Clean Energy for the Commonwealth

A report of the UMass system-wide Clean Energy Working Group (2008) [PDF]

 

Harvest

Nearly all energy is solar energy, stored in different forms. Today, more than ever, advanced technologies are needed to improve energy harvest and conversion efficiency.

Faculty & Research
(Print All Faculty Profiles)

Marc Acherman
Time-Resolved Spectroscopy of Functional Nanomaterials

Neal Anderson
Nanostructured Photovoltaics

Scott Auerbach
Theory and Simulation of Nanoporous Materials for Renewable Energy Materials & Devices

Michael Barnes
Single-Molecule Spectroscopy, Polymer-Based Nanoscale Photonics

Jeffrey Blanchard
Climate Change: Global Effects of Populations of Marine Cyanobacteria

Ken Carter
Functional Polymeric Nanostructures

W. Curtis Conner
Biomass Refinement Catalysts

Bryan Coughlin
Synthesis of Polymer Nanocomposites for Renewable Energy Materials and Devices

Samuel Gido
Self-assembling Nanostructures

Jeanne Hardy
Organic/Inorganic Composite Fuel Cell Membranes

Michael Henson
Nonlinear Systems Modeling and Analysis

Stephen Herbert
Renewable Energy Crop Agronomy

George Huber
Catalytic Processes for Biofuels and Biochemicals Production

Robert Hyers
Condition Monitoring and Prognosis in Wind Turbines

Bret Jackson
Theoretical Studies of Reactions on Surfaces

Susan Leschine
Fuels from Biomass: Microbially Mediated Production of Cellulosic Ethanol

Derek Lovley
Microbial Fuel Cells

James Manwell
Wind Power and Distributed Energy

Michael Maroney
Biohybrid Catalysts

Jon McGowan
Wind Power and Distributed Energy

Murugappan Muthukumar
Theory and Modeling of Polymer Crystallization

Klaus Nusslein
Unconventional Fossil Fuels Recovery

Om Parkash
Plant Biotechnology for Development of Improved "Energy Crops"

Steven Petsch
Unconventional Fossil Fuels Recovery

Thomas Russell
Polymers and Block Copolymers for Nanostructured Energy Devices

Danny Schnell
Primary Productivity: Feedstock Optimization for Production of Biofuels and Bioproducts

Sankaran Thayumanavan
Polymers and Nanoscale Assemblies for Renewable Energy Materials and Devices

Mark Tuominen
Experimental Condensed Matter Physics

Dhandapani Venkataraman
Molecular and Macromolecular Synthesis and Nanoscale Assemblies for Photovoltaic Cells and Fuel Cells

James Watkins
Hybrid Solar Cells

Sigfrid Yngvesson
Microwave Effects on Catalytic Chemical Reactions



Marc Acherman
Assistant Professor, Physics
405A Hasbrouck, University of Massachusetts
Amherst, MA 01003-9292
(413) 545-3472
achermann@physics.umass.edu
http://people.umass.edu/acherman/
 
 
 
Time-Resolved Spectroscopy of Functional Nanomaterials
Our research focuses on the optical spectroscopy of nanoscale materials, specifically semiconductor, metal and organic nanostructures. We study the carrier and energy relaxation dynamics of nanostructures and the dynamics of interfacial interactions in hybrid excitonic/plasmonic materials. Understanding this behavior in functional nanomaterials will promote the implementation of these materials in solid-state lighting, sensor, and light-harvesting applications (e.g. solar cells). In addition to standard, steady-state optical characterization, our experiments rely on various time-resolved optical spectroscopy techniques in combination with far- and near-field optical microscopies.
 
 
Energy Research Interest
Potential Application
Hybrid nanostructures
Exciton-plasmon interactions in hybrid materials based on semiconductor, metal and organic nanostructures can result in enhanced absorption cross-sections or emission efficiencies and, therefore, increase the output of photovoltaic and light emitting devices.
Charge-carrier and energy dynamics
Understanding the dynamical processes in light harvesting or light emitting materials enables the optimization of charge-carrier and energy pathways towards more efficient solar energy conversion devices or light emitters.
 
 
Center/Institute Affiliation(s):
Massachusetts Center for Renewable Energy Science & Technology (Mass-CREST)

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Neal Anderson
Associate Professor, Electrical and Computer Engineering
201B Marcus Hall, University of Massachusetts
Amherst, MA 01003-9292
(413) 545-0765
anderson@ecs.umass.edu
http://www.ecs.umass.edu/ece/dept/people/faculty/anderson.html
 
 
 
Nanostructured Photovoltaics
Professor Anderson's research interests are in the broad area of physical electronics, including fundamental issues related to energy conversion and information processing in electronic systems. He was an early worker in the area of quantum well solar cells - the first photovoltaic devices to employ engineered nanostructures for the purposes of improving cell performance - and has made contributions to the modeling of these devices and the fundamental understanding of their operation and efficiency limits.
 
 
Energy Research Interest
Potential Application
Nanostructured photovoltaics
Use of nanostructures to enhance energy conversion efficiency and other characteristics of solar cells.
 
 
Center/Institute Affiliation(s):


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   Advanced Energy Research >> Harvest >> Biomass Conversion
Scott Auerbach
Professor, Chemistry
222 Goessman Lab, University of Massachusetts
Amherst, MA 01003-9292
(413) 545-1240
auerbach@chem.umass.edu
http://samson.chem.umass.edu
 
 
 
Theory and Simulation of Nanoporous Materials for Renewable Energy Materials & Devices
Professor Auerbach employs theoretical approaches and computer simulation techniques to model applications of nanoporous materials for use in renewable energy devices and systems. Zeolites are nanoporous crystalline alumino-silicates with a rich variety of interesting properties and industrial applications. Indeed, the importance of zeolites to nanotechnology cannot be overstated, considering that the value of zeolite catalysis to petroleum cracking is well in excess of 200 billion dollars. Mixed metal oxide catlysts and specialty zeolites have great potential for use as catalysts in biofuels production. However, the physical chemistry underlying these systems is poorly known. Computational studies reduce R&D cycle times by elucidating how nano-confinement produces selective adsorption, diffusion and reaction, thereby augmenting trial-and-error discovery with rational design. Prof. Auerbach is Co-Leader of Fuels for the Future Energy Research Group of Mass-CREST.
 
 
Energy Research Interest
Potential Application
Theory and simulation of microwave heated zeolites
New and possibly more energy-efficient separations
Theory and Simulation of Basic Zeolites for Biofuels
Shape-selective control over chemistry leading in the biorefinery.
Theory and Simulation of Zeolite Growth and Silica Colloid Self Assembly
Synthesis of new nanoporous materials tailored for specialized applications
Theory and Simulation of Diffusion in Zeolite Membranes
New and possibly more energy-efficient steady-state processes for separations in zeolites; using catalytically active zeolites as membrane reactors
Theoretical Basis for Organic-Based Fuel Cell Membranes
The objective of this research is the development of PEMs capable of operating at high temperatures that remain thermally, mechanically, and chemically stable and provide for the rapid unidirectional conduction of protons.
 
 
Center/Institute Affiliation(s):
Massachusetts Center for Renewable Energy Science & Technology (Mass-CREST)

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Michael Barnes
Associate Professor, Chemistry
701 LGRT, University of Massachusetts
Amherst, MA 01003-9336
413-577-3121
mdbarnes@chem.umass.edu
http://www.chem.umass.edu/Faculty/barnes.htm
 
 
 
Single-Molecule Spectroscopy, Polymer-Based Nanoscale Photonics
My current research focuses on the question of three-dimensional confinement effects in polymeric systems with specific emphasis on materials that can be used in a nanoscale optoelectronic context (e.g. solar cells).
 
 
Energy Research Interest
Potential Application
Organic Photovoltaic Devices
Organic maerials will enable lightweight, flexible, and inexpensive PV devices. The outcomes of this research may be applied to development of devices designed to more efficiently capture, convert, and utilize solar energy in a cost effective manner.
 
 
Center/Institute Affiliation(s):
Massachusetts Center for Renewable Energy Science & Technology (Mass-CREST)

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   Advanced Energy Research >> Harvest >> Biomas Conversion
Jeffrey Blanchard
Assistant Professor, Microbiology
203 Morrill Science Center IVN, University of Massachusetts
Amherst, MA 01003-
413-577-2130
blanchard@microbio.umass.edu
http://www.bio.umass.edu/micro/faculty/blanchard.html#snail
 
 
 
Climate Change: Global Effects of Populations of Marine Cyanobacteria
Global climate change is an international problem that already is impacting the evolutionary trajectory of our planet's biota. In spite of the widely appreciated magnitude of this problem, we still have a limited ability to estimate current and long-term biological effects. As the most numerically dominant species in the ocean, Prochlorococcus has become a central object of study for understanding carbon fixation by photosynthetic organisms.   Prochlorococcus is very unusual for a free living organism in that it show signs of reductive genome evolution that are typically found in organelles, endosymbionts and pathogens (see Blanchard et al. 2000) and now has a minimal transcriptional regulator network for sensing environmental change.   The long-term goal of our research is to integrate large-scale "genomic" data sets into probabilistic models that allow inferences and decisions regarding the trajectory of photosynthetic organisms in a changing global climate. 
 
 
Energy Research Interest
Potential Application
Microbial cellular and community networks
Systems Biology
Applications of genomics coupled with other model-based strategies may be used to optimize ethanol production from biomass by the microbe Clostridium phytofermentans.
Bioinformatics
 
 
Center/Institute Affiliation(s):
Massachusetts Center for Renewable Energy Science & Technology (Mass-CREST)

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   Advanced Energy Research >> Harvest >> Solar, High-efficiency Electronic Devices
Ken Carter
Associate Professor, Polymer Science and Engineering
416 Conte Building, University of Massachusetts
Amherst, MA 01003-9292
(413) 577-1416
krcarter@polysci.umass.edu
http://www.pse.umass.edu/faculty/carter.html
 
 
 
Functional Polymeric Nanostructures
There has been a steady increase in number of techniques and "tools" that are available to the polymer chemist that have allowed us to continue to gain a better understanding of complex systems and to "build" polymers with functionality and properties that were not thought possible even 5 years ago. Our research group is concerned with the design and use of high performance polymers, especially as they impact advanced microelectronics and devices. Specific research programs include high resolution nanopatterning (materials and processes); synthesis and design of electroactive polymers; controlled surface functionalization of nanopatterned polymer surfaces; bioactive surfaces and sensors.
 
 
Energy Research Interest
Potential Application
Nanolithography and Imprint Lithography
Controlled creation of nanostructures. Development of materials and processes to allow for nanofabrication
Functionalized structures
Surface modification of polymer thin films that allows for the creation of chemical specific surfaces
Polymer brushes
Study of the controlled growth of polymer brushes
Electrical and Optical Active Polymers
Design and synthesis of polymers for LED, waveguide, photovoltaic and organic electronic device applications
Patterned Bioactive Surface
Synthesis of controlled bioactive surfaces for sensor and therapeutic applications
 
 
Center/Institute Affiliation(s):


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   Advanced Energy Research >> Harvest >> Biomass Conversion
W.Curtis Conner
Professor, Chemical Engineering
105 Goessman Lab, University of Massachusetts
Amherst, MA 01003-3110
(413) 545-0316
wconner@ecs.umass.edu
http://www.ecs.umass.edu/che/faculty/conner.html
 
 
 
Biomass Refinement Catalysts
Characterization of biomass conversion catalysts is an essential step in the process of biorefinery process design. The research activities of Professor Conner in this area are focused on the use of promising mixed-metal oxide catalysts and base-functionalized zeolites for promoting condensation and addition reactions crucial to biomass refinement.
 
 
Energy Research Interest
Potential Application
Catalytic Engineering
We are developing an engineering basis for the design of new catalysts and adsorbents for the polymerization and environmental industries. Our approach is to relate the synthesis, morphology and activity of heterogeneous catalysts to the transport and adsorption within these high surface area solids. The emphasis is on the dynamics of the transport and reaction.
Characterization of high surface-area materials
We are developing the techniques to analyze porous materials and are investigating the complex, often dynamic, transformations that take place. A primary focus is on adsorption, diffusion, and transport in zeolites. The emphasis is on the interaction between morphological dynamics and the adsorbing/reacting species.
Solid-surface morphology
The petrochemical, environmental, and materials synthesis industries are dominated by reaction on the surface of solids. We are concentrating on olefin polymerization, environmental catalysis, and deactivating catalyst systems. Our approach is to study the interactions and reactions in situ and, thereby, to understand the surface chemistry and dynamics leading to reaction and catalysis.
Catalytic Microwave Engineering
Microwave energy often has a unique ability to influence chemical reactions, resulting in more efficient processes and new products. Specifically, recent studies document enhancement of nanoporous oxide synthesis, selective separations and catalytic reactions employing microwaves. However, the mechanism and engineering for the enhanced reactions have been unknown. We are studying these novel reactions by in situ spectroscopy and microwave reactor engineering to understand the enhancements and to control these processes.
 
 
Center/Institute Affiliation(s):
Massachusetts Center for Renewable Energy Science & Technology (Mass-CREST)

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   Advanced Energy Research >> Harvest >> Fuel Cells and Batteries
Bryan Coughlin
Co-Director Mass-CREST - Associate Professor, Polymer Science and Engineering
612 Conte Building, University of Massachusetts
Amherst, MA 01003-9292
(413) 577-1616
coughlin@mail.pse.umass.edu
http://www.pse.umass.edu/coughlin
 
 
 
Synthesis of Polymer Nanocomposites for Renewable Energy Materials and Devices
Synthesis of novel polymer-inorganic hybrid copolymers, and investigation of their physical and mechanical properties. Copolymerization of molecularly precise nanometer-scale inorganic particles with simple vinyl monomers to develop fundamental understandings necessary to exploit the resulting structure-property correlations. A chemistry-based "bottom-up" approach to the formation of hybrid polymer nanocomposites, harnessing the beneficial thermodynamics associated with self-assembly processes.
 
 
Energy Research Interest
Potential Application
Living Polymerization
Living polymerization enables the creation of well-defined block copolymer electrolyte compositions. The objective of this research is to precisely control fuel cell membrane property determining factors such as ionic strength, inter-ionic distances, and water uptake.
Novel Block Copolymer Assemblies for Improved Fuel Cell Membranes
Current proton-conducting membrane materials (e.g. Nafion) cannot operate at low relative humidity - this is a fundatmental limitation. This research investigates the effects of novel polymer chemistries and tailored morphologies on proton conduction in polymer electrolytes. The objective of this research is to develop fundamental knowledge about the conductivity properties of polymer electrolytes in order to create low-cost membranes that can operate at high temperature and relatively low humidity.
Highly Ordered Nanoscale Architectures
Newly designed chemical compositions of diblock copolymers comprised of highly ordered nanoscale architectures will enable the development of new fuel cell membrane materials with enhanced performance characteristics.
Precision Functionalized Polymers
Nanoparticle Stabilization
 
 
Center/Institute Affiliation(s):
Massachusetts Center for Renewable Energy Science & Technology (Mass-CREST)

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   Advanced Energy Research >> Harvest >> Solar, Fuel Cells
Samuel Gido
Associate Professor, Polymer Science and Engineering
A216 Conte Buildin, University of Massachusetts
Amherst, MA 01003-9292
(413) 577-1216
spgido@mail.pse.umass.edu
http://www.pse.umass.edu/gido/
 
 
 
Self-assembling Nanostructures
My research is focused on understanding how controlled polymer molecular architecture can be used to guide the self assembly and processing behavior of materials in order to create novel and useful structures on a morphological length scale (nanometers to microns).
 
 
Energy Research Interest
Potential Application
Morphology of self-assembling materials of controlled molecular architecture.
Block Copolymers, biopolymers, liquid crystalline polymers, and semicrystalline polymers
Electron microscopy, X-ray and neutron scattering
 
 
Center/Institute Affiliation(s):


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Jeanne Hardy
Assistant Professor, Chemistry
1021 LGRT, University of Massachusetts
Amherst, MA 01003-
(413) 545-3486
hardy@chem.umass.edu
http://www.chem.umass.edu/Faculty/hardy.htm
 
 
 
Organic/Inorganic Composite Fuel Cell Membranes
Professor Hardy's research, as it applies to renewable energy devices, is focused on the application of a biological proton pump that can be incorporated into nanoporous polycarbonate membranes. The work addresses the problem of achieving routine proton transfer across unidirectional PEM. The objective of this research is to build a stable membrane that selectively transports protons generated in a fuel cell.
 
 
Energy Research Interest
Potential Application
Biologic Proton Transporter in PEMs
The M2 protein from influenza virus is the smallest known biological proton pump, just 4 helices and 25 amino acids. Nanoporous polycarbonate membranes may be functionalized with engineered M2 proteins in order to facilitate unidirectional proton transfer.
Protein Production, Manipulation, Rational Design, and Characterization of Proteins by X-Ray Crystallography
Function-based protein screening may be applied to the identification of other biological moieties with renewable energy device applications
 
 
Center/Institute Affiliation(s):


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   Advanced Energy Research >> Harvest >> Biomass Conversion
Michael Henson
Director, Center for Process Design and Control - Professor, Chemical Engineering
259A Goessmann Lab, University of Massachusetts
Amherst, MA 01003-3110
(413) 545-3481
henson@ecs.umass.edu
http://www.ecs.umass.edu/che/henson_group/index.html
 
 
 
Nonlinear Systems Modeling and Analysis
Nonlinear modeling techniques are being developed and evaluated for a wide variety of complex systems with an emphasis on microbially mediated biomass conversion to ethanol. Professor Henson's laboratory focuses on integrated cellular and process engineering strategies to optimize microbial metabolism for biofuel production.
 
 
Energy Research Interest
Potential Application
Dynamic Modeling and Genome-Scale Analysis of Yeast Metabolism
Our long-term goal is to develop an integrated optimization framework that simultaneously identifies promising genetic manipulations and favorable dynamic operating policies for batch and fed-batch overproduction of valuable primary metabolites such as ethanol.
 
 
Center/Institute Affiliation(s):
Center for Process Design and Control http://www.ecs.umass.edu/che/pdcc/

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   Advanced Energy Research >> Harvest >> Biomass Conversion
Stephen Herbert
Professor, PSIS
Bowdwitch Hall 207, University of Massachusetts
Amherst, MA 01003-0910
(413) 545-2250
sherbert@pssci.umass.edu
http://www-unix.oit.umass.edu/~sherbert/
 
 
 
Renewable Energy Crop Agronomy
Agronomy field research trials are required to determine the effective energy yield of switchgrass and other potential "energy crops" under marginal soil conditions. Data generated through such field trials may be used to determine the agricultural feasability of energy biomass cropping in Massachusetts
 
 
Energy Research Interest
Potential Application
Switchgrass Agronomy
Switchgrass may be grown on soils that would be inhospitable to food crops. This crop is being studied as a potential feedstock for biomass energy production.
 
 
Center/Institute Affiliation(s):
Massachusetts Center for Renewable Energy Science & Technology (Mass-CREST)

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   Advanced Energy Research >> Harvest >> Biomass Conversion
George Huber
Assistant Professor, Chemical Engineering
159 Goessmann Lab, University of Massachusetts
Amherst, MA 01003-9303
413-545-2507
huber@ecs.umass.edu
http://www.ecs.umass.edu/che/faculty/huber.html
 
 
 
Catalytic Processes for Biofuels and Biochemicals Production
The objective of our research is to develop highly efficient and low-cost catalytic processes, catalytic materials and reactors for biomass conversion to fuels and chemicals. One technology we are developing is aqueous-phase processing, which is advantageous for biomass conversion strategies in that high energy efficiencies are obtained, recyclable-heterogeneous catalysts are used, and biomass-derived molecules, which have a high degree of functionality and low thermal stability, can be processed.
 
 
Energy Research Interest
Potential Application
Aqueous-phase processing
Production of liquid and gaseous fuels from plant biomass. Liquid fuels are produced including gasoline, diesel fuel, and heating oil. We are studying a range of feedstocks that are all derived from plant biomass including bio-oils, sugars, vegetable oils, and waste streams from paper.
Synergies between bio and oil refineries
We are studying methods to produce biofuels in a petroleum refinery. This has the advantage in that little capital cost is required as the petroleum refinery is already built. Biomass-derived feedstocks can be feed directly into a petroleum refinery and produce: diesel, gasoline, jet fuel, heating oil, and olefins.
Hydrogen production from Biomass
We are developing processes for production of hydrogen from plant biomass. One of these technologies is aqueous-phase reforming which is currently being commercialized by Virent Energy Systems.
Fast Pyrolysis Chemistry
Bio-oils, which are a combustible mixture of more than 400 compounds, can be produced by fast pyrolysis of biomass. During this process a complex pathway of chemical reactions are occurring produced a wide range of products. We are studying and modeling the pyrolysis chemistry to try and improve this process to produce targeted chemicals and fuels.
 
 
Center/Institute Affiliation(s):
Massachusetts Center for Renewable Energy Science & Technology (Mass-CREST)

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Robert Hyers
Associate Professor, Mechanical and Industrial Engineering
160 Governors Drive, University of Massachusetts
Amherst, MA 1003
413-545-2253
hyers@ecs.umass.ed
http://www.ecs.umass.edu/mie/faculty/hyers.html
 
 
 
Condition Monitoring and Prognosis in Wind Turbines
As wind turbines grow larger and are installed in remote and offshore locations, operation and maintenance grows as a fraction of the total cost of energy. In such locations, the heavy equipment needed for major repairs can only reach the wind turbine for a few months out of the year. Therefore it is essential to predict failures of these machines as far in advance as possible, and to provide a continuously revised operating window in damaged machines to maximize energy production until service is possible. Such a strategy not only maximizes the value of the wind machine, but it also minimizes the risk of downtime and of propagation of failure to more expensive parts of the system.
 
 
Energy Research Interest
Potential Application
Condition Monitoring and Prognosis of large composite structures
Detection of damage and prediction of future damage in wind turbine blades.
High-Temperature Materials
More efficient jet engines and stationary gas turbines.
 
 
Center/Institute Affiliation(s):
Renewable Energy Research Laboratory

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   Advanced Energy Research >> Harvest >> Biomass Conversion
Bret Jackson
Professor, Chemistry
701A LGRT, University of Massachusetts
Amherst, MA 01003-9336
413-545-2583
jackson@chem.umass.edu
http://www.chem.umass.edu/Faculty/jackson.htm
 
 
 
Theoretical Studies of Reactions on Surfaces
We use a variety of theoretical methods to gain a molecular-level understanding of chemical reactions occuring on metal, semiconductor, and carbon surfaces. Problems of interest include reactions important to heterogeneous catalysis, etching, and semiconductor processing. Electronic structure methods based on Density Functional Theory are used to examine the interactions between molecules and these substratres, and to compute the potential energy surfaces controling these processes. Both quantum and classical mechanics are used to explore the dynamics of sticking and reaction. Methodologies are employed to include the exchange of energy between the reacting species and the thermal and electronic excitations of the substrate.
 
 
Energy Research Interest
Potential Application
Development of improved metal-based catalysts
Our goal is to develop an understanding of how and why reactions take place on catalytic surfaces. These ideas will contribute to the development of improved catalysts for such things as biomass conversion or fuel cells.
 
 
Center/Institute Affiliation(s):
Massachusetts Center for Renewable Energy Science & Technology (Mass-CREST)

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   Advanced Energy Research >> Harvest >> Biomass Conversion
Susan Leschine
Professor, Microbiology
203 Morrill Science Center IVN, University of Massachusetts
Amherst, MA 01003-
413-545-0673
suel@microbio.umass.edu
http://www.bio.umass.edu/micro/faculty/leschine.html
 
 
 
Fuels from Biomass: Microbially Mediated Production of Cellulosic Ethanol
The diversity of the microbial world is enormous and microbes have played a central role in the development of the biotechnology industry. Microbes also have important applications for renewable energy technology. An objective of Professor Leschine's research program is to advance our understanding of these diverse microorganisms and the interactions among these organisms and their environment. Such knowledge is essential for the successful application of microbes, their activities and products, to solve problems and fill needs of our society.
 
 
Energy Research Interest
Potential Application
Natural History of Clostridium phytofermentans
The bacterium C. phytofermentans actively and efficiently decomposes cellulose and produces ethanol. Cellulose-fermenting cultures of C. phytofermentans produce prodigious amounts of ethanol and they also form H2. C. phytofermentans possesses exceptional nutritional versatility and is therefore capable of decomposing more components of biomass than most other known microbes. C. phytofermentans is able to simultaneously ferment different polymeric components of biomass (e.g., cellulose and xylan), a property that would be particularly useful for the efficient production of ethanol from biomass. C. phytofermentans was isolated from forest soil near Massachusetts' Quabbin reservoir.
Consolidated Bioprocessing
Consolidated Bioprocessing (CBP) is an ethanol production method using C. phytofermentans in which cellulase enzyme synthesis hydrolysis of biomass polysaccharides, and fermentation of the resulting simple sugars occur simultaneously in a single bioreactor. The inherent simplicity of the C. phytofermentans CBP technology obviates the need for separate and costly enzyme manufacture.
Genomics of C. phytofermentans
Future advancements in C.phytofermentans CBP technology might involve genetic modifications of the microbe to further improve its fermentation properties. We are exploring genetic engineering strategies to modify the metabolic properties of C. phytofermentans in order to maximize the cellulosic ethanol yield and increase the microbe's tolerance to ethanol. These strategies are anticipated to enhance cellulase activity and eliminate unwanted byproduct formation. In support of this research, the genome sequence of C. phytofermentans has been determined in collaboration with the U.S. Department of Energy Joint Genome Institute.
 
 
Center/Institute Affiliation(s):
Massachusetts Center for Renewable Energy Science & Technology (Mass-CREST)

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Derek Lovley
Professor, Microbiology
203 Morrill Science Center IVN, University of Massachusetts
Amherst, MA 01003-
413-545-9651
dlovley@microbio.umass.edu
http://www.geobacter.org/
 
 
 
Microbial Fuel Cells
It is well established that some reduced fermentation products or microbially reduced artificial mediators can abiotically react with electrodes to yield a small electrical current. This type of metabolism does not typically result in an efficient conversion of organic compounds to electricity because only some metabolic end products will react with electrodes, and the microorganisms only incompletely oxidize their organic fuels. A new form of microbial respiration has recently been discovered in which microorganisms conserve energy to support growth by oxidizing organic compounds to carbon dioxide with direct quantitative electron transfer to electrodes. These organisms, termed electricigens, offer the possibility of efficiently converting organic compounds into electricity in self-sustaining systems with long-term stability.
 
 
Energy Research Interest
Potential Application
Microbial electricigens
Microbial fuel cells for power sources in remote locations and regions of developing countries that are not served by well-developed, centralized power grids.
Bioremediation and waste removal
Harvest electricity from many types of waste organic matter.
 
 
Center/Institute Affiliation(s):
Massachusetts Center for Renewable Energy Science & Technology (Mass-CREST)

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James Manwell
Research Associate Professor and Director, Renewable Energy Research Laboratory, Mechanical and Industrial Engineering
160 Govenor's Dr., University of Massachusetts
Amherst, MA 01003-
413-545-4359
manwell@ecs.umass.edu
http://www.ceere.org/rerl/team/manwell_j.html
 
 
 
Wind Power and Distributed Energy
Prof. Manwell has been working in field of wind energy for over 25 years, where his research interests have focused on wind resource assessment, hybrid power system design, and offshore wind energy. Since the 1980's he has been active in the design and modeling of hybrid power systems, including the development of the Hybrid2 computer code. Hybrid systems include multiple types of generators, electrical loads, storage units and control systems. Under his direction, the Renewable Energy Research Laboratory installed in 1994 the first utility scale (250 kW) wind turbine in Massachusetts. More recently, he has assisted the Town of Hull in acquiring a 660 kW wind turbine in 2001 (the largest in New England at that time), followed by a 1.8 MW wind turbine in 2006 (again, the largest in New England). He is currently working with the Town of Hull to design a small offshore wind farm. He is an author of a textbook on wind energy: Wind Energy Explained: Theory, Design and Application. Currently he is the U.S. representatives to the International Electrotechnical Commission's program (IEC TC88 WG3) to develop design standards for offshore wind turbines. He is also a member of the Planning Group for the International Science Panel on Renewable Energy.
 
 
Energy Research Interest
Potential Application
Hybrid Power System Modeling
Hybrid systems include multiple types of generators, electrical loads, storage units and control systems. Improved distributed systems and enhanced battery performance will diversify and strengthen the national power infrastructure.
Wind-Based Renewable Energy
The Renewable Energy Research Laboratory installed in 1994 the first utility scale (250 kW) wind turbine in Massachusetts. This turbine forms an integral part of the research and education program at the University.
Off-Shore Wind Power
Development of off-shore wind power generation systems will enable greater access to this renewable resource. Consortium planning: MTC/DOE/GE/MIT/Woods Hole. Research outcomes include - Wind farm optimization: Structures and foundations. Economics, environment, and grid integration.
 
 
Center/Institute Affiliation(s):
Renewable Energy Research Laboratory

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Michael Maroney
Professor, Chemistry
505B Lederle GRT, University of Massachusetts
Amherst, MA 010003-9292
413-545-4876
mmaroney@chem.umass.edu
http://www.chem.umass.edu/Faculty/maroney.htm
 
 
 
Biohybrid Catalysts
Work in my group involves collaborative efforts to attach metalloenzymes to nanoparticles and other materials for use as catalysts. An example is our work to attach hydrogenase to various materials to produce materials that can generate hydrogen.
 
 
Energy Research Interest
Potential Application
Hydrogenases
Hydrogen generating materials and fuel cell catalysts
Integration of Biological Catlysts with Nanoscale Materials for Hydrogen Production and Utilization
The objective of this research is to create an efficient and economical immobilized, integrated catalyst system for hydrogen production and utilization
 
 
Center/Institute Affiliation(s):
Massachusetts Center for Renewable Energy Science & Technology (Mass-CREST)

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Jon McGowan
Professor, Mechanical and Industrial Engineering
220 Elab, University of Massachusetts
Amherst, MA 01003-2210
413-545-2756
jgmcgowan@ecs.umass.edu
http://www.ecs.umass.edu/mie/faculty/mcgowan.html
 
 
 
Wind Power and Distributed Energy
Work has focused on analytical models for component of wind and distributed energy system performance analysis, and experimental work dealing with the calibration/validation of such models.
 
 
Energy Research Interest
Potential Application
Energy conversion systems
Development of models and design codes for hybrid (wind/diesel/PV) energy systems, and the improvements of components (such as the diesel generator or battery storage) for hybrid systems
Windpower systems
Key design variables of wind turbines, and the economic and performance analysis of large scale wind systems, especially in the environment of New England
 
 
Center/Institute Affiliation(s):
Renewable Energy Research Laboratory

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   Advanced Energy Research >> Harvest >> Solar and Fuel Cells
Murugappan Muthukumar
Professor, Polymer Science and Engineering
A212 Conte Research Center, University of Massachusetts
Amherst, MA 01003-
413-577-1212
muthu@polysci.umass.edu
http://www.pse.umass.edu/faculty/muthu.html
 
 
 
Theory and Modeling of Polymer Crystallization
Polymer theory and modeling techniques may be employed to design novel materials for use in renewable energy devices such as organic photovoltaics and fuel cell membranes.
 
 
Energy Research Interest
Potential Application
Polymer Crystallization
Polyelectrolyte Physics
Translocation of DNA and proteins through protein channels and nanopores
 
 
Center/Institute Affiliation(s):
Massachusetts Center for Renewable Energy Science & Technology (Mass-CREST)

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Klaus Nusslein
Associate Professor, Microbiology
203 Morrill Science Center IVN, University of Massachusetts
Amherst, MA 01003-
413-545-1356
nusslein@microbio.umass.edu
http://www.bio.umass.edu/micro/faculty/nusslein.html
 
 
 
Unconventional Fossil Fuels Recovery
Indigenous microbial consortia may be optimized to perform methane conversion on fossil fuel deposits for which conventional recovery methods are not cost effective. This research focuses on efforts to stimulate natural gas (methane) producing microbes to convert unmineable coal to methane underground. Further research ideas include the use of other buried organic matter with the intent to provide long-term biotechnology-driven solutions for enhancement and sustained production of natural gas.
 
 
Energy Research Interest
Potential Application
Methane-producing microbes
Conversion of hard-to-reach fossil fuel reserves (oil and coal) into methane gas for surface collection.
 
 
Center/Institute Affiliation(s):


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   Advanced Energy Research >> Harvest >> Biomass Conversion
Om Parkash
Assistant Professor, PSIS
202 French Hall, University of Massachusetts
Amherst, MA 01003-
413-545-0062
parkash@psis.umass.edu
http://www.bio.umass.edu/plantbio/faculty/parkash.html
 
 
 
Plant Biotechnology for Development of Improved "Energy Crops"
Professor Parkash employs biotech methods to enhance the characteristics of a non-food plant for use in phytoremediation applications and as a potential "energy crop." The Parkash laboratory posesses genetic engineering expertise that can be applied to any crop plants for biomass enhancment and optimization of the pathways governing lignin production and cellulose degradation.
 
 
Energy Research Interest
Potential Application
Genetic Engineering of a Brassica Plant Species
Crambe sp. is a high-biomass, non-food oil crop capable of cultivation on agriculturally marginal lands. Oil extracted from plants of this species may be used for BioDiesel production. In addition to the biofuels produced from Crambe, its woody stem may be incinerated for production plant electricity generation. Apart from these "BioEnergy" benefits, several important biomaterials can be recovered from Crambe oil such as Erucic acid and the high-protein content of its seed meal. Products that may be manufactured from Crambe oil include lubricants, synthetic rubber additives, adhesives and electrical insulation. Moreover, the biomass can be used for environmental remediation of sites contaminated by heavy metals (e.g. arsenic). Subsequently harvested biomass may be used for all the bioenergy and materials production processes described above.
 
 
Center/Institute Affiliation(s):
Massachusetts Center for Renewable Energy Science & Technology (Mass-CREST)

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Steven Petsch
Assistant Professor, Geosciences
Dept of Geosciences, 611 N. Pleasant St., University of Massachusetts
Amherst, MA 01003-9297
413-545-4413
spetsch@geo.umass.edu
http://www.geo.umass.edu/faculty/petsch/
 
 
 
Unconventional Fossil Fuels Recovery
Certain microbial species thrive in the most extreme geologic environments, hundred of meters underground. We're testing the limits of what it means to be refractory, labile or biologically available, by examining degradation, dissolution and biological utilization of ancient organic matter in modern soils, aquatic systems, and the deep subsurface. An increased understanding of the geologic and biotic properties of these extreme environments may enable exploitation of microbial metabolism to convert organic matter in rocks deep underground into methane gas for surface collection.
 
 
Energy Research Interest
Potential Application
Molecular biomarkers
Identification of isotopic and geochemical fingerprints of microbial methane generation in sedimentary basins may permit development of biotechnologies for controlled converstion of coal deposits into methane gas.
Identification of isotopic and molecular fingerprints of microbial methane generation in sedimentary basins may guide exploration and development of biogenic natural gas reservoirs.
Aqueous environmental geochemistry
Characteristics of the geochemical environments that support the subsurface biosphere may serve to indicate particular geological conditions that have stimulated microbial methane generation in the past, such as deep groundwater recharge, glaciation, and lack of thermal maturation.
 
 
Center/Institute Affiliation(s):


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   Advanced Energy Research >> Harvest >> Solar Fuel Cell Membranes
Thomas Russell
Professor, Polymer Science and Engineering
Conte Research Center Room A516, University of Massachusetts
Amherst, MA 01003-
413-545-2680
russell@mail.cpse.umass.edu
http://www.pse.umass.edu/faculty/russell.html
 
 
 
Polymers and Block Copolymers for Nanostructured Energy Devices
Over the past decade we have been developing routes and understanding the mechanism by which the orientation and long-range ordering of the morphology in thin block copolymer films can be controlled with exquisite precision. This has given rise to applications ranging from separations to addressable magnetic storage.media and has clear potential in photovoltaic devices. In addition, by understanding the interfacial activity of nanoparticles we are developing routes to achieve multi-length scale ordering of nanoparticles and nanorods on patterned surfaces that is emerging as a novel interesting platform for producing self-assembling, self-directing photovoltaics devices. We are also pursuing studies on fluorinated copolymers with sulfonated styrene-based side chains for fuel cell applications.
 
 
Energy Research Interest
Potential Application
Block Copolymers
Nanofabrication techniques such as self-assembly of highly-ordered nanoarrays with applications for prodution of high-efficiency photovoltaic materials and fuel cell membranes.
Fluorinated Comb Copolymer
Possible replacement of the industry standard of Nafion membranes using a well-designed comb-shaped copolymers to produce membranes wiith well-defined, well-controlled morphologies for fuel cell applications.
Nanorod Assemblies
Using a self-corralling process developed in our laboratories, hexagonal arrays of nanorods, functionalized with photoactive ligands, are being placed on patterned surfaces for generating inexpensive, highly-efficient photovoltaic devices.
 
 
Center/Institute Affiliation(s):
Massachusetts Center for Renewable Energy Science & Technology (Mass-CREST)

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   Advanced Energy Research >> Harvest >> Biomass Conversion
Danny Schnell
Professor, Biochemistry and Molecular Biology
1020 Lederle Graduate Research Tower, University of Massachusetts
Amherst, MA 01003
413-545-4024
dschnell@biochem.umass.edu
http://www.biochem.umass.edu/schnell/index.html
 
 
 
Primary Productivity: Feedstock Optimization for Production of Biofuels and Bioproducts
Professor Schnell's cellular and molecular genetic approaches to understanding protein trafficking and membrane biogenesis in chloroplasts have had a major impact on the fields of chloroplast biology, photosynthesis and plant cell biology in general. The bioenergy-related components of his research program are intended to accelerate the introduction of desirable traits into dedicated biomass crops and improve their yield. Such improvements to bioenergy-relevant plant species will help meet the billion tons of biomass annual production goal that is needed to reach the DOE target of 30% gasoline reduction by 2030.
 
 
Energy Research Interest
Potential Application
Plant cell wall structure, physiology, and development
Research is aimed at both identifying and introducing desirable traits that increase cellulosic biomass and facilitate decomposition of the cellulosic and hemicellulosic components of bioenergy-relevant species.
Chloroplast engineering
Engineering the chloroplast protein targeting system to express and accumulate foreign proteins in chloroplasts. Wide range of applications for biofuels and premium bioproducts.
 
 
Center/Institute Affiliation(s):


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   Advanced Energy Research >> Harvest >> Solar Fuel Cell Membranes
Sankaran Thayumanavan
Co-Director MassCREST - Associate Professor, Chemistry
1537 Lederle GRT, University of Massachusetts
Amherst, MA 01003-9292
(413) 545-1313
thai@chem.umass.edu
http://www.umass.edu/thaigroup
 
 
 
Polymers and Nanoscale Assemblies for Renewable Energy Materials and Devices
Professor Thayumanavan's research interests are focused on the design, syntheses, characterization, and use of new functionalized macromolecules and fabrication of nanoscale materials. The motivations behind these molecular designs are focused on addressing a biological or materials problem that is not addressed by the systems known in nature. The applications of this work should lead to improved energy harvesting and solar conversion efficiencies.
 
 
Energy Research Interest
Potential Application
Polymers for Harvesting Solar Energy
Polymers investigation will enable lightweight, flexible, and inexpensive photovoltaic devices that can efficiently capture, convert, and utilize solar energy in a cost-effective manner. Novel charge transport polymers and light absorbers are being designed and synthesized.
Nanoscale Photovoltaics
Limitations based on exciton diffusion lengths suggest that nanomaterials are promising scaffolds for photovoltaics. Organic and organic/inorganic composite based nanomaterials are being used for device fabrication.
Integration of Biological Molecules into Materials for Fuel Cell and Hydrogen Production Systems
Specificity and efficiency are hallmarks of biological systems. Utilizing these features, but in the surroundings of a device is a challenge. For example, we are interested in generating composite materials with hydrogenases and proton transport proteins for hydrogen production and fuel cell usage respectively.
 
 
Center/Institute Affiliation(s):
Massachusetts Center for Renewable Energy Science & Technology (Mass-CREST)

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   Advanced Energy Research >> Harvest >> Solar, Nanoscale electronic devices
Mark Tuominen
Professor, Physics
411 Hasbrouk Lab, University of Massachusetts
Amherst, MA 01003-
413-545-1691
tuominen@physics.umass.edu
http://people.umass.edu/tuominen/
 
 
 
Experimental Condensed Matter Physics
Research in the fabrication and physics of nanoscale devices and materials. This includes two primary research areas: nanostructures from self-assembling block copolymer templates and nanoscale device physics. The first area addresses the general scientific challenge of fabricating nanoscale structures by a convenient method and providing appropriate electrical interfacing to these structures. To adress this challenge, diblock copolymer films are used as a convenient self-assembling template for the fabrication of arrays of nanoscale elements. This results in a new fabrication method for producing integrated devices using block copolymer templates in combination with other lithographic methods. Associate Director of MassCREST.
 
 
Energy Research Interest
Potential Application
Nanostructures
Nanoscale fabrication technique permit the development of precisely engineered nanostructures for use in renewable energy devices and systems.
Single charge transport
Higher conversion efficiencies of photovoltaic materials may result from our single-electron investigations of mesoscopic superconductors and, more recently, experimental and theoretical studies on charge shuttle devices, which involves quantum charge transport coupled with mechanical vibration.
 
 
Center/Institute Affiliation(s):
Massachusetts Center for Renewable Energy Science & Technology (Mass-CREST)

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   Advanced Energy Research >> Harvest >> Solar and Fuel Cells
Dhandapani Venkataraman
Associate Professor, Chemistry
701A LGRT, University of Massachusetts
Amherst, MA 01003-9336
413-545-2028
dv@chem.umass.edu
http://www.chem.umass.edu/Faculty/venkataraman.htm
 
 
 
Molecular and Macromolecular Synthesis and Nanoscale Assemblies for Photovoltaic Cells and Fuel Cells
We focus on the synthesis of conjugated molecules and macromolecules (p- and n-type semiconductors) and their directed assembly into heterojunction structures. We equip molecules or macromolecules with appropriate side-chains, which will direct the assembly of p-type and n-type semiconductors into p-n junctions. We also focus on the synthesis oriented inorganic semiconductor nanorods and heterojunction arrays using porous templates derived cleavable diblock polymers. The porous templates can also be chemically modified for use as membranes for fuels cells. Bioinorganic conjugates of Inorganic semiconductor nanorods or nanoparticles and enzymes will also be used as catalysts for the generation of hydrogen from water.
 
 
Energy Research Interest
Potential Application
p-type semiconductor molecules and n-type semiconductormolecules with mutually phobic side-chain interactions
Fabrication of efficient heterojunctions with increased mobility and efficient exciton dissociation
Heterojunction Arrays of inorganic (n-type) and organic (p-type) semiconductors through cleavable diblock polymer
Fabrication of efficient heterojunction arrays, increased photocurrent conversion efficiencies
Bioinorganic conjugates catalysts
Clean and efficient production of hydrogen from water. Efficient photo or electrochemical dissociation of water including saline, sea water
 
 
Center/Institute Affiliation(s):
Massachusetts Center for Renewable Energy Science & Technology (Mass-CREST)

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James Watkins
Professor, Polymer Science and Engineering
Conte Research Center Room A616, University of Massachusetts
Amherst, MA 01003-
413-545-2569
watkins@polysci.umass.edu
http://www.pse.umass.edu/faculty/watkins.html
 
 
 
Hybrid Solar Cells
Hybrid organic-inorganic composite solar cells have the potential to deliver competitive conversion efficiencies at comparatively low cost relative to solid state devices. A simple design is a bilayer device in which a planar interface separates an inorganic semiconductor such as titania and a sensitized conjugated polymer sandwiched between electrodes. However, such a design suffers from low interfacial area and poor efficiency. Substantial improvements can be realized by the use of three-dimensional bulk heterojunctions.
 
 
Energy Research Interest
Potential Application
Inorganic nanoparticle-organic polymer blending
Photovoltaic materials with increased energy conversion efficiencies.
Conducting polymer coatings
Photovoltaic polymeric materials with an increased spectral absorption range.
 
 
Center/Institute Affiliation(s):
Massachusetts Center for Renewable Energy Science & Technology (Mass-CREST)

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   Advanced Energy Research >> Harvest >> Biomass Conversion
Sigfrid Yngvesson
Professor Emeritus, Electrical and Computer Engineering
142B Marston Hall, University of Massachusetts
Amherst, MA 01003-9293
413-545-0771
yngvesson@ecs.umass.edu
http://www.ecs.umass.edu/ece/dept/people/faculty/yngvesson.html
 
 
 
Microwave Effects on Catalytic Chemical Reactions
Microwave energy can be used to enhance the catalysis of biomass conversion.
 
 
Energy Research Interest
Potential Application
Microwave reactor engineering
 
 
Center/Institute Affiliation(s):
Laboratory for Millimeter Wave Devices and Applications (LAMMDA), Terahertz Laboratory (THz Lab)

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Research
Centers

Political Economy Research Institute

Fueling the Future Center for Chemical Innovation

Energy Frontiers Research Center

The Institute for Massachusetts Biofuels Research

Climate System Research Center

Center for Energy Efficiency and Renewable Energy

Wind Energy Center

Geobacter Project

The Environmental Institute

Virtual Center for Supernetworks

Green Building Research Group

Technology Transfer

 
 
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