, S. S.; Emrick, T. Evaluation of PolyMPC-Dox Prodrugs in a Human Ovarian Tumor Model. Molecular Pharmaceutics 2016, 13(5), 1679-1687. DOI: 10.1021/acs.molpharmaceut.6b00092
Chang, CC., Letteri, R., Hayward, RC., Emrick, T. “Functional sulfobetaine polymers: Synthesis and salt-responsive stabilization of oil-in-water droplets” Macromolecules, 2015, 48, 7843-7850. DOI: 10.1021/acs.macromol.5b01861
Chen, DY., Chang, CC., Cooper, B., Silvers, A., Emrick T., Hayward, RC. “Photopatternable biodegradable aliphatic polyester with pendent benzophenone groups” Biomacromolecules, 2015, 16, 3329-3335. DOI: 10.1021/acs.biomac.5b00991
Liu, YJ., Chen, YC., Hutchens, S., Lawrence, J., Emrick, T., Crosby, AJ. “Directly measuring the complete stress-strain response of ultrathin polymer films” Macromolecules, 2015, 48, 6534-6540. DOI: 10.1021/acs.macromol.5b01473
Liu, Y., Page, ZA., Russell, TP., Emrick, T. “Finely tuned polymer interlayers enhance solar cell efficiency” Angewandte Chemie-International Edition, 2015, 54, 11485-11489. DOI: 10.1002/anie.201503933
Kim, HJ., Skinner, M., Yu, H., Oh, JH., Briseno, AL., Emrick, T., Kim, BJ., Haryward, RC. “Water processable polythiophene nanowires by photo-cross-linking and click-functionalization” Nano Letters, 2015, 15, 5689-5695. DOI: 10.1021/acs.nanolett.5b01185
Liu, Y., Page, Z., Ferdous, S., Liu, F., Kim, P., Emrick, T., Russell, T. “Dual functional zwitterionic fullerene interlayer for efficient inverted polymer solar cells” Advanced Energy Materials, 2015, 5. DOI: 10.1002/aenm.201500405
Neto, MF., Letteri, R., Chan-Seng, D., Emrick, T., Figueiredo, ML. “Sonodelivery facilitates sustained luciferase expression from an episomal vector in skeletal muscle” Materials, 2015, 8, 4608-4617. DOI: 10.3390/ma8074608
Acevedo-Cartagena, DE., Zhu, JX., Trabanino, E., Pentzer, E., Emrick, T., Nonnenmann, SS., Briseno, AL., Hayward, RC. “Selective nucleation of poly(3-hexyl thiophene) nanofibers on multilayer graphene substrates” ACS Macro Letters, 2015, 4, 483-487. DOI: 10.1021/acsmacrolett.5b00038
Karak, S., Page, ZA., Tinkham, JS., Lahti, PM., Emrick, T., Duzhko, VV. “Raising efficiency of organic solar cells with electrotropic additives” Applied Physics Letters, 2015, 106. DOI: 10.1063/1.4914847
Page, ZA., Liu, F., Russell, TP., Emrick, T. “Tuning the energy gap of conjugated polymer zwitterions for efficient interlayers and solar cells” Journal of Polymer Science Part A-Polymer Chemistry, 2015, 53, 327-336. DOI: 10.1002/pola.27349
Lee, H., Puodziukynaite, E., Zhang, Y., Stephenson, JC., Richter, LJ., Fischer, DA., DeLongchamp, DM., Emrick, T., Briseno, AL. “Poly(sulfobetaine methacrylate)s as electrode modifiers for inverted organic electronics” Journal of the American Chemical Society, 2015, 137, 540-549. DOI: 10.1021/ja512148d
Hu, GJ., Parelkar, SS., Emrick, T. “A facile approach to hydrophilic, reverse zwitterionic, choline phosphate polymers” Polymer Chemistry, 2015, 6, 525-530. DOI: 10.1039/c4py01292e
Baghgar, M., Barnes, A.M., Pentzer, E., Wise, A.J., Hammer, B.A.G., Emrick, T., Dinsmore, A.D. and Barnes, M.D. Morphology-Dependent Electronic Properties in Cross-Linked (P3HT-b-P3MT) Block Copolymer Nanostructures. ACS Nano, 2014, 8(8): 8344-8349. DOI: 10.1021/nn502806d
Carnis, J., Cha, W., Wingert, J., Kang, J., Jiang, Z., Song, S., Sikorski, M., Robert, A., Gutt, C., Chen, S.-W., Dai, Y., Ma, Y., Guo, H., Lurio, L.B., Shpyrko, O., Narayanan, S., Cui, M., Kosif, I., Emrick, T., Russell, T.P., Lee, H.C., Yu, C.-J., Gruebel, G., Sinha, S.K. and Kim, H. Demonstration of Feasibility of X-Ray Free Electron Laser Studies of Dynamics of Nanoparticles in Entangled Polymer Melts. Scientific Reports, 2014, 4. DOI: 10.1038/srep06017
Chang, C.-C. and Emrick, T. Functional Polyolefins Containing Disulfide and Phosphoester Groups: Synthesis and Orthogonal Degradation. Macromolecules, 2014, 47(4): 1344-1350. DOI: 10.1021/ma500121a
Chantarak, S., Liu, F., Emrick, T. and Russell, T.P. Solvent-Assisted Orientation of Poly(3-hexylthiophene)-Functionalized CdSe Nanorods Under an Electric Field. Macromolecular Chemistry and Physics, 2014, 215(17): 1647-1653. DOI: 10.1002/macp.201400188
Ellis, J., Falzon, M., Emrick, T. and Figueiredo, M.L. Imaging Cytokine Targeting to the Tumor/Bone Microenvironment In Vivo. Human Gene Therapy Clinical Development, 2014, 25(4): 200-201.
DOI: 10.1089/humc.2014.085
Hammer, B.A.G., Reyes-Martinez, M.A., Bokel, F.A., Liu, F., Russell, T.P., Hayward, R.C., Briseno, A.L. and Emrick, T. Reversible, Self Cross-Linking Nanowires from Thiol-Functionalized Polythiophene Diblock Copolymers. ACS Applied Materials & Interfaces, 2014, 6(10): 7705-7711. DOI: 10.1021/am500976w
Hammer, B.A.G., Reyes-Martinez, M.A., Bokel, F.A., Liu, F., Russell, T.P., Hayward, R.C., Briseno, A.L. and Emrick, T. Robust polythiophene nanowires cross-linked with functional fullerenes. Journal of Materials Chemistry C, 2014, 2(45): 9674-9682. DOI: 10.1039/c4tc01898b
Kosif, I., Chang, C.C., Bai, Y., Ribbe, A.E., Balazs, A.C. and Emrick, T. Picking up Nanoparticles with Functional Droplets. Advanced Materials Interfaces, 2014, 1(5). DOI: 10.1002/admi.201400121
Lawrence, J., Pham, J.T., Lee, D.Y., Liu, Y., Crosby, A.J. and Emrick, T. Highly conductive ribbons prepared by stick-slip assembly of organosoluble gold nanoparticles. ACS Nano, 2014, 8(2), 1173-1179. DOI: 10.1021/nn4057726.
Lee, C.H., Crosby, A.J., Emrick, T. and Hayward, R.C. Characterization of heterogeneous polyacrylamide hydrogels by tracking of single quantum dots. Macromolecules, 2014, 47(2), 741-749. DOI: 10.1021/ma402373s.
Lee, C.H., Crosby, A.J., Hayward, R.C. and Emrick, T. Patterning nanoparticles into rings by "2-D pickering emulsions". ACS Applied Materials & Interfaces, 2014, 6(7), 4850-4855. DOI: 10.1021/am405828a.
Maiz, J., Zhao, W., Gu, Y., Lawrence, J., Arbe, A., Alegria, A., Emrick, T., Colmenero, J., Russell, T.P. and Mijangos, C. Dynamic study of polystyrene-block-poly(4-vinylpyridine) copolymer in bulk and confined in cylindrical nanopores. Polymer, 2014, 55(16): 4057-4066. DOI: 10.1016/j.polymer.2014.05.042
McRae Page, S., Henchey, E., Chen, X., Schneider, S. and Emrick, T. Efficacy of polyMPC-DOX prodrugs in 4T1 tumor-bearing mice. Molecular Pharmaceutics, 2014, 11(5): 1715-1720. DOI: 10.1021/mp500009r
Miesch, C. and Emrick, T. Photo-sensitive ligands on nanoparticles for achieving triggered emulsion inversion. Journal of Colloid and Interface Science, 2014, 425: 152-158. DOI: 10.1016/j.jcis.2014.03.036
Page, S.M., Henchey, E., Chen, X., Schneider, S. and Emrick, T. Efficacy of PolyMPC-DOX Prodrugs in 4T1 Tumor-Bearing Mice. Molecular Pharmaceutics, 2014, 11(5): 1715-1720. DOI: 10.1021/mp500009r
Page, S.M., Parelkar, S., Gerasimenko, A., Shin, D.Y., Peyton, S.R. and Emrick, T. Promoting cell adhesion on slippery phosphorylcholine hydrogel surfaces. Journal of Materials Chemistry B, 2014, 2(6), 620-624. DOI: 10.1039/c3tb21493a.
Page, Z.A., Liu, Y., Duzhko, V.V., Russell, T.P. and Emrick, T. Fulleropyrrolidine interlayers: Tailoring electrodes to raise organic solar cell efficiency. Science, 2014, 346(6208): 441-444. DOI: 10.1126/science.1255826
Page, Z.A., Liu, F., Russell, T.P. and Emrick, T. Rapid, facile synthesis of conjugated polymer zwitterions in ionic liquids. Chemical Science, 2014, 5(6): 2368-2373. DOI: 10.1039/c4sc00475b
Parelkar, S.S., Letteri, R., Chan-Seng, D., Zolochevska, O., Ellis, J., Figueiredo, M. and Emrick, T. Polymer-peptide delivery platforms: Effect of oligopeptide orientation on polymer-based DNA delivery. Biomacromolecules, 2014, 15(4), 1328-1336. DOI: 10.1021/bm401878p.
Pham, J.T., Lawrence, J., Grason, G.M., Emrick, T. and Crosby, A.J. Stretching of assembled nanoparticle helical springs. Physical Chemistry Chemical Physics, 2014, 16(22): 10261-10266. DOI: 10.1039/c3cp55502j
Puodziukynaite, E., Wang, H.-W., Lawrence, J., Wise, A.J., Russell, T.P., Barnes, M.D. and Emrick, T. Azulene Methacrylate Polymers: Synthesis, Electronic Properties, and Solar Cell Fabrication. Journal of the American Chemical Society, 2014, 136(31): 11043-11049. DOI: 10.1021/ja504670k
Szyndler, M.W., Timmons, J.C., Yang, Z.H., Lesser, A.J. and Emrick, T. Multifunctional deoxybenzoin-based epoxies: Synthesis, mechanical properties, and thermal evaluation. Polymer, 2014, 55(17): 4441-4446. DOI: 10.1016/j.polymer.2014.06.043
Wang, H.-W., Pentzer, E., Emrick, T. and Russell, T.P. Preparation of low band gap fibrillar structures by solvent-induced crystallization. ACS Macro Letters, 2014, 3(1), 30-34. DOI: 10.1021/mz400431s.
Zhang, Y., Diao, Y., Lee, H., Mirabito, T.J., Johnson, R.W., Puodziukynaite, E., John, J., Carter, K.R., Emrick, T., Mannsfed, S.C.B. and Briseno, A.L. Intrinsic and Extrinsic Parameters for Controlling the Growth of Organic Single-Crystalline Nanopillars in Photovoltaics. Nano Letters, 2014, 14(10): 5547-5554. DOI: 10.1021/nl501933q
Emrick, T. and Pentzer, E. Nanoscale assembly into extended and continuous structures and hybrid materials. Nature Asia Materials, 2013, 5. DOI: 10.1038/am.2012.73
Zolochevska, O., Ellis, J., Parelkar, S., Chan-Seng, D., Emrick, T., Wei, JN., Patrikeev, I., Motamedi, M., Figueiredo, ML. “Interleukin-27 gene delivery for modifying malignant interactions between prostate tumor and bone” Human Gene Therapy, 2013, 24, 970-981. DOI: 10.1089/hum.2013.091
Pham, JT., Lawrence, J., Lee, DY., Grason, GM., Emrick, T., Crosby, AJ. “Highly stretchable nanoparticle helices through geometric asymmetry and surface forces” Advanced Materials, 2013, 25, 6703-6708. DOI: 10.1002/adma.201302817
Liu, F., Page, ZA., Duzhko, VV., Russell, TP., Emrick, T. “Conjugated polymeric zwitterions as efficient interlayers in organic solar cells” Advanced Materials, 2013, 25, 6868-6873. DOI: 10.1002/adma.201302477
Pham, JT., Lawrence, J., Lee, DY., Grason, GM., Emrick, T., Crosby, AJ. “Nanoparticle helices: Highly stretchable nanoparticle helices through geometric asymmetry and surface forces” Advanced Materials, 2013, 25, 6635. DOI: 10.1002/adma.201370287
Du, K., Glogowski, E., Tuominen, MT., Emrick, T., Russell, TP., Dinsmore, AD. “Self-assembly of gold nanoparticles on gallium droplets: controlling charge transport through microscopic devices” Langmuir, 2013, 29, 13640-13646. DOI: 10.1021/la403263z
Heo, K., Miesch, C., Emrick, T., Hayward, RC. “Thermally reversible aggregation of gold nanoparticles in polymer nanocomposites through hydrogen bonding” Nano Letters, 2013, 13, 5297-5302. DOI: 10.1021/nl402813q
Cui, MM., Emrick T., Russell, TP. “Stabilizing liquid drops in nonequilibrium shapes by the iinterfacial jamming of nanoparticles” Science, 2013, 342, 460-463. DOI: 10.1126/science.1242852
Baghgar, M., Pentzer, E., Wise, AJ., Labastide, JA., Emrick, T., Barnes, MD. “Cross-linked functionalized poly(3-hexylthiophehe) nanofibers with tunable excitonic coupling” ACS Nano, 2013, 7, 8917-8923. DOI: 10.1021/nn403392b
Herrick, WG., Ngyuen, TV., Sleiman, M., McRae, S., Emrick, TS. “PEG-phosphorylcholine hydrogels as tunable and versatile platforms for mechanobiology” Biomacromolecules, 2013, 14, 2294-2304. DOI: 10.1021/bm400418g
Page, SM., Martorella, M., Parelkar, S., Kosif, I., Emrick, T. “Disulfide cross-linked phosphorylcholine micelles for triggered release of camptothecin” Molecular Pharmaceutics, 2013, 10, 2684-2692. DOI: 10.1021/mp400114n
Han, DZ., Letteri, R., Chan-Seng, D., Emrick, T., Tu, HL. “Examination of zwitterionic polymers and gels subjected to mechanical constraints” Polymer, 2013, 54, 2887-2894. DOI: 10.1016/j.polymer.2013.04.003
Moon, S., Emrick, T. “High flame resistant and strong electrospun polyacrylonitrile-carbon nanotubes-ochre nanofibers” Polymer, 2013, 54, 1813-1819. DOI: 10.1016/j.polymer.2013.01.053
Lee, DY., Pham, JT., Lawrence, J., Lee, CH., Parkos, C., Emrick, T., Crosby, AJ. “Macroscopic nanoparticle ribbons and fabrics” Advanced Materials, 2013, 9, 1248-1253. DOI: 10.1002/adma.201203719
Laprade, EJ., Long, R., Pham, JT., Lawrence, J., Emrick, T., Crosby, AJ., Hui, CY., Shull, KR. “Large deformation and adhesive contact studies of axisymmetric membranes” Langmur, 2013, 5, 1407-1419. DOI: 10.1021/la303810d
Page, ZA., Duzhko, VV., Emrick, T. “Conjugated thiophene-containing polymer zwitterions: Direct synthesis and thin film electronic properties” Macromolecules, 2013, 2, 344-351. DOI: 10.1021/ma302232q
Chen, XJ., Lawrence, J., Parelkar, S., Emrick, T. “Novel zwitterionic copolymers with dihydrolipoic acid: Synthesis and preparation of nonfouling nanorods” Macromolecules, 2013, 1, 119-127. DOI: 10.1021/ma301288m
Kosif, I., Cui, MM., Russell, TP., Emrick, T. “Triggered insitu disruption and inversion of nanoparticle-stabilized droplets” Angewandte Chemie-International Edition, 2013, 52, 6620-6623. DOI: 10.1002/anie.201302112
Bu, L., Pentzer, E., Bokel, F., Emrick, T., Hayward, R. “Growth of polythiophene/perylene tetracarboxydiimide donor/acceptor shish-kebab nanostructures by coupled crystal modification” ACS Nano, 2012, 6, 10924-10929. DOI: 10.1021/nn3043836
Chen, XJ., Parelkar, S., Henchey, E., Schneider, S., Emrick, T. “PolyMPC-doxorubicin prodrugs” Bioconjugate Chemistry, 2012, 23, 1753-1763. DOI: 10.1021/bc200667s
Silvers, A., Chang, CC., Emrick, T. “Functional aliphatic polyesters and nanoparticles prepared by organocatalysis and orthogonal grafting chemistry” Journal of Polymer Science Part A – Polymer Chemistry, 2012, 50, 3517-3529. DOI: 10.1002/pola.26114
Mcrae, S, Chen, XJ., Kratz, K., Samanta, D., Henchey, E., Schneider, S., Emrick, T. “Pentafluorophenyl ester-functionalized phosphorylcholine polymers: Preparation of linear, two-arm, and grafted polymer-protein conjugates” Biomacromolecules, 2012, 13, 2099-2109. DOI: 10.1021/bm3004836
Baghgar, M., Labastide, J., Bokel, F., Dujovne, I., McKenna, A., Barnes, AM., Pentzer, E., Emrick, T., Hayward, R., Barnes, MD. “Probing inter- and intrachain exciton coupling in isolated poly(3-hexylthiophene) nanofibers: Effect of solvation and regioregularity” Journal of Physical Chemistry Letters, 2012, 3, 1674-1679. DOI: 10.1021/jz3005909
Bae, J., Lawrence, J., Miesch, C., Ribbe, A., Li, W., Emrick, T., Zhu, J., Hayward, RC. “Multifunctional nanoparticle-loaded spherical and wormlike micelles formed by interfacial instabilities” Advanced Materials, 2012, 24, 2735-2741. DOI: 10.1002/adma.201200570
Pentzer, EB., Bokel, FA., Hayward, RC., Emrick, T. “Nanocomposite ‘superhighways’ by solution assembly of semiconductor nanostructures with ligand-functionalized conjugated polymers” Advanced Materials, 2012, 24, 2254-2258. DOI: 10.1002/adma.201104788
Kratz, K., Narasimhan, A., Tangirala, R., Moon, SC., Revanu, R., Kundu, S., Kim, HS.,Crosby, AJ., Russell, TP., Emrick, T., Kolmakov, G., Balazs, AC. “Probing and repairing damaged surfaces with nanoparticle-containing microcapsules” Nature Nanotechnology, 2012, 7, 87-90. DOI: 10.1038/NNANO.2011.235
Ravichandran, S., Nagarajan, S., Ku, BC., Coughlin, B., Emrick, T., Kumar, J., Nagarajan, R. “Halogen-free ultra-high flame retardant polymers through enzyme catalysis” Green Chemistry, 2012, 14, 819-824. DOI: 10.1039/c2gc16192c
Miesch, C., Kosif, I., Lee, E., Kim, JK., Russell, TP., Hayward, RC., Emrick, T. “Nanoparticle-stabilized double emulsions and compressed droplets” Angewandte Chemie-International Edition, 2012, 51, 145-149. DOI: 10.1002/anie.201106665
Kratz, K., Xie, W., Lee, A., Freeman, BD., Emrick, T. “Phosphorylcholine-substituted ROMP polyolefin coatings provide fouling resistance to membrane materials” Macromolecular Materials and Engineering, 2011, 296, 1142-1148. DOI: 10.1002/mame.201100064
Elder, RM., Emrick, T., Jayaraman, A. “Understanding the effect of polylysine architecture on DNA binding using molecular dynamics simulations” Biomacromolecules, 2011, 12, 3870-3879. DOI: 10.1021/bm201113y
Hammer, BAG., Bokel, FA., Hayward, RC., Emrick, T. “Cross-linked conjugated polymer fibrils: Robust nanowires from functional polythiophene diblock copolymers” Chemistry of Materials, 2011, 23, 4250-4256. DOI: 10.1021/cm2018345
Ryu, BY., Emrick, T. “Bisphenol-1,2,3-triazole (BPT) epoxies and cyanate esters: Synthesis and self-catalyzed curing” Macromolecules, 2011, 44, 5693-5700. DOI: 10.1021/ma200767j
Lee, E., Hammer, B., Kim, JK., Page, Z., Emrick, T., Hayward, RC. “Hierarchical helical sssembly of conjugated poly(3-hexylthiophene)-block-poly(3-triethylene glycol thiophene) diblock copolymers” Journal of the American Chemical Society, 2011, 133, 10390-10393. DOI: 10.1021/ja2038547
Su, GM., Best, K., Ranganathan, T., Emrick, T., Crosby, AJ. “Tailored nanoparticles for enhancing polymer adhesion” Macromolecules, 2011, 44, 5256-5261. DOI: 10.1021/ma200561g
Li, L., Miesch, C., Sudeep, PK., Balazs, AC., Emrick, T., Russell, TP., Hayward, RC. “Kinetically trapped co-continuous polymer morphologies through intraphase gelation of nanoparticles” Nano Letters, 2011, 11, 1997-2003. DOI: 10.1021/nl200366z
Bokel, FA., Sudeep, PK., Pentzer, E., Emrick, T., Hayward, RC. “Assembly of poly(3-hexylthiophene)/CdSe hybrid nanowires by cocrystallization” Macromolecules, 2011, 44, 1768-1770. DOI: 10.1021/ma2003807
Parelkar, SS., Chan-Seng, D, Emrick, T. “Reconfiguring polylysine architectures for controlling polyplex binding and non-viral transfection” Biomaterials, 2011, 32, 2432-2444. DOI: 10.1016/j.biomaterials.2010.12.004
Pochan, DJ., Zhu, JH., Zhang, K., Wooley, KL., Miesch, C., Emrick, T. “Multicompartment and multigeometry nanoparticle assembly” Soft Matter, 2011, 7, 2500-2506. DOI: 10.1039/c0sm00960a
Kim, HS., Lee, CH., Sudeep, PK., Emrick, T., Crosby, A. “Nanoparticle stripes, grids, and ribbons produced by flow coating” Advanced Materials, 2010, 22, 4600-4604. DOI: 10.1002/adma.201001892
Hu, Y., Samanta, D., Parelkar, S., Hong, SW., Wang, Q., Russell, T., Emrick, T. “Ferritin-polymer conjugates: Grafting chemistry and integration into nanoscale assemblies.” Advanced Function Materials, 2010, 20, 3603-3612. DOI: 10.1002/adfm.201000958
Ryu, BY., Emrick, T. “Thermally induced structural transformation of bisphenol-1,2,3-triazole polymers: Smart, self-extinguishing materials” Angewandte Chemie-International Edition, 2010, 49, 9644-9647. DOI: 10.1002/anie.201005456
Chen, XJ., McRae, S., Samanta, D., Emrick, T. “Polymer-protein conjugation in ionic liquids” Macromolecules, 2010, 43, 6261-6263. DOI: 10.1021/ma101156e
Du, K., Glogowski, E., Emrick, T., Russell, TP., Dinsmore, AD. “Adsorption energy of nano- and microparticles at liquid-liquid interfaces” Langmuir, 2010, 26, 12518-12522. DOI: 10.1021/la100497h
Hu YX., Chen, DA., Park, S., Emrick, T., Russell, TP. “Guided assemblies of ferritin nanocages: Highly ordered arrays of monodisperse nanoscopic elements” Advanced Materials, 2010, 22, 2583-2587. DOI: 10.1002/adma.200903578
Early, KT., Sudeep, PK., Emrick, T., Barnes, MD. “Polarization-driven stark shifts in quantum dot luminescence from single CdSe/oligo-PPV nanoparticles” Nano Letters, 2010, 10, 1754-1758. DOI: 10.1021/nl1001789
Ranganathan, T., Cossette, P., Emrick, T. “Halogen-free, low flammability polyurethanes derived from deoxybenzoin-based monomers” Journal of Materials Chemistry, 2010, 20, 3681-3687. DOI: 10.1039/b924034a
Lee, JU., Jung, JW., Emrick, T., Russell, TP., Jo, WH. “Synthesis of C-60-end capped P3HT and its application for high performance of P3HT/PCBM bulk heterojunction solar cells” Journal of Materials Chemistry, 2010, 20, 3287-3294. DOI: 10.1039/b923752f
Joralemon, MJ., Mcrae, S., Emrick, T. “PEGylated polymers for medicine: From conjugation to self-assembled systems” Chemical Communications, 2010, 46, 1377-1393. DOI: 10.1039/b920570p
Lee, JU., Jung, JW., Emrick, T., Russell, TP., Jo, WH. “Morphology control of a polythiophene-fullerene bulk heterojunction for enhancement of the high-temperature stability of solar cell performance by a new donor-acceptor diblock copolymer” Nanotechnology, 2010, 21. DOI: 10.1088/0957-4484/21/10/105201
Kolmakov, GV., Revanur, R., Tangirala, R., Emrick, T., Russell, TP., Crosby, AJ., Balazs, AC. “Using nanoparticle-filled microcapsules for site-specific healing of damaged substrates: Creating a "repair-and-go" system” ACS Nano, 2010, 4, 1115-1123. DOI: 10.1021/nn901296y
Niu, ZW., Kabispatpathy, S., He, JB., Lee, LA., Rong, JH., Yang, L., Sikha, G., Popov, BN., Emrick, TS., Russell, TP., Wang, Q. “Synthesis and characterization of bionanoparticle-silica composites and mesoporous silica with large pores” Nano Research, 2009, 2, 474-485. DOI: 10.1007/s12274-009-9043-6
Sudeep, PK., Emrick, T. “Functional Si and CdSe quantum dots: Synthesis, conjugate formation, and photoluminescence” ACS Nano, 2009, 3, 4105-4109. DOI: 10.1021/nn901016u
Chen, XJ., McRae, S., Parelkar, S., Emrick, T. “Polymeric phosphorylcholine-camptothecin conjugates prepared by controlled free radical polymerization and click chemistry” Bioconjugate Chemistry, 2009, 20, 2331-2341. DOI: 10.1021/bc900339x
Cooper, BM., Emrick, T. “Sequential and localized grafting on aliphatic polyester diblock copolymers using alkyne deprotection and click cycladdition” Journal of Polymer Science Part A – Polymer Chemistry, 2009, 47, 7054-7065. DOI: 10.1002/pola.23745
Sudeep, PK., Emrick, T. “Pearls of wisdom: Stringing nanoparticles and polymers into new assemblies and materials” ACS Nano, 2009, 3, 2870-2875. DOI: 10.1021/nn901358a
Du, K., Knutson, CR., Glogowski, E., McCarthy, KD., Shenhar, R., Rotello, VM., Tuominen, MT., Emrick, T., Russell, TP., Dinsmore, AD. “Self-assembled electrical contact to nanoparticles using metallic droplets” Small, 2009, 5, 1974-1977. DOI: 10.1002/smll.200900203
Chan-Seng, D., Ranganathan, T., Zhang, XF., Tang, YW., Lin, Q.; Kleiner, L., Emrick, T. “Aliphatic polyester terpolymers for stent coating and drug elution: Effect of polymer composition on drug solubility and release” Drug Delivery, 2009, 16, 304-311. DOI: 10.1080/10717540902999653
Doi, MY., Early, KT., Tangirala, R., Sudeep, PK., Emrick, T., Barnes, MD. “Probing multiexcitonic emission in single CdSe-Oligo(phenylenevinylene) composite nanostructures” Journal of Physical Chemistry, 2009, 113, 13462-13465. DOI: 10.1021/jp9051787
Kratz, K., Breitenkamp, K., Hule, R., Pochan, D., Emrick, T. "PC-Polyolefins: Synthesis and assembly behavior in water" Macromolecules, 2009, 42, 3227-3229. DOI: 10.1021/ma900653h
He, JB., Niu, ZW., Tangirala, R., Wan, JY., Wei, XY., Kaur, G., Wang, Q., Jutz, G., Boeker, A., Lee, B., Pingali, SV., Thiyagaran, P., Emrick, T., Russell, TP. "Self-assembly of tobacco mosaic virus at oil/water interfaces" Langmuir, 2009, 25, 4979-4987. DOI: 10.1021/la803533n
Kaur, G., He, JB., Xu, J., Pingali, SV., Jutz, G., Boker, A., Niu, ZW., Li, T., Rawlinson, D., Emrick, T., Lee, B., Thiyagarajan, P., Russell, TP., Wang, Q. "Interfacial assembly of turnip yellow mosaic virus nanoparticles" Langmuir, 2009, 25, 5168-5176. DOI: 10.1021/la900167s
Tangirala, R., Hu YX., Joralemon, M., Zhang, QL., He, JB., Russell, TP., Emrick, T. "Connecting quantum dots and bionanoparticles in hybrid nanoscale ultra-thin films" Soft Matter, 2009, 5, 1048-1054. DOI: 10.1039/b807757f
Chen, D., Chen, JT., Glogowski, E., Emrick, T., Russell, TP. "Thin film instabilities in blends under cylindrical confinement" Macromolecular Rapid Communications, 2009, 30, 377-383. DOI: 10.1002/marc.200800730
Lee, JU., Cirpan, A., Emrick, T., Russell, TP., Jo, WH. "Synthesis and photophysical property of well-defined donor-acceptor diblock copolymers based on regioregular poly(3-hexythiophene) and fullerene" Journal of Materials Chemistry, 2009, 19, 1483-1489. DOI: 10.1039/b813368a
Early, KT., McCarthy, KD., Odoi MY., Sudeep, PK., Emrick, T., Barnes, MD. "Linear dipole behavior in single CdSe-Oligo(phenylene vinylene) nanostructures" ACS Nano, 2009, 3, 453-461. DOI: 10.1021/nn800785s
Zhang, QL., Cirpan, A., Russell, TP., Emrick, T. "Donor-acceptor poly(thiophene-block-perylene diimide) copolymers: Synthesis and solar cell fabrication" Macromolecules, 2009, 42, 1079-1082. DOI: 10.1021/ma801504e
Ryu, BY., Moon, S., Kosif, I., Ranganathan, T., Farris, RJ., Emrick, T. "Deoxybenzoin-based epoxy resins" Polymer, 2009, 50, 767-774. DOI: 10.1016/j.polymer.2008.12.009
Cooper, BM., Chan-Seng, D., Samanta, D., Zhang, XF., Parelkar, S., Emrick, T. “Polyester-graft-phosphorylcholine prepared by ring-opening polymerization and click chemistry” Chem. Commun. 2009, 7, 815-817. DOI: 10.1039/b817600k
Moon, S., Ku, B.C., Emrick, T., Coughlin, BE., Farris, RJ. “Flame resistant electrospun polymer nanofibers from deoxybenzoin” Journal of Applied Polymer Science, 2009, 111, 301-307. DOI: 10.1002/app.29067
Sudeep, PK., Page, Z., Emrick, T. “PEGylated silicon nanoparticles: Synthesis and characterization” Chemical Communications, 2008, 46, 6126-6127. DOI: 10.1039/b813025f
Li, T., Niu, Z., Emrick, T., Russell TR., Wang, Q. “Core/Shell biocomposites from the hierarchical assembly of bionanoparticles and polymer” Small, 2008, 4, 1624-1629. DOI: 10.1002/smll.200800403
Samanta, D., McRae, S., Cooper, B., Hu, Y., Emrick, T. “End-functionalized phosphorylcholine methacrylates and their use in protein conjugation” Biomacromolecules, 2008, 9, 2891-2897. DOI: 10.1021/bm8006715
Breitenkamp, RB., Emrick, T. “Pentalysine-grafted ROMP polymers for DNA complexation and delivery” Biomacromolecules, 2008, 9, 2495-2500. DOI: 10.1021/bm800511p
Mark, P.R.; Murthy, N.S.; Weigand, S.; Breitenkamp, K.; Kade, M.; Emrick, T. “Microphase separated structures in the solid and molten states of double-crystal graft copolymers of polyethylene and poly(ethylene oxide)” Polymer, 2008, 49, 3116-3124. DOI: 10.1016/j.polymer.2008.05.012
Lyon, R.E.; Emrick, T. “Non-halogen fire resistant plastics for aircraft interiors” Polymers for Advanced Technologies, 2008, 19, 609-619. DOI: 10.1002/pat.1126
Ranganathan, T.; Beaulieu, M.; Ziberman, J.; Smith, K.D.; Westmoreland, P.R.; Farris, R.J.; Coughlin, E.B.; Emrick, T. “Thermal degradation of deoxybenzoin polymers studied by pyrolysis-gas chromatography/mass spectrometry” Polymer Degradation and Stability, 2008, 93, 1059-1066. DOI: 10.1016/j.polymdegradstab.2008.03.021
Li, Q.F; He, J.B.; Glogowski, E.; Li, X.F.; Wang, J.; Emrick, T.; Russell, T.P. “Responsive assemblies: Gold nanoparticles with mixed ligands in microphase separated block copolymers” Advanced Materials 2008, 20, 1462-1466. DOI: 10.1002/adma.200702004
Rathnayake, H.P.; Emrick, T. “Grafting-from nanoparticles using aldol group transfer polymerization” Macromolecules 2008, 41, 2969-2971. DOI: 10.1021/ma800571c
Bae, J.; Glogowski, E.; Gupta, S.; Chen, W.; Emrick, T.; Russell, T.P. “Effect of nanoparticles on the electrohydrodynamic instabilities of polymer/nanoparticle thin films” Macromolecules 2008, 41, 2722-2726. DOI: 10.1021/ma702750y
Bruckman, M.A.; Kaur, G.; Lee, L.A.; Xie, F.; Sepulvecla, J.; Breitenkamp, R.; Zhang, X.; Joralemon, M.; Russell, T.P; Emrick, T.; Wang, Q. “Surface modification of tobacco mosaic virus with “Click” chemistry” Chembiochem 2008, 9, 519-523. DOI: 10.1002/cbic.200700559
Sudeep, P.K.; Early, K.T.; McCarthy, K.D.; Odoi, M.Y.; Barnes, M.D.; Emrick, T. “Monodisperse oligo(phenylene vinylene) ligands on CdSe quantum dots: Synthesis and polarization anisotropy measurements” J. Am. Chem. Soc. 2008, 130, 2384-2385. DOI: 10.1021/ja077409
Samanta, D.; Kratz, K.; Zhang, X.; Emrick, T. “A synthesis of PEG- and phosphorylcholine-substituted pyridines to afford water-soluble ruthenium benzylidene metathesis catalysts” Macromolecules 2008, 41, 530-532. DOI: 0.1021/ma7019732
Hammer, N.I.; Emrick, T.; Barnes, M.D. “Quantum dots coordinated with conjugated organic ligands: new nanomaterials with novel photophysics” Nanoscale Research Letters 2007, 2, 282-290. DOI: 10.1007/s11671-007-9062-8
Odoi, M.Y.; Hammer, N.I.; Early, K.T.; McCarthy, K.D.; Tangirala, R.; Emrick, T.; Barnes, MD. “Fluorescence lifetimes and correlated photon statistics from single CdSe/oligo(phenylene vinylene) composite nanostructures” NanoLetters 2007, 7, 2769-2773. DOI: 10.1021/nl0713068
Early, KT.; McCarthy, KD.; Hammer, NI.; Odoi, MY.; Tangirala, R.; Emrick, T.; Barnes, MD. “Blinking suppression and intensity recurrences in single CdSe-oligo(phenylene vinylene) nanostructures: experiment and kinetic model” Nanotechnology 2007, 18. DOI: 10.1088/0957-4484/18/42/424027
Breitenkamp, R.B.; Ou, Z.; Breitenkamp, K.; Muthukumar, M.; Emrick, T. “Synthesis and Characterization of polyolefin-graft-oligopeptide polyelectrolytes” Macromolecules 2007, 40, 7617-7624. DOI: 10.1021/ma070714v
Boker, A.; He, J.; Emrick, T.; Russell, TP. “Self-assembly of nanoparticles at interfaces” Soft Matter 2007, 3, 1231-1248. DOI: 10.1039/b706609k
Kutuzov, S.; He, J.; Tangirala, R.; Emrick, T.; Russell, TP.; Boker, A. “On the kinetics of nanoparticle self-assembly at liquid/liquid interfaces“ Physical Chemistry Chemical Physics 2007, 9, 6351-6358. DOI: 10.1039/b710060b
Ranganathan, T.; Ku, B.C.; Zilberman, J.; Beaulieu, M.; Farris, R.J.; Coughlin, E.B.; Emrick, T. “Poly(arylate-phosphonate) copolymers with deoxybenzoin in the backbone: synthesis, characterization, and thermal properties” J. Polym. Sci. A.: Polym. Chem. 2007, 45, 4573-4580. DOI: 10.1002/pola.22188
Sudeep, PK; Emrick, T. “Polymer-nanoparticle composites: Preparative methods and electronically active materials” Polymer Reviews 2007, 47, 155-163. DOI: 10.1080/15583720701271229
Huang, J; Juskiewicz, M; de Jeu, WH; Cerda, E; Emrick, T; Menon, N; Russell, TP. “Capillary wrinkling of floating thin polymer films” Science 2007, 317, 650-653. DOI: 10.1126/science.1144616
He, J; Zhang, Q; Gupta, S; Emrick, T; Russell, TR; Thiyagarajan, P. “Drying Droplets: A window into the behavior of nanorods at interfaces” Small, 2007, 3, 1214-1217. DOI: 10.1002/smll.200700055
Lee, JY; Zhang, Q.; Wang, JY; Emrick T; Crosby, A.J. “Failure mechanism of glassy polymer-nanoparticle composites” Macromolecules, 2007, 40, 6406-6412. DOI: 10.1021/ma0710479
Zhang, Q.; Russell, T.P.; Emrick, T. “Synthesis and Characterization of CdSe Nanorods Functionalized with Regioregular Poly(3-hexylthiophene)’ Chem. Mater., 2007, 19, 3712-3716. DOI: 10.1021/cm070603a
Revanur, R.; McCloskey, B.; Breitenkamp, K.; Freeman, B.D.; Emrick, T. “Reactive amphiphilic graft copolymer coatings applied to poly(vinylidene fluoride) ultrafiltration membranes,” Macromolecules, 2007, 40, 3624-3630. DOI: 10.1021/ma0701033
Glogowski, E.; Tangirala, R.; He, J.B.; Russell, T.P.; Emrick, T. “Microcapsules of PEGylated gold nanoparticles prepared by fluid-fluid interfacial assembly,” NanoLetters, 2007, 7, 389-393. DOI: 10.1021/nl062581h
He, J.B.; Tangirala, R.; Emrick, T.; Russell, T.P. “Self-assembly of nanoparticle-copolymer mixtures: A kinetic point of view,” Advanced Materials, 2007 19, 381-386. DOI: 10.1002/adma.200602094
Zou, S.; Hong, R.; Emrick, T.; Walker, G. “Ordered CdSe nanoparticles within self-assembled block copolymer domains on surfaces,” Langmuir, 2007, 23, 1612-1614. DOI: 10.1021/la0629274
Tangirala R.; Revanur R.; Russell T.P.; Emrick T. “Sizing nanoparticle-covered droplets by extrusion through track-etch membranes,” Langmuir, 2007, 23, 965-969. DOI: 10.1021/la061575y
Parrish B.; Emrick T. “Soluble camptothecin derivatives prepared by click cycloaddition chemistry on functional aliphatic polyesters,” Bioconjugate Chemistry, 2007, 18, 263-267. DOI: 10.1021/bc060201d
Hammer, NI., Emrick, T., Barnes, MD. “Quantum dots coordinated with conjugated organic ligands: new nanomaterials with novel photophysics” Nanoscale Research Letters, 2007, 2, 282-290. DOI: 10.1007/s11671-007-9062-8
Hong, R; Fernandez, J.M; Nakade, H; Emrick, T; “In situ observation of place exchange reactions of gold nanoparticles: Correlation of monolayer structure and stability”, Chemical Communications, 2006, 22: 2347-2349. DOI: 10.1039/b603988j
Balazs, A.C.; Emrick, T.; Russell, T.P. “Nanoparticle-polymer Composites: Where Two Small Worlds Meet” Science, 2006, 314, 1107-1110. DOI: 10.1126/science.1130557
Zhang, Q.L.; Gupta, S.; Emrick, T.; Russell, T.P. “Surface-functionalized CdSe nanorods for assembly in diblock copolymer templates,” J. Am. Chem. Soc. 2006, 128, 3898-3899. DOI: 10.1021/ja058615p
Gupta, S; Zhang, Q.L.; Emrick, T.; Russell, T.P. “Self-corralling" nanorods under an applied electric field” NanoLetters 2006, 6, 2066-2069. DOI: 10.1021/nl061336v
Ranganathan T., Zilberman J., Farris R.J., Coughlin E.B., Emrick T. “Synthesis and characterization of halogen-free antiflammable polyphosphonates containing 4,4'-bishydroxydeoxybenzoin”, Macromolecules 2006, 39, 5974-5975. DOI: 10.1021/ma0614693
Jordan B.J., Hong R., Gider B., Hill J., Emrick T., Rotello, V.M. “Stabilization of alpha-chymotrypsin at air-water interface through surface binding to gold nanoparticle scaffolds” Soft Matter 2 (7): 558-560 2006 DOI: 10.1039/b603980d
Glogowski E., Tangirala R., Russell T.P., Emrick T. “Functionalization of nanoparticles for dispersion in polymers and assembly in fluids” J. Polym. Sci. A: Polym. Chem. 44 (17): 5076-5086 2006 DOI: 10.1002/pola.21598
Hammer N.I., Early K.T., Sill K., Odoi M.Y., Emrick T., Barnes M.D. “Coverage-mediated suppression of blinking in solid state quantum dot conjugated organic composite nanostructures”, J. Phys. Chem. B. 2006, 110, 14167-14171. DOI: 10.1021/jp062065f
Niu Z.W., Bruckman M., Kotakadi V.S., He J.B., Emrick T., Russell T.P., Yang L., Wang Q. “Study and characterization of tobacco mosaic virus head-to-tail assembly assisted by aniline polymerization”, Chem. Commun. 2006, 28, 3019-3021. DOI: 10.1039/b603780a
Lee J.Y., Zhand Q.L., Emrick T., Crosby A.J. “ Nanoparticle alignment and repulsion during failure of glassy polymer nanocomposites” Macromolecules 2006, 39, 7392-7396. DOI: 10.1021/ma061210k
Cardoen G. Breitenkamp K., Emrick T., Coughlin E.B. “Manifold assembly for the convenient polymerization of ethylene oxide and butadiene” Macromolecules 2006, 39, 7170-7173. DOI: 10.1021/ma061379y
Ellzey, K.A., Ranganathan, T., Zilberman, J., Coughlin, EB; Farris, R.J., Emrick, T. “Deoxybenzoin-based Polyarylates as Halogen-free Fire-resistant Polymers”, Macromolecules 2006, 39, 3553-3558. DOI: 10.1021/ma052777o
Gupta, S.; Zhang, QL.; Emrick, T.; Balazs, A.C.; Russell, T.P. “Entropy-driven Segregation of Nanoparticles to Cracks: A Route to Self-healing Systems,” Nature Materials 2006, 5, 229-233. DOI: 10.1038/nmat1582
Odoi, M.Y.; Hammer, N.I.; Sill, K.; Emrick, T.; Barnes, M.D. “Observation of enhanced energy transfer in individual quantum dot-oligophenylene vinylene nanostructures” J. Am. Chem. Soc. 2006, 128, 3506-3507. DOI: 10.1021/ja058429j
Glogowski, E.; He, J.B.; Russell, T.P.; Emrick, T. “Mixed monolayer coverage on gold nanoparticles for interfacial stabilization of immiscible fluids,” Chem. Commun. 2005, 32, 4050-4052. DOI: 10.1039/b503670d
Parrish, B.; Breitenkamp, R.B.; Emrick, T. “PEG and Peptide-grafted Aliphatic Polyesters by Click Chemistry” J. Am. Chem. Soc., 2005, 127, 7404-7410. DOI: 10.1021/ja050310n
Skaff, H.; Lin, Y.; Tangirala, R.; Breitenkamp, K.; Boker, A.; Russell, T.P.; Emrick, T. “Cross-linked Capsules of Quantum Dots by Interfacial Assembly and Ligand Cross-linking” Adv. Mater. 2005, 17, 2082-2085. DOI: 10.1002/adma.200500587
Sill, K.; Emrick, T. “Bis-dendritic Polyethylene Prepared by Ring-opening Metathesis Polymerization in the Presence of Bis-dendritic Chain Transfer Agents”, J. Polym. Sci. A.: Polym. Chem. 2005, 43, 5429-5439. DOI: 10.1002/pola.20995
Breitenkamp, K.; Emrick, T. “Amphiphilic Ruthenium Benzylidene Metathesis Catalysts with PEG-substituted Pyridine Ligands,” J. Polym. Sci. A.: Polym. Chem. 2005, 43, 5715-5721. DOI: 10.1002/pola.21061
Russell, J.T.; Lin, Y.; Boker, A.; Su, L; Carl, P.; Zettl, H.; He, J.B.; Sill, K.; Tangirala, R.; Emrick, T.; Littrell, K.; Thiyagarajan, P.; Cookson, D.; Fery, A.; Wang, Q.; Russell, T.P. “Self-assembly and Cross-linking of Bionanoparticles at Liquid-Liquid Interfaces,” Angew. Chem. Int. Ed. 2005, 44, 2420-2426. DOI: 10.1002/anie.200462653
Lin, Y.; Boker, A.; He, J.B.; Sill, K.; Xiang, H.Q.; Abetz, C.; Li, X.F.; Wang, J.; Emrick, T.; Long, S.; Wang, Q.; Balas, A.; Russell, T.P. “Self-directed Self-assembly of Nanoparticle/copolymer Mixtures” Nature 2005, 434, 55-59. DOI: 10.1038/nature03310
Zhang, Q.; Xu, T.; Butterfield, D.; Misner, M.J.; Ryu, D.Y.; Emrick, T.; Russell, T.P. “Controlled Placement of CdSe Nanoparticles in Diblock Copolymer Templates by Electrophoretic Deposition” NanoLetters 2005, 5, 357-361. DOI: 10.1021/nl048103t
Ki, C.D.; Emrick, T.; Chang, J.Y. “Preparation of Functional Nanoporous Silica for Encapsulation of CdSe Nanoparticles”, Adv. Mater. 2005, 17, 230-233. DOI: 10.1002/adma.200400184
Lin, Y.; Boeker, A.; Skaff, H.; Cookson, D.; Dinsmore, A.D.; Emrick, T.; Russell, T.P. “Nanoparticle Assembly at Fluid Interfaces: Structure and Dynamics” Langmuir, 2005, 21, 191-194. DOI: 10.1021/la048000q
Hong, R.; Fischer, N.O.; Emrick, T.; Rotello, V.M. “Surface PEGylation and Ligand Exchange Chemistry of FePt Nanoparticles for Biological Applications” Chem. Mater. 2005, 17, 4617-4621. DOI: 10.1021/cm0507819
Skaff, H.; Emrick, T. “Reversible Addition-Fragmentation Chain Transfer Polymerization from the Surface of Unprotected CdSe Nanoparticles” Angew. Chem. Int. Ed. 2004, 43, 5383-5386. DOI: 10.1002/anie.200453822
Skaff, H.; Sill, K.; Emrick, T. “Quantum Dots Tailored with Poly(para-phenylene vinylene)” J. Am. Chem. Soc. 2004, 126, 11322-11325. DOI: 10.1021/ja047260r
Parrish, B.; Emrick, T. “Aliphatic Polyesters with Pendant Cyclopentene Groups: Controlled Synthesis and Conversion to Polyester-graft-PEG Copolymers” Macromolecules 2004, 37, 5863-5865. DOI: 10.1021/ma048981d
Boeker, A.; Lin, T.; Chiapperini, K.; Horowitz, R.; Thompson, M.; Carreon, V.; Xu, T.; Abetz, C.; Skaff, H.; Dinsmore, A.D.; Emrick, T.; Russell, T.P. “Hierarchical Nanoparticle Assemblies Formed by Decorating Breath Figures” Nature Materials 2004, 3, 302-306. DOI: 10.1038/nmat1110
Sill, K.; Emrick, T. “Nitroxide-Mediated Radical Polymerization from CdSe Nanoparticles”, Chemistry of Materials, 2004, 16, 1240-1243. DOI: 10.1021/cm035077b
Hong, R.; Fisher, N.O.; Verma, A.; Goodman, C.M.; Emrick, T.; Rotello, V.M. “Control of Protein Structure and Function through Surface Recognition by Tailored Nanoparticle Scaffolds” J. Am. Chem. Soc. 2004, 126, 739-743. DOI: 10.1021/ja037470o
Hong, R.; Emrick, T.; Rotello, V.M. “Monolayer-controlled Substrate Selectivity using Non-covalent Enzyme-Nanoparticle Conjugates” J. Am. Chem. Soc. 2004, 126, 13572-13573. DOI: 10.1021/ja0461163
Breitenkamp, K.; Emrick, T. “Novel Polymer Capsules from Amphiphilic Graft Copolymers and Ring-opening Cross Metathesis” J. Am. Chem. Soc. 2003, 125, 12070-12071. DOI: 10.1021/ja036561i
Lin Y.; Skaff, H.; Boker, A.; Dinsmore, A.D.; Emrick, T.; Russell, T.P. “Ultrathin Cross-linked Nanoparticle Membranes” J. Am. Chem. Soc. 2003, 125, 12690-12691. DOI: 10.1021/ja036919a
Lin, Y.; Skaff, H.; Emrick, T.; Dinsmore, A.D.; Russell, T.P. “Nanoparticle assembly and transport at liquid-liquid interfaces” Science 2003, 299, 226-229. DOI: 10.1126/science.1078616
Misner, M.J.; Skaff, H.; Emrick, T.; Russell, T.P. "Directed Deposition of Nanoparticles using Diblock Copolymer Templates" Advanced Materials, 2003, 15, 221-224. DOI: 10.1002/adma.200390050
Skaff, H.; Emrick, T. "The Use of 4-Substituted Pyridines to Afford Amphiphilic, PEGylated Cadmium Selenide Nanoparticles" Chem. Comm. 2003, 52-53. DOI: 10.1039/b208718a
Ellzey, K.A.; Farris, R.J.; Emrick, T. “Synthetic and Thermal Studies of Bisphenol-C Containing Poly(aryletherketone)” Polym. Bull. 2003, 50, 235-242.
Evans, RN., Gilardi, R., Emrick, T. “1-(p-biphenyl)-4 '-(2-naphthyl)cubane” Acta Crystallographica Section E-Structure Reports Online, 2003, 59, O1283-O1285. DOI: 10.1107/S160053803017483
Breitenkamp, K.; Simeone, J.; Jin, E.; Emrick, T. "Novel Amphiphilic Graft Copolymers Prepared by Ring-opening Metathesis Polymerization of Poly(ethylene glycol)-Substituted Cyclooctene Macromonomers” Macromolecules 2002, 35, 9249-9252.
Parrish, B.; Quansah, J.K.; Emrick, T. "Functional Polyesters Prepared by Polymerization of a-Allyl(d-valerolactone), and its Copolymerization with e-Caprolactone and d-Valerolactone" J. Polym. Sci. Part A: Polym. Chem. 2002, 40, 1983-1990.
Skaff, H.; Ilker, M.F.; Coughlin, E.B.; Emrick, T. “Preparation of Cadmium Selenide-Polyolefin Composites from Functional Phosphine Oxides and Ruthenium-based Metathesis” J. Am. Chem. Soc. 2002, 124, 5729-5733.
Emrick, T.; Chang, H-T.; Fréchet, J.M.J. "The Preparation of Hyperbranched Aromatic and Aliphatic Polyether Epoxies by Chloride-Catalyzed Proton Transfer Polymerization from AB(n) and A(2) + B-3 Monomers" J. Polym. Sci. Part A: Polym. Chem. 2000, 33, 4850. DOI: 10.1002/1099-0518(200012)38:1+<4850::AID-POLA230>3.0.CO;2-G
Hecht, S.; Emrick, T.; Fréchet, J.M.J. "Hyperbranched Porphyrins - A Rapid Synthetic Approach To Multiporphyrin Macromolecules" Chem. Commun. 2000, 313. DOI: 10.1039/a909258g
Emrick, T.; Chang, H.T.; Fréchet, J.M.J., Baccei, L., Woods, J. "Hyperbranched Aromatic Epoxies in the Design of Adhesive Materials" Polym. Bull. 2000, 45, 1. DOI: 10.1007/s002890070049
Emrick, T.; Chang, H-T.; Fréchet, J.M.J "An A(2)+B-3 Approach to Hyperbranched Aliphatic Polyethers Containing Chain End Epoxy Substituents" Macromolecules 1999, 32, 6380. DOI: 10.1021/ma990687b
Emrick, T.; Hayes, W.; Fréchet, J.M.J. "A TEMPO Mediated “Living” Free Radical Approach to ABA Triblock Dendritic-Linear Hybrid Copolymers" J. Polym. Sci. Part A: Polym. Chem. 1999, 37, 3748. DOI: 10.1002/(SICI)1099-0518(19991015)37:20<3748::AID-POLA2>3.3.CO;2-8
Emrick, T; Fréchet, J.M.J. "Self-Assembly of Dendritic Structures" Curr. Opin. Coll. In. Sci. 1999, 4, 15-23. DOI: 10.1016/S1359-0294(99)00008-4
Eaton, P.E.; Pramod, K.; Emrick, T., Gilardi, R. "Building with Cubane-1,4-diyl. Synthesis of Aryl Substituted Cubanes, p-[n]Cubyls, and Cubane Separated Bis-Arenes" J. Am. Chem. Soc. 1999, 121, 4111. DOI: 10.1021/ja983441f
Yildrim, T., Kilic, C., Ciraci, S., Gehring, PM., Neumann, DA., Eaton, PE., Emrick, T. “Vibrations of the cubane molecule: inelastic neutron scattering study and theory” Chemical Physics Letters, 1999, 309, 234-240. DOI: 10.1016/S0009-2614(99)00655-7
Yildrim, T., Gehring, PM., Neumann, DA., Eaton, PE., Emrick, T. “Neutron-scattering investigation of molecular reorientations in solid cubane” Physical Review B, 1999, 60, 314-321. DOI: 10.1103/PhysRevB.60.314
Yildirim, T.; Gehring, P.M.; Neumann D.A.; Eaton, P.E.; Emrick, T. "Solid Cubane: A Brief Review" Carbon 1998, 36, 809.
Yildrim, T., Gehring, PM., Neumann, DA., Eaton, PE., Emrick, T. “Unusual structure, phase transition, and dynamics of solid cubane” Physical Review Letters, 1997, 78, 4938-4941. DOI: 10.1103/PhysRevLett.78.4938
Hare, M.; Emrick, T.; Eaton, P.E.; Kass, S.R. "Cubyl Anion Formation and an Experimental Determination of the Acidity and C-H Bond Dissociation Energy of Cubane" J. Am. Chem. Soc. 1997, 119, 237.
Engling, G.; Emrick, T.; Hellmann, J.; McElroy, E.; Brandt, M.; Reingold, I.D. "A Novel Approach to Bicyclo[3.3.0]octane-2,8-dione" J. Org. Chem. 1994, 59, 1945-1946.